Spectrometric Determination of Manganese in Spring Waters after Rapidly Synergistic Cloud Point Extraction

Hasan Pınar; Nuket Kartal Temel

doi:10.17776/csj.1737815

Spectrometric Determination of Manganese in Spring Waters after Rapidly Synergistic Cloud Point Extraction

Abstract

In this study, the rapidly synergistic cloud point extraction (RS-CPE) method, which is an improved version of cloud point extraction (CPE), has been used. Based on this method, spectrometric determination (the flame atomic absorption spectrometry (FAAS)) of the manganese (Mn) was carried out in Sivas hot spring water (HSW) and in cold spring water (CSW) after extraction in the presence of synergistic reagent and a complexing agent. The effect of pH, amount of surfactant, amount of complexing agent, amount of synergistic cloud point regulator and solvent species used to reduce the viscosity of the organic phase on extraction were investigated. Optimum conditions were found to be 7.00; 6.90 for pH, 0.15%; 0.18% (v/v) for surfactant, 7.07×10^-5; 8.08×10^-5mol L^-1for complexing agent, 0.8; 0.6 mL for synergistic cloud point regulator HSW and CSW, respectively. It was also found to be methanol solution for solvent type (1.0 mol L^-1 with nitric acid), HSW and CSW, respectively. Matrix-compatible calibration was determined at a range of 2-120; 3-120 μg L^-1 with a detection limit of 0.56; 0.87 μg L¹, HSW and CSW, respectively. A sensitization improvement of 109.1; 105.5 after enrichment resulted in a preconcentration factor of 40 for the 40.0 mL sample HSW and CSW, respectively. After the addition of 50.0 μg L^-1 manganese to the matrix, the precision was 3.15% and 3.8% and recovery of the five replicate measurements and 97.2%; 96.5%, HSW and CSW, respectively. The soluble Mn concentration was 85.2; 32.7 μg L^-1 from the sample analysis performed under optimum conditions, HSW and CSW, respectively

Keywords

Supporting Institution

No

Project Number

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Ethical Statement

No

References

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Details

Primary Language

English

Subjects

Analytical Spectrometry

Journal Section

Research Article

Authors

Hasan Pınar ^*
0009-0004-5013-4303
Türkiye

Nuket Kartal Temel
0000-0002-3539-4930
Türkiye

Publication Date

February 27, 2026

Submission Date

July 8, 2025

Acceptance Date

February 3, 2026

Published in Issue

Year 2026 Volume: 47 Number: 1

DOI

https://doi.org/10.17776/csj.1737815

IZ

https://izlik.org/JA43AC96BK

Cite

RIS / Bibtex

APA

Pınar, H., & Kartal Temel, N. (2026). Spectrometric Determination of Manganese in Spring Waters after Rapidly Synergistic Cloud Point Extraction. Cumhuriyet Science Journal, 47(1), 110-118. https://doi.org/10.17776/csj.1737815