Year 2021,
Volume: 42 Issue: 2, 452 - 464, 30.06.2021
İpek Çelen-erdem
,
Gülsüm Ürper
,
Derya Köseoğlu
,
İsmail Koyuncu
,
İzzet Öztürk
Supporting Institution
Toprak Mahsulleri ofisi (TMO)
Thanks
TMO yetkili ve çalışanlarına maddi ve manevi destekleri için teşekkürü bir borç biliriz.
References
- [1] Cengiz N.Ü., Sağlam M., Yüksel M., Ballice L., Treatment of high-strength opium alkaloid wastewater using hydrothermal gasification, J. Supercrit. Fluids, 130 (2017) 301–310.
- [2] Sevimli M.F., Aydın A.F., Sarikaya H.Z., Öztürk İ., Characterization and treatment of effluent from opium alkaloid processing wastewater, Water Sci. Technol., 40 (1999) 23–30.
- [3] Yaniv Z., Dudai N., Medicinal and aromatic plants of the middle-east, Netherlands: Springer, (2014).
- [4] Kınlı H., The report of treatability studies of biological wastewater treatment plant effluent of TMO Opium Alkaloids Plant, Marmara Res. Center, TUBİTAK, Gebze, Türkiye, (1994).
- [5] Ozturk I., Aydin A.F., Koyuncu I., Technical Evaluation Report for Upgrading of Bolvadin Alkaloid Industry Wastewater Treatment Plant, Istanbul Tech. Univ., Istanbul, (2008).
- [6] Sakar H., Balcik Canbolat C., Karagunduz A., Keskinler B., Sulfate removal from nanofiltration concentrate of alkaloid wastewater by electrodialysis, Desalin. Water Treat., 57 (2016) 21003–21014.
- [7] Aytimur G., Atalay S., Treatment of an alkaloid industry wastewater by biological oxidation and/or chemical oxidation, Energy Sources, 26 (2004) 661–670.
- [8] Kaçar Y., Alpay E., Ceylan V.K., Pretreatment of Afyon alcaloide factory’s wastewater by wet air oxidation (WAO), Water Res., 37 (2003) 1170–1176.
- [9] Bural C.B., Demirer G.N., Kantoglu O., Dilek F.B., Treatment of opium alkaloid containing wastewater in sequencing batch reactor (SBR)—Effect of gamma irradiation, Radiat. Phys. Chem., 79 (2010) 519–526.
- [10] Aydin A.F., Ersahin M.E., Dereli R.K., Sarikaya H.Z., Ozturk I., Long-term anaerobic treatability studies on opium alkaloids industry effluents, J. Environ. Sci. Heal. Part A., 45 (2010) 192–200.
- [11] Dereli R.K., Ersahin M.E., Ozgun H., Ozturk I., Aydin A.F., Applicability of Anaerobic Digestion Model No. 1 (ADM1) for a specific industrial wastewater: Opium alkaloid effluents, Chem. Eng. J., 165 (2010) 89–94.
- [12] Koyuncu I., An advanced treatment of high-strength opium alkaloid processing industry wastewaters with membrane technology: Pretreatment, fouling and retention characteristics of membranes, Desalination, 155 (2003) 265–275.
- [13] Koyuncu I., Sevimli M.F., Ozturk I., Aydin A.F., Application of membrane and ozonation technologies to remove color from agro-industry effluents, Water Sci. Technol., 43 (2001) 233–241.
- [14] Gençsoy E.B., Afyon Alkaloidleri Endüstrisi Atıksularının Anaerobik Arıtılması, M.Sc thesis., İstanbul Technical University, (2003).
- [15] A. American Public Health Association, Standard methods for the examination of water and wastewater, American public health association Washington DC, (1995).
- [16] Çelen Erdem İ., Türker M., Çiftçi G., Öztürk İ., Çiftçi T., Afyon Alkoloidleri Endüstrisi Atiksularinin Anaerobik Proseslerle Aritilabilirliği, Mühendislik Bilim. ve Tasarım Derg., 6(3) (2018) 479-486.
- [17] Bouhabila E.H., Ben Aïm R., Buisson H., Microfiltration of activated sludge using submerged membrane with air bubbling (application to wastewater treatment), Desalination, 118 (1998) 315–322.
- [18] Benitez J., Rodríguez A., Malaver R., Stabilization and dewatering of wastewater using hollow fiber membranes, Water Res., 29 (1995) 2281–2286.
- [19] Arévalo J., Ruiz L.M., Parada-Albarracín J.A., González-Pérez D.M., Pérez J., Moreno B., Gómez M.A., Wastewater reuse after treatment by MBR. Microfiltration or ultrafiltration?, Desalination, 299 (2012) 22–27.
- [20] Domínguez L., Cases V., Birek C., Rodríguez M., Prats D., Influence of organic loading rate on the performance of ultrafiltration and microfiltration membrane bioreactors at high sludge retention time, Chem. Eng. J., 181 (2012) 132–143.
- [21] Hacıfazlıoğlu M.C., Tomasini H.R., Kabay N., Bertin L., Pek T., Kitiş M., Yiğit N., Yüksel M., Effect of pressure on desalination of MBR effluents with high salinity by using NF and RO processes for reuse in irrigation, J. Water Process Eng., 25 (2018) 22–27.
- [22] Insel G., Karagunduz A., Aksel M., Cokgor E., Kor-Bicakci G., Ozyildiz G., Toroz I., Keskinler B., Membrane integrated process for advances treatment of high strength opium alkalois wastewaters, Wat. Sci.Technol., 77(7) (2018) 1899-1908.
Optimization of operational parameters at laboratory scale membrane bioreactor for treatment of high-strength opium alkaloid wastewater: The effect of pretreatment
Year 2021,
Volume: 42 Issue: 2, 452 - 464, 30.06.2021
İpek Çelen-erdem
,
Gülsüm Ürper
,
Derya Köseoğlu
,
İsmail Koyuncu
,
İzzet Öztürk
Abstract
Two different membrane treatment scenarios have been applied for treatment of the high strength dark color alkaloid industry wastewater. A membrane bioreactor (MBR) system having separately UF and MF membranes was operated with raw alkaloid wastewater treatment (scenario-A) and anaerobically pre-treated alkaloid wastewater (scenario-B). NF 270, NF 90 and RO (XLE) membranes were used as a polish-ing step at two different recovery ratios of 50% and 75% for both scenarios. In scenario-A, the COD re-moval efficiencies for MBR-MF and MBR-UF were found as 86±9% and 55±24%, respectively. At the polishing step, RO performance after scenario-A indicated that the 99.6% COD and complete color remov-al was achieved. On the other hand, in the scenario-B, the COD removal efficiencies for MBR-MF and MBR-UF were found as 41±16.4% and 24±18.3%, respectively. RO experiments with raw wastewater indi-cated that the 99.6% COD and complete color removal were achieved. The most crucial problem during direct MBR operation was found as a foaming problem and prevented by anti-foaming agent which caused an increase in effluent COD concentration and chemical cost. For these reasons, it can be concluded that MBR operation with anaerobically pre-treated was more effective than the other scenario.
References
- [1] Cengiz N.Ü., Sağlam M., Yüksel M., Ballice L., Treatment of high-strength opium alkaloid wastewater using hydrothermal gasification, J. Supercrit. Fluids, 130 (2017) 301–310.
- [2] Sevimli M.F., Aydın A.F., Sarikaya H.Z., Öztürk İ., Characterization and treatment of effluent from opium alkaloid processing wastewater, Water Sci. Technol., 40 (1999) 23–30.
- [3] Yaniv Z., Dudai N., Medicinal and aromatic plants of the middle-east, Netherlands: Springer, (2014).
- [4] Kınlı H., The report of treatability studies of biological wastewater treatment plant effluent of TMO Opium Alkaloids Plant, Marmara Res. Center, TUBİTAK, Gebze, Türkiye, (1994).
- [5] Ozturk I., Aydin A.F., Koyuncu I., Technical Evaluation Report for Upgrading of Bolvadin Alkaloid Industry Wastewater Treatment Plant, Istanbul Tech. Univ., Istanbul, (2008).
- [6] Sakar H., Balcik Canbolat C., Karagunduz A., Keskinler B., Sulfate removal from nanofiltration concentrate of alkaloid wastewater by electrodialysis, Desalin. Water Treat., 57 (2016) 21003–21014.
- [7] Aytimur G., Atalay S., Treatment of an alkaloid industry wastewater by biological oxidation and/or chemical oxidation, Energy Sources, 26 (2004) 661–670.
- [8] Kaçar Y., Alpay E., Ceylan V.K., Pretreatment of Afyon alcaloide factory’s wastewater by wet air oxidation (WAO), Water Res., 37 (2003) 1170–1176.
- [9] Bural C.B., Demirer G.N., Kantoglu O., Dilek F.B., Treatment of opium alkaloid containing wastewater in sequencing batch reactor (SBR)—Effect of gamma irradiation, Radiat. Phys. Chem., 79 (2010) 519–526.
- [10] Aydin A.F., Ersahin M.E., Dereli R.K., Sarikaya H.Z., Ozturk I., Long-term anaerobic treatability studies on opium alkaloids industry effluents, J. Environ. Sci. Heal. Part A., 45 (2010) 192–200.
- [11] Dereli R.K., Ersahin M.E., Ozgun H., Ozturk I., Aydin A.F., Applicability of Anaerobic Digestion Model No. 1 (ADM1) for a specific industrial wastewater: Opium alkaloid effluents, Chem. Eng. J., 165 (2010) 89–94.
- [12] Koyuncu I., An advanced treatment of high-strength opium alkaloid processing industry wastewaters with membrane technology: Pretreatment, fouling and retention characteristics of membranes, Desalination, 155 (2003) 265–275.
- [13] Koyuncu I., Sevimli M.F., Ozturk I., Aydin A.F., Application of membrane and ozonation technologies to remove color from agro-industry effluents, Water Sci. Technol., 43 (2001) 233–241.
- [14] Gençsoy E.B., Afyon Alkaloidleri Endüstrisi Atıksularının Anaerobik Arıtılması, M.Sc thesis., İstanbul Technical University, (2003).
- [15] A. American Public Health Association, Standard methods for the examination of water and wastewater, American public health association Washington DC, (1995).
- [16] Çelen Erdem İ., Türker M., Çiftçi G., Öztürk İ., Çiftçi T., Afyon Alkoloidleri Endüstrisi Atiksularinin Anaerobik Proseslerle Aritilabilirliği, Mühendislik Bilim. ve Tasarım Derg., 6(3) (2018) 479-486.
- [17] Bouhabila E.H., Ben Aïm R., Buisson H., Microfiltration of activated sludge using submerged membrane with air bubbling (application to wastewater treatment), Desalination, 118 (1998) 315–322.
- [18] Benitez J., Rodríguez A., Malaver R., Stabilization and dewatering of wastewater using hollow fiber membranes, Water Res., 29 (1995) 2281–2286.
- [19] Arévalo J., Ruiz L.M., Parada-Albarracín J.A., González-Pérez D.M., Pérez J., Moreno B., Gómez M.A., Wastewater reuse after treatment by MBR. Microfiltration or ultrafiltration?, Desalination, 299 (2012) 22–27.
- [20] Domínguez L., Cases V., Birek C., Rodríguez M., Prats D., Influence of organic loading rate on the performance of ultrafiltration and microfiltration membrane bioreactors at high sludge retention time, Chem. Eng. J., 181 (2012) 132–143.
- [21] Hacıfazlıoğlu M.C., Tomasini H.R., Kabay N., Bertin L., Pek T., Kitiş M., Yiğit N., Yüksel M., Effect of pressure on desalination of MBR effluents with high salinity by using NF and RO processes for reuse in irrigation, J. Water Process Eng., 25 (2018) 22–27.
- [22] Insel G., Karagunduz A., Aksel M., Cokgor E., Kor-Bicakci G., Ozyildiz G., Toroz I., Keskinler B., Membrane integrated process for advances treatment of high strength opium alkalois wastewaters, Wat. Sci.Technol., 77(7) (2018) 1899-1908.