Determination of Trace Levels of Nitrite in Beverages Samples Through Micellar Improved Catalytic Kinetic Spectrophotometry

Adil Elik; Nail Altunay; Ramazan Gürkan

doi:10.17776/csj.340413

TR EN

Misel İyileştirilmiş Katalitik Kinetik Spektrofotometri Aracılığıyla İçecek Örneklerinde Eser Düzeylerdeki Nitritin Belirlenmesi

Öz

Bu çalışmada nitrite tayini için basit ve hassas bir katalitik kinetik spektrofotometre yöntemi anlatılmıştır. Yöntemin temeli, asitli ortamda (520 nm'de emiliminde azalma olur) karışık yüzeyaktif maddeler varlığında nitrit ile klorpromazinin oksidasyonuna dayanır. Çeşitli kimyasal (asitlik etkisi, reaktif konsantrasyonları gibi) ve enstrümantal parametreler (zaman, numune hacmi ve sıcaklık) optimize edilmiştir. Çeşitli kimyasal türlerin girişim etkileri incelendi. Optimum koşullarda, doğrusal kalibrasyon grafiği, 2.5-125 μg L^-1 nitrit derişimi aralıklarında doğrusal idi. Nitrit için tespit limiti 0.71 μg L^-1 'dir. Nitritin 25 ve 75 μg L^-1 derişimleri için göreceli standart sapma değerleri sırasıyla % 3.40 ve % 2.35 dir. Misel geliştirilmiş katalitik kinetik spektrofotometri, iyi hassasiyet, tekrarlanabilirlik, kararlılık ve nitrite seçicilik de dahil olmak üzere iyi analitik performans göstermiştir. Yöntemin, içecek örneklerine uygulanması sonucu % 97.3-103.8 aralığında tatmin edici geri kazanım değerleri elde edilmiştir. Sonuç olarak, önerilen yöntemin gıda güvenliği için umut verici bir uygulama olduğunu göstermektedir.

Anahtar Kelimeler

Klorpromazin,Nitrit,Katalitik Kinetik,Yüzey Aktif Maddeler,Spektrofotometri,İçecek Örnekleri

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Details

Primary Language

English

Subjects

-

Journal Section

Research Article

Authors

Adil Elik
Türkiye

Nail Altunay
Türkiye

Ramazan Gürkan
Türkiye

Publication Date

September 30, 2017

Submission Date

May 15, 2017

Acceptance Date

June 5, 2017

Published in Issue

Year 1970 Volume: 38 Number: 3

DOI

https://doi.org/10.17776/csj.340413

IZ

https://izlik.org/JA38GZ33AP

Cite

RIS / Bibtex

APA

Elik, A., Altunay, N., & Gürkan, R. (2017). Determination of Trace Levels of Nitrite in Beverages Samples Through Micellar Improved Catalytic Kinetic Spectrophotometry. Cumhuriyet Science Journal, 38(3), 400-411. https://doi.org/10.17776/csj.340413

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Determination of Trace Levels of Nitrite in Beverages Samples Through Micellar Improved Catalytic Kinetic Spectrophotometry

Misel İyileştirilmiş Katalitik Kinetik Spektrofotometri Aracılığıyla İçecek Örneklerinde Eser Düzeylerdeki Nitritin Belirlenmesi

Öz

Anahtar Kelimeler