Exploration of Seasonal Metal Pollution in Karacaören II Dam Lake Sediment Samples using X-ray Fluorescence Method
Year 2023,
Volume: 44 Issue: 3, 567 - 582, 29.09.2023
Gökhan Apaydın
,
Oğuz Kağan Köksal
,
Erhan Cengiz
,
Murat Şirin
,
Hasan Baltas
,
Engin Tıraşoğlu
Abstract
In this study, the seasonal metal pollution of sediment samples taken from twelve distinct notes of the Karacaören II Dam Lake was examined. The quantity of metal in soil samples was determined using energy dispersive X-ray fluorescence spectroscopy. The geoaccumulation index and enrichment factor expressions were created using the metal concentrations found in the sediments. Seasonal values at the local, state, and international levels were compared to the findings. The ratios of the elements copper, zinc, lead, arsenic, nickel, chromium, and mercury, measured in parts per million (ppm), were found to be 42-96, 53-78, 11-14, 4-7, 233-244, and 611-711, respectively. There is also discussion of the sediments' elemental composition and degree of pollution. In contrast, it was found that the Urbach energy increased from 0.246 eV to 0.630 eV with increasing levels of V2O5. These synthetic glasses' densities and molar volumes were also investigated and discussed.
Supporting Institution
TÜBİTAK
Thanks
This work has been made possible thanks to TUBITAK Project No. 115Y768 from the Turkish Council for Scientific and Technological Research.
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Year 2023,
Volume: 44 Issue: 3, 567 - 582, 29.09.2023
Gökhan Apaydın
,
Oğuz Kağan Köksal
,
Erhan Cengiz
,
Murat Şirin
,
Hasan Baltas
,
Engin Tıraşoğlu
References
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- [2] Singh K.P., Mohan D., Singh V.K., Malik A., Studies on distribution and fractionation of heavy metals in Gomti river sediments—a tributary of the Ganges, India, Journal of Hydrology, 312 (2005) 14-27.
- [3] Mwamburi J., Variations in trace elements in bottom sediments of major rivers in Lake Victoria's basin, Kenya, Lakes & Reservoirs: Research & Management, 8 (2003) 5-13.
- [4] Ghrefat H., Yusuf N., Assessing Mn, Fe, Cu, Zn, and Cd pollution in bottom sediments of Wadi Al-Arab Dam, Jordan, Chemosphere, 65 (2006) 2114-2121.
- [5] Khaled A., El Nemr A., El Sikaily A., An assessment of heavy-metal contamination in surface sediments of the Suez Gulf using geoaccumulation indexes and statistical analysis, Chemistry and Ecology, 22 (2006) 239-252.
- [6] Linnik P.M., Zubenko I.B., Role of bottom sediments in the secondary pollution of aquatic environments by heavy‐metal compounds, Lakes & Reservoirs: Research & Management, 5 (2000) 11-21.
- [7] Makundi I.N., A study of heavy metal pollution in Lake Victoria sediments by energy dispersive X-ray fluorescence, Journal of Environmental Science and Health, Part A, 36 (2001) 909-921.
- [8] Çevik F., Göksu M.Z.L., Derici O.B., Fındık Ö., An assessment of metal pollution in surface sediments of Seyhan dam by using enrichment factor, geoaccumulation index and statistical analyses, Environmental monitoring and assessment, 152 (2009) 309-317.
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- [10] Bat L., Yesim Ozkan E., Oztekin H. Can, The contamination status of trace metals in Sinop coast of the Black Sea, Turkey, (2015).
- [11] Bryan G., Some aspects of heavy metal tolerance in aquatic organisms, Effects of pollutants on aquatic organisms, 2 (1976) 7- 34.
- [12] Fernandez-Leborans G., Herrero Y.O., Toxicity and bioaccumulation of lead and cadmium in marine protozoan communities, Ecotoxicology and environmental safety, 47 (2000) 266-276.
- [13] Järup L., Hazards of heavy metal contamination, British medical bulletin, 68 (2003) 167-182.
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- [15] Alkan A., Alkan N., Yanar B., Investigation of pollution levels originated from anthropogenic gadolinium in Ankara Stream, Environmental Science and Pollution Research, 27 (2020) 23677-23685.
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- [18] Ozkan E.Y., Buyukisik B., Geochemical and statistical approach for assessing heavy metal accumulation in the southern Black Sea sediments, Ekoloji, 21 (2012) 11-24.
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- [21] Kir I., Erdogan M., Engin M.S., Cay S., Trace metals in sediment, water and their bioaccumalation in Carp (Cyprinus Carpio L., 1758) samples, captured from the Karacaoren (I) Dam Lake, Turkey, Fresenius Environmental Bulletin, 25 (2016) 3557-3562.
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- [23] Kalyoncu L., Kalyoncu H., Arslan G., Determination of heavy metals and metals levels in five fish species from Işıklı Dam Lake and Karacaören Dam Lake (Turkey), Environmental monitoring and assessment, 184 (2012) 2231-2235.
- [24] Ozvarol Z., Karabacak G., Changes in the population structure of pikeperch (Sander lucioperca Linnaeus, 1758) Karacaoren-I Dam Lake, Turkey, Journal of Animal and Veterinary Advances, 10 (2011) 224-228.
- [25] Ozvarol Z.A.B., Ramazan I., Mortality ratio and stock analysis of Vimba (Vimba vimba tenella (Nordmann, 1840)) population ın Karacaoren I Dam Lake (Burdur-Turkey), Journal of Applied Biological Sciences, 3 (2009) 143-147.
- [26] Becer Z., İkiz R., Investigation of some biological characters of the Vimba (Vimba vimba tenella (Nordmann, 1840)) population in Karacaören I Dam Lake, Turkish Journal of Veterinary & Animal Sciences, 25 (2001) 111-117.
- [27] Diler, A., Becer Z., Chemical composition and meat yield of vimba (Vimba vimba tenella (Nordmann, 1840)) in Karacaören I Dam Lake, Turkish Journal of Veterinary & Animal Sciences, 25 (2001) 87-92.
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- [29] Al-Haidarey M., Hassan F., Al-Kubaisey A., Douabul A., The geoaccumulation index of some heavy metals in Al-Hawizeh Marsh, Iraq, E-Journal of Chemistry, 7 (2010) S157-S162.
- [30] Loska K., Cebula J., Pelczar J., Wiechuła D., KwapulińskiJ., Use of enrichment, and contamination factors together with geoaccumulation indexes to evaluate the content of Cd, Cu, and Ni in the Rybnik water reservoir in Poland, Water, Air, and Soil Pollution, 93 (1997) 347-365.
- [31] Hasan A.B., Kabir S., Reza A.S., Zaman M.N., Ahsan A., Rashid M., Enrichment factor and geo-accumulation index of trace metals in sediments of the ship breaking area of Sitakund Upazilla (Bhatiary–Kumira), Chittagong, Bangladesh, Journal of Geochemical Exploration, 125 (2013) 130-137.
- [32] Krauskoph K., Bird D., Introduction to geochemistry McGraw-Hill Inc, New York, (1995) 647.
- [33] Krauskopf K.B., Bird D.K., Introduction to geochemistry, McGraw-Hill New York, 1967.
- [34] Karadede H., Ünlü E., Concentrations of some heavy metals in water, sediment and fish species from the Atatürk Dam Lake (Euphrates), Turkey, Chemosphere, 41 (2000) 1371-1376.
- [35] Çevik F., Göksu M.Z.L., Derici O.B., Fındık Ö., An assessment of metal pollution in surface sediments of Seyhan dam by using enrichment factor, geoaccumulation index and statistical analyses, Environmental monitoring and assessment, 152 (2009) 309-317.
- [36] Kır I., Tumantozlu H., Investigation of some heavy metal accumulation in water, sediment and carp (Cyprinus carpio) samples of Karacaoren-II Dam Lake, Ekoloji, 21 (2012) 65-70.
- [37] Öztürk M., Özözen G., Minareci O., Minareci E., Determination of heavy metals in fish, water and sediments of Avsar Dam Lake in Turkey, Journal of Environmental Health Science & Engineering, 6 (2009) 73-80.
- [38] Uysal K., Özden Y., Çiçek A., Esengül K., Bioaccumulation ratios of sediment-bound heavy metals of Porsuk and Enne Dam Lakes (Kütahya/Turkey) to different tissues of common carp (Cyprinus carpio), Aquatic Sciences and Engineering, 25 (2010) 1-10.
- [39] Akin B.S., Kırmızıgül O., Heavy metal contamination in surface sediments of Gökçekaya Dam Lake, Eskişehir, Turkey, Environmental Earth Sciences, 76 (2017) 1-11.