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Orange Emitting SrS: Eu2+, Dy3+ Afterglow Phosphor: Structural and Luminescence Properties

Year 2024, , 394 - 399, 30.06.2024
https://doi.org/10.17776/csj.1408773

Abstract

SrS:Eu is known as an attractive material for imaging, scintillator, or persistent phosphor applications, thanks to its effective photoluminescence (PL) and thermoluminescence (TL) capabilities, but there are still great mysteries of persistent phosphors and attract great interest. Hence, this work investigated the luminescence properties of well-known persistent phosphor based on SrS using various spectroscopic techniques for detailed characterization. Measurements using X-ray photoelectron spectroscopy (XPS) and X-ray diffraction (XRD) were used to analyze the phase and elements of the phosphor. Belongs to the XRD data the microcrystalline phosphor is cubic, and the diameters ranged from 1 to 100 µm. The morphology of the phosphor was examined by scanning electron microscope (SEM). A time-resolved PL system recorded PL properties, namely the emission and excitation spectra of the phosphor. SrS emits around 626 nm with a broad excitation band peaking around 466 nm. A TLD reader system measured the TL glow curve of the phosphors after UVB radiation. The TL glow curve exhibited a broad peak around 160oC. The dose-response of this peak was obtained up to 600 seconds of exposure to UVB radiation, and it was observed that the dose-response curve exhibits a saturating exponential behavior.

References

  • [1] Dos Santos D., Giordano L., Barbara M., Portes M., Pedroso C., Teixeira V., Lastusaari M., L. Rodrigues, Abnormal Co-doping Effect on The Red Persistent Luminescence SrS: Eu2+, RE3+ Materials, Dalton Transactions, 45 (2020) 16386-16393.
  • [2] Roa R. P., The Preparation and Thermoluminescence of Alkaline Earth Sulfide Phosphors, Journal of Materials Science, 21 (1986) 3357-3386.
  • [3] Duan X., Huang S., You F., Kang K., Hydrothermal Preparation and Persistence Characteristics of Nanosized Phosphor SrS: Eu2+, Dy3+, Journal of Rare Earths, 27 (1) (2009) 43.
  • [4] Vij A., Lochabb S., Singha S., Kumar R., Singh N., Thermoluminescence Study of UV Irradiated Ce doped SrS Nanostructures, Journal of Alloys and Compounds, 486 (2009) 554-558.
  • [5] Kojima Y., Takahashi A., Umegaki T., Synthesis of Orange-red-emitting Eu2+, Pr3+ Codoped SrS Long Afterglow Phosphor, Journal of Luminescence, 146 (2014) 42-45.
  • [6] Summers C. J., Wagner B. K., Tong W., Chaichimansour M., Xin Y. B., Recent Progress in The Development of Full Color SrS-Based Electroluminescent Phosphors, Journal of Crystal Growth, 214-215 (2000) 918-925.
  • [7] Khare A., Mishra S., Kshatri D., Tiwari S., Optical Properties of Rare Earth Doped SrS Phosphor: A Review, Journal of Electronic Materials, 46, (2), (2017) 687-708.
  • [8] Shao S., Du K., Huang K., Cheng L., Mi X., Peng Z., Lin H., Cui S., Lin T., Ba Z.and Zhang X., Rapid Synthesis and Characterization of SrS: Eu, Sm Infrared Up-Conversion Materials, Advance Powder Technology, 25 (2014) 1516-1519.
  • [9] Hu R., Zhang Y., Zhao Y., Wang X., Li G., Wang C., UV–Vis-NIR Broadband-Photo Stimulated Luminescence of LiTaO3:Bi3+ Long-Persistent Phosphor and The Optical Storage Properties, Chemical Engineering Journal, 392 (2020) 124807.
  • [10] Kong M., Fang M., Liu M., Shang G. L., Fei G. T., Zhang L., The Investigation on The Mechanism of The Increased Decay Time in Red SrS: Eu2+, Dy3+ Phosphor, Materials Chemistry and Physics, 207 (2018) 161-166.
  • [11] Parmentier A., Joos J., Smet P., Poelman D., Luminescence of Ytterbium in CaS and SrS, Journal of Luminescence, 154 (2014) 445-451.
  • [12] Singh V., Tiwari M., Dhoble S., Luminescence studies of SrS and CaS based Phosphors, Indian Journal of Pure & Applied Physics, 43 (2005). 1000-1003.
  • [13] Dobrowolska A., Karsu E. C., Bos A. J.J., Dorenbos P., Spectroscopy, thermoluminescence and afterglow studies of CaLa4(SiO4)3O: Ln (Ln=Ce,Nd,Eu,Tb,Dy), Journal of Luminescence, 160 (2015) 321-327.
Year 2024, , 394 - 399, 30.06.2024
https://doi.org/10.17776/csj.1408773

Abstract

References

  • [1] Dos Santos D., Giordano L., Barbara M., Portes M., Pedroso C., Teixeira V., Lastusaari M., L. Rodrigues, Abnormal Co-doping Effect on The Red Persistent Luminescence SrS: Eu2+, RE3+ Materials, Dalton Transactions, 45 (2020) 16386-16393.
  • [2] Roa R. P., The Preparation and Thermoluminescence of Alkaline Earth Sulfide Phosphors, Journal of Materials Science, 21 (1986) 3357-3386.
  • [3] Duan X., Huang S., You F., Kang K., Hydrothermal Preparation and Persistence Characteristics of Nanosized Phosphor SrS: Eu2+, Dy3+, Journal of Rare Earths, 27 (1) (2009) 43.
  • [4] Vij A., Lochabb S., Singha S., Kumar R., Singh N., Thermoluminescence Study of UV Irradiated Ce doped SrS Nanostructures, Journal of Alloys and Compounds, 486 (2009) 554-558.
  • [5] Kojima Y., Takahashi A., Umegaki T., Synthesis of Orange-red-emitting Eu2+, Pr3+ Codoped SrS Long Afterglow Phosphor, Journal of Luminescence, 146 (2014) 42-45.
  • [6] Summers C. J., Wagner B. K., Tong W., Chaichimansour M., Xin Y. B., Recent Progress in The Development of Full Color SrS-Based Electroluminescent Phosphors, Journal of Crystal Growth, 214-215 (2000) 918-925.
  • [7] Khare A., Mishra S., Kshatri D., Tiwari S., Optical Properties of Rare Earth Doped SrS Phosphor: A Review, Journal of Electronic Materials, 46, (2), (2017) 687-708.
  • [8] Shao S., Du K., Huang K., Cheng L., Mi X., Peng Z., Lin H., Cui S., Lin T., Ba Z.and Zhang X., Rapid Synthesis and Characterization of SrS: Eu, Sm Infrared Up-Conversion Materials, Advance Powder Technology, 25 (2014) 1516-1519.
  • [9] Hu R., Zhang Y., Zhao Y., Wang X., Li G., Wang C., UV–Vis-NIR Broadband-Photo Stimulated Luminescence of LiTaO3:Bi3+ Long-Persistent Phosphor and The Optical Storage Properties, Chemical Engineering Journal, 392 (2020) 124807.
  • [10] Kong M., Fang M., Liu M., Shang G. L., Fei G. T., Zhang L., The Investigation on The Mechanism of The Increased Decay Time in Red SrS: Eu2+, Dy3+ Phosphor, Materials Chemistry and Physics, 207 (2018) 161-166.
  • [11] Parmentier A., Joos J., Smet P., Poelman D., Luminescence of Ytterbium in CaS and SrS, Journal of Luminescence, 154 (2014) 445-451.
  • [12] Singh V., Tiwari M., Dhoble S., Luminescence studies of SrS and CaS based Phosphors, Indian Journal of Pure & Applied Physics, 43 (2005). 1000-1003.
  • [13] Dobrowolska A., Karsu E. C., Bos A. J.J., Dorenbos P., Spectroscopy, thermoluminescence and afterglow studies of CaLa4(SiO4)3O: Ln (Ln=Ce,Nd,Eu,Tb,Dy), Journal of Luminescence, 160 (2015) 321-327.
There are 13 citations in total.

Details

Primary Language English
Subjects Material Physics
Journal Section Natural Sciences
Authors

Eren Cihan Karsu Asal 0000-0001-6392-2668

Serdar Yıldırım 0000-0002-3730-3473

Publication Date June 30, 2024
Submission Date December 23, 2023
Acceptance Date March 1, 2024
Published in Issue Year 2024

Cite

APA Karsu Asal, E. C., & Yıldırım, S. (2024). Orange Emitting SrS: Eu2+, Dy3+ Afterglow Phosphor: Structural and Luminescence Properties. Cumhuriyet Science Journal, 45(2), 394-399. https://doi.org/10.17776/csj.1408773