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Efficient Methanol Electro-oxidation on Ni, S Dual Doped Reduced Graphene Layer Catalyst

Year 2023, , 697 - 702, 28.12.2023

Rukan Suna Karatekin , Sedef Kaplan

https://doi.org/10.17776/csj.1278386

Abstract

Energy crisis is the most popular issue in the world, which must be overcome with the development of alternative energy sources. Among them, methanol is a promising fuel when used in direct methanol fuel cells. However, the mentioned cell needs highly electroactive and stable anode materials toward MeOH. Ni has gained attention as it is an alternative to noble atoms. In this study, Ni was deposited on reduced graphene layer which functionalized with S atoms via the hydrothermal method. The fabricated sample was characterized by using Scanning Electron Microscopy (SEM), Energy Dispersive X-ray Spectroscopy (EDX), mapping, X-ray Powder Diffraction (XRD), and Brunauer–Emmett–Teller method (BET). Two samples as called Ni/GCE and Ni@s-rGO/GCE were examined for methanol oxidation reaction in alkaline media. For methanol oxidation, due to the higher surface area, and small particle size of Ni, the mass activity of Ni@s-rGO/GCE is two times higher than Ni/GCE

Keywords

methanol oxidation s-doped reduced graphene Ni nanoparticles.

References

  • [1] Mei J., Hou G., Zhang H., Chen Q., Cao H., Tang Y., Zhang J., Zheng G., Convenient construction of porous dendritic Cu-doped Ni@PPy/stainless steel mesh electrode for oxidation of methanol and urea, Applied Surface Science, 623 (2023) 156930.
  • [2] Mahapatra S.S., Datta J., Characterization of Pt-Pd/C Electrocatalyst for Methanol Oxidation in Alkaline Medium, International Journal of Electrochemistry, (2011) 563495.
  • [3] Wu D., Albert M., Soldan A., Pettigrew C., Oishi K., Tomogane Y., Ye C., Ma T., Miller M.I., Mori S., Multi-atlas based detection and localization (MADL) for location-dependent quantification of white matter hyperintensities, NeuroImage: Clinical, 22 (2019) 101772.
  • [4] Liu C., Yang F., Schechter A., Feng L., Recent progress of Ni-based catalysts for methanol electrooxidation reaction in alkaline media, Advanced Sensor and Energy Materials, 2 (2023) 100055.
  • [5] Samimi G., Ashrafi H., Tashkhourian J., Haghighi B., rGO@Ni/NiO composite an effective electrocatalyst for methanol oxidation reaction in alkaline media, Journal of Physics and Chemistry of Solids, 184 (2024) 111724.
  • [6] Wang J., Zhao Q., Hou H., Wu Y., Yu W., Ji X., Shao L. Nickel nanoparticles supported on nitrogen-doped honeycomb-like carbon frameworks for effective methanol oxidation, RSC Advances, 7 (2017) 14152–14158.
  • [7] Sun H., Ye Y., Liu J., Tian Z., Cai Y., Li P., Liang C., Pure Ni nanocrystallines anchored on rGO present ultrahigh electrocatalytic activity and stability in methanol oxidation, The Royal Society of Chemistry,54 (2018) 1563-1566.
  • [8] Raluca Tarcan R., Todor-Boer O., Petrovai I., Leordean C., Astilean S., Botiz I., Reduced graphene oxide today, The Royal Society of Chemistry, 8 (2020) 1198-1224.
  • [9] Sundaram R.S., Chemically derived graphene, Graphene. Cambridge: Elsevier, (2014) 50-80.
  • [10] Hummers W.S., Offeman R.E., Preparation of Graphitic Oxide, . Am. Chem. Soc, 80 (1958) 1339.
  • [11] Kaplan S., Suna Karateki̇n R., Kahya Dudukcu M., Avcı G., A novel Ni-Fe3O4@s-rGO/GCE electrode for electrochemical detection of H2O2, Materials Chemistry and Physics, 294 (2023) 127051.
  • [12] Taghizadeh F., The study of structural and magnetic properties of NiO nanoparticles, Optics and Photonics Journal, 6 (2016) 164-169.
  • [13] Kumar P R., Prasad N., Veillon F., Prellier W., Raman spectroscopic and magnetic properties of Europium doped nickel oxide nanoparticles prepared by microwave-assisted hydrothermal method, Journal of Alloys and Compounds, 858 (2021) 157639.
  • [14] Suna Karatekin R., Kaya D., Kaplan S., Kahya Düdükcü M., Effect of the configurations of N and S atoms on electrochemical performance of Pt for methanol oxidation, Journal of Nanoparticle Research, 24 (2022) 233.
  • [15] Suna Karatekin R., Kaplan S., Ildan Ozmen S., Kahya Düdükcü M., Enhanced methanol oxidation on N-doped reduced graphene oxide/ZnO/nano-Pt catalyst, Diamond & Related Materials, 127 (2022) 109145.
  • [16] Karazehir T., Electrodeposited Pd nanoparticles on polypyrole/nickel foam for efficient methanol oxidation, International Journal of Hydrogen Energy, 48 (2023) 10493-10506.

Year 2023, , 697 - 702, 28.12.2023

Rukan Suna Karatekin , Sedef Kaplan

https://doi.org/10.17776/csj.1278386

Abstract

References

  • [1] Mei J., Hou G., Zhang H., Chen Q., Cao H., Tang Y., Zhang J., Zheng G., Convenient construction of porous dendritic Cu-doped Ni@PPy/stainless steel mesh electrode for oxidation of methanol and urea, Applied Surface Science, 623 (2023) 156930.
  • [2] Mahapatra S.S., Datta J., Characterization of Pt-Pd/C Electrocatalyst for Methanol Oxidation in Alkaline Medium, International Journal of Electrochemistry, (2011) 563495.
  • [3] Wu D., Albert M., Soldan A., Pettigrew C., Oishi K., Tomogane Y., Ye C., Ma T., Miller M.I., Mori S., Multi-atlas based detection and localization (MADL) for location-dependent quantification of white matter hyperintensities, NeuroImage: Clinical, 22 (2019) 101772.
  • [4] Liu C., Yang F., Schechter A., Feng L., Recent progress of Ni-based catalysts for methanol electrooxidation reaction in alkaline media, Advanced Sensor and Energy Materials, 2 (2023) 100055.
  • [5] Samimi G., Ashrafi H., Tashkhourian J., Haghighi B., rGO@Ni/NiO composite an effective electrocatalyst for methanol oxidation reaction in alkaline media, Journal of Physics and Chemistry of Solids, 184 (2024) 111724.
  • [6] Wang J., Zhao Q., Hou H., Wu Y., Yu W., Ji X., Shao L. Nickel nanoparticles supported on nitrogen-doped honeycomb-like carbon frameworks for effective methanol oxidation, RSC Advances, 7 (2017) 14152–14158.
  • [7] Sun H., Ye Y., Liu J., Tian Z., Cai Y., Li P., Liang C., Pure Ni nanocrystallines anchored on rGO present ultrahigh electrocatalytic activity and stability in methanol oxidation, The Royal Society of Chemistry,54 (2018) 1563-1566.
  • [8] Raluca Tarcan R., Todor-Boer O., Petrovai I., Leordean C., Astilean S., Botiz I., Reduced graphene oxide today, The Royal Society of Chemistry, 8 (2020) 1198-1224.
  • [9] Sundaram R.S., Chemically derived graphene, Graphene. Cambridge: Elsevier, (2014) 50-80.
  • [10] Hummers W.S., Offeman R.E., Preparation of Graphitic Oxide, . Am. Chem. Soc, 80 (1958) 1339.
  • [11] Kaplan S., Suna Karateki̇n R., Kahya Dudukcu M., Avcı G., A novel Ni-Fe3O4@s-rGO/GCE electrode for electrochemical detection of H2O2, Materials Chemistry and Physics, 294 (2023) 127051.
  • [12] Taghizadeh F., The study of structural and magnetic properties of NiO nanoparticles, Optics and Photonics Journal, 6 (2016) 164-169.
  • [13] Kumar P R., Prasad N., Veillon F., Prellier W., Raman spectroscopic and magnetic properties of Europium doped nickel oxide nanoparticles prepared by microwave-assisted hydrothermal method, Journal of Alloys and Compounds, 858 (2021) 157639.
  • [14] Suna Karatekin R., Kaya D., Kaplan S., Kahya Düdükcü M., Effect of the configurations of N and S atoms on electrochemical performance of Pt for methanol oxidation, Journal of Nanoparticle Research, 24 (2022) 233.
  • [15] Suna Karatekin R., Kaplan S., Ildan Ozmen S., Kahya Düdükcü M., Enhanced methanol oxidation on N-doped reduced graphene oxide/ZnO/nano-Pt catalyst, Diamond & Related Materials, 127 (2022) 109145.
  • [16] Karazehir T., Electrodeposited Pd nanoparticles on polypyrole/nickel foam for efficient methanol oxidation, International Journal of Hydrogen Energy, 48 (2023) 10493-10506.
There are 16 citations in total.

Details

Primary Language English
Subjects Chemical Engineering
Journal Section Natural Sciences
Authors

Rukan Suna Karatekin 0000-0003-3052-1539

Sedef Kaplan 0000-0002-3345-1452

Publication Date December 28, 2023
Submission Date April 6, 2023
Acceptance Date November 14, 2023
Published in Issue Year 2023

Cite

APA Suna Karatekin, R., & Kaplan, S. (2023). Efficient Methanol Electro-oxidation on Ni, S Dual Doped Reduced Graphene Layer Catalyst. Cumhuriyet Science Journal, 44(4), 697-702. https://doi.org/10.17776/csj.1278386