Interference-free determination of carmine in food samples using ultrasonic assisted cloud point extraction coupled with spectrophotometry

Adil Elik

doi:10.17776/csj.486753

EN TR

Interference-free determination of carmine in food samples using ultrasonic assisted cloud point extraction coupled with spectrophotometry

Abstract

In this study, a simple, green and cost effective method of extraction and preconcentration of carmine used as a food additive in some food samples was developed using ultrasonic assisted cloud point extraction (UA-CPE) before spectrophotometric determination. Carmine was extracted from the aqueous solution using polyoxyethylenesorbitan monolaurate (Tween 20) as the extraction solvent in presence of Ni(II) at pH 6.5. Variables such as pH, amount of metal, temperature, ultrasonic effect, solvent type, type and concentration of nanionic surfactant have been optimized in detail. Under the optimum conditions, the analytical characteristics of the method are as follows; linear working range 1.5-350 μg L^-1; the detection limit, 0.4 μg L^-1; and preconcentration factor, 80. The relative standard deviation (RSD%) obtained for the 10 μg L^-1 concentration (n: 5) of carmine was 3.7%. Recovery values for two different concentration levels were in the range of 94.8-104.7%. The accuracy and precision of the method were evaluated by intra- and inter-day studies. Finally, the method has been successfully applied to the determination of carmine in various foods.

Keywords

Carmine,food samples,ultrasound assisted extraction,green chemistry,spectrophotometry

References

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Details

Primary Language

English

Subjects

-

Journal Section

Research Article

Authors

Adil Elik ^*
0000-0002-3942-4711
Türkiye

Publication Date

June 30, 2019

Submission Date

November 22, 2018

Acceptance Date

February 4, 2019

Published in Issue

Year 2019 Volume: 40 Number: 2

DOI

https://doi.org/10.17776/csj.486753

IZ

https://izlik.org/JA39MR46PM

Cite

RIS / Bibtex

APA

Elik, A. (2019). Interference-free determination of carmine in food samples using ultrasonic assisted cloud point extraction coupled with spectrophotometry. Cumhuriyet Science Journal, 40(2), 305-316. https://doi.org/10.17776/csj.486753

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Interference-free determination of carmine in food samples using ultrasonic assisted cloud point extraction coupled with spectrophotometry

Interference-free determination of carmine in food samples using ultrasonic assisted cloud point extraction coupled with spectrophotometry

Abstract

Keywords

Spektrofotometri ile birleştirilmiş ultrasonik destekli bulutlanma noktası ekstraksiyonu kullanılarak gıda örneklerinde karminin girişimsiz tayini

Öz

Anahtar Kelimeler

References

Details

Primary Language

Subjects

Journal Section

Authors

Publication Date

Submission Date

Acceptance Date

Published in Issue

DOI

IZ

Cite

Cited By

An optimization approach for fast, simple and accurate determination of indigo-carmine in food samples

Ultrasonic-assisted cloud point microextraction and spectrophotometric determination of Ponceau 4R in various beverage samples using Non-ionic surfactant PONPE 7.5

Chemometric-Based Optimization of Ionic Liquid-Based Dispersive Liquid-Liquid Microextraction for Separation and Preconcentration of Erythrosine from Real Matrices

A rapid colorimetric method for the detection of carminic acid in samples based on visible color change

Preparation and investigation of green and cheap deep eutectic solvents for determination of essential and toxic metal ions at trace levels in different coffee products