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Spectrometric Determination of Manganese in Spring Waters after Rapidly Synergistic Cloud Point Extraction

Year 2026, Volume: 47 Issue: 1, 110 - 118, 27.02.2026

Hasan Pınar , Nuket Kartal Temel

https://doi.org/10.17776/csj.1737815
https://izlik.org/JA43AC96BK

Abstract

In this study, the rapidly synergistic cloud point extraction (RS-CPE) method, which is an improved version of cloud point extraction (CPE), has been used. Based on this method, spectrometric determination (the flame atomic absorption spectrometry (FAAS)) of the manganese (Mn) was carried out in Sivas hot spring water (HSW) and in cold spring water (CSW) after extraction in the presence of synergistic reagent and a complexing agent. The effect of pH, amount of surfactant, amount of complexing agent, amount of synergistic cloud point regulator and solvent species used to reduce the viscosity of the organic phase on extraction were investigated. Optimum conditions were found to be 7.00; 6.90 for pH, 0.15%; 0.18% (v/v) for surfactant, 7.07×10-5; 8.08×10-5mol L-1 for complexing agent, 0.8; 0.6 mL for synergistic cloud point regulator HSW and CSW, respectively. It was also found to be methanol solution for solvent type (1.0 mol L-1 with nitric acid), HSW and CSW, respectively. Matrix-compatible calibration was determined at a range of 2-120; 3-120 μg L-1 with a detection limit of 0.56; 0.87 μg L1, HSW and CSW, respectively. A sensitization improvement of 109.1; 105.5 after enrichment resulted in a preconcentration factor of 40 for the 40.0 mL sample HSW and CSW, respectively. After the addition of 50.0 μg L-1 manganese to the matrix, the precision was 3.15% and 3.8% and recovery of the five replicate measurements and 97.2%; 96.5%, HSW and CSW, respectively. The soluble Mn concentration was 85.2; 32.7 μg L-1 from the sample analysis performed under optimum conditions, HSW and CSW, respectively

 

 

 

Keywords

Cloud point extraction Manganese Rapidly synergistic Spectrometric Spring water

Ethical Statement

No

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References

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There are 34 citations in total.

Details

Primary Language English
Subjects Analytical Spectrometry
Journal Section Research Article
Authors

Hasan Pınar 0009-0004-5013-4303

Nuket Kartal Temel 0000-0002-3539-4930

Project Number no
Submission Date July 8, 2025
Acceptance Date February 3, 2026
Publication Date February 27, 2026
DOI https://doi.org/10.17776/csj.1737815
IZ https://izlik.org/JA43AC96BK
Published in Issue Year 2026 Volume: 47 Issue: 1

Cite

APA Pınar, H., & Kartal Temel, N. (2026). Spectrometric Determination of Manganese in Spring Waters after Rapidly Synergistic Cloud Point Extraction. Cumhuriyet Science Journal, 47(1), 110-118. https://doi.org/10.17776/csj.1737815

As of 2026, Cumhuriyet Science Journal will be published in six issues per year, released in February, April, June, August, October, and December