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Polydopamine-mediated facile Silver grown on ZnO Thin Films as High Performance SERS Substrates for R6G Detection

Year 2024, Volume: 45 Issue: 2, 352 - 359, 30.06.2024

Sami Pekdemir

https://doi.org/10.17776/csj.1351460

Abstract

Surface-enhanced Raman spectroscopy (SERS) is a widely known technique that uses plasmonic structures (silver, gold, etc.) to detect low-concentration molecules. However, the limited number of metallic elements with plasmonic properties leads to limitations in their application. The qualitative detection method of SERS holds considerable promise in providing novel platforms for diverse applications, owing to its utilization of hybrid structures. Mussel-inspired polydopamine offers a promising avenue for the fabrication and integration of hybrid structures suitable for the SERS platform. Here, sputtered ZnO thin films were modified with Ag Nanostructures using polydopamine to fabricate a homogeneous Ag@ZnO hybrid high-performance SERS substrate. Ag/ZnO hybrid nanostructures were analyzed by FESEM and XRD to investigate their morphological and structural characterizations. SERS measurements were performed for all silver growth times to understand the effect of the silver growth process and hybrid structure synergy on SERS performance. The Ag@ZnO hybrid structure, cultivated with 24-hour silver growth, exhibited remarkable detectability even at an ultra-low R6G concentration of 10 pM

Keywords

Polydopamine Plasmonics SERS Ag-ZnO hybrid structures R6G

References

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  • [2] P.L. Stiles, J.A. Dieringer, N.C. Shah, R.P. Van Duyne, Surface-Enhanced Raman Spectroscopy, Annual Review of Analytical Chemistry. 1 (2008) 601–626.
  • [3] O. Szabó, S. Flickyngerová, T. Ignat, I. Novotný, V. Tvarozek, Gold nanostructures sputtered on zinc oxide thin film and corning glass substrates, Facta universitatis - series: Electronics and Energetics. 29 (2016) 77–88.
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  • [7] H. Lee, S.M. Dellatore, W.M. Miller, P.B. Messersmith, Mussel-Inspired Surface Chemistry for Multifunctional Coatings, Science. 318 (2007) 426–430.
  • [8] Y. Cong, T. Xia, M. Zou, Z. Li, B. Peng, D. Guo, Z. Deng, Mussel-inspired polydopamine coating as a versatile platform for synthesizing polystyrene/Ag nanocomposite particles with enhanced antibacterial activities, J. Mater. Chem. B. 2 (2014) 3450–3461.
  • [9] M. Kuru, H. Narsat, The effect of heat treatment temperature and Mg doping on structural and photocatalytic activity of ZnO thin films fabricated by RF magnetron co-sputtering technique, Journal of Materials Science: Materials in Electronics. 30 (2019) 18484–18495.
  • [10] H.L. Cao, X.F. Qian, Q. Gong, W.M. Du, X.D. Ma, Z.K. Zhu, Shape- and size-controlled synthesis of nanometre ZnO from a simple solution route at room temperature, Nanotechnology. 17 (2006) 3632–3636.
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  • [16] S. Nie, S.R. Emory, Probing Single Molecules and Single Nanoparticles by Surface-Enhanced Raman Scattering, Science. 275 (1997) 1102–1106..
  • [17] C. Jiang, S. Markutsya, V. V. Tsukruk, Collective and Individual Plasmon Resonances in Nanoparticle Films Obtained by Spin-Assisted Layer-by-Layer Assembly, Langmuir. 20 (2004) 882–890.
  • [18] D. Cheng, Y. Zhang, C. Yan, Z. Deng, X. Tang, G. Cai, X. Wang, Polydopamine-assisted in situ growth of three-dimensional ZnO/Ag nanocomposites on PET films for SERS and catalytic properties, Journal of Molecular Liquids. 338 (2021) 116639.
  • [19] E.C. Le Ru, E. Blackie, M. Meyer, P.G. Etchegoin, Surface enhanced Raman scattering enhancement factors: a comprehensive study, The Journal of Physical Chemistry C. 111 (2007) 13794–13803.
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Year 2024, Volume: 45 Issue: 2, 352 - 359, 30.06.2024

Sami Pekdemir

https://doi.org/10.17776/csj.1351460

Abstract

References

  • [1] K. Kneipp, Y. Wang, H. Kneipp, L.T. Perelman, I. Itzkan, R.R. Dasari, M.S. Feld, Single Molecule Detection Using Surface-Enhanced Raman Scattering (SERS), Physical Review Letters. 78 (1997) 1667–1670..
  • [2] P.L. Stiles, J.A. Dieringer, N.C. Shah, R.P. Van Duyne, Surface-Enhanced Raman Spectroscopy, Annual Review of Analytical Chemistry. 1 (2008) 601–626.
  • [3] O. Szabó, S. Flickyngerová, T. Ignat, I. Novotný, V. Tvarozek, Gold nanostructures sputtered on zinc oxide thin film and corning glass substrates, Facta universitatis - series: Electronics and Energetics. 29 (2016) 77–88.
  • [4] A. Guerrero-Martínez, S. Barbosa, I. Pastoriza-Santos, L.M. Liz-Marzán, Nanostars shine bright for you, Current Opinion in Colloid & Interface Science. 16 (2011) 118–127.
  • [5] Y. Fang, N.-H. Seong, D.D. Dlott, Measurement of the Distribution of Site Enhancements in Surface-Enhanced Raman Scattering, Science. 321 (2008) 388–392.
  • [6] X.-S. Zheng, I.J. Jahn, K. Weber, D. Cialla-May, J. Popp, Label-free SERS in biological and biomedical applications: Recent progress, current challenges and opportunities, Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy. 197 (2018) 56–77.
  • [7] H. Lee, S.M. Dellatore, W.M. Miller, P.B. Messersmith, Mussel-Inspired Surface Chemistry for Multifunctional Coatings, Science. 318 (2007) 426–430.
  • [8] Y. Cong, T. Xia, M. Zou, Z. Li, B. Peng, D. Guo, Z. Deng, Mussel-inspired polydopamine coating as a versatile platform for synthesizing polystyrene/Ag nanocomposite particles with enhanced antibacterial activities, J. Mater. Chem. B. 2 (2014) 3450–3461.
  • [9] M. Kuru, H. Narsat, The effect of heat treatment temperature and Mg doping on structural and photocatalytic activity of ZnO thin films fabricated by RF magnetron co-sputtering technique, Journal of Materials Science: Materials in Electronics. 30 (2019) 18484–18495.
  • [10] H.L. Cao, X.F. Qian, Q. Gong, W.M. Du, X.D. Ma, Z.K. Zhu, Shape- and size-controlled synthesis of nanometre ZnO from a simple solution route at room temperature, Nanotechnology. 17 (2006) 3632–3636.
  • [11] P. Fageria, S. Gangopadhyay, S. Pande, Synthesis of ZnO/Au and ZnO/Ag nanoparticles and their photocatalytic application using UV and visible light, RSC Adv. 4 (2014) 24962–24972.
  • [12] S. Heinonen, J.-P. Nikkanen, E. Huttunen-Saarivirta, E. Levänen, Investigation of long-term chemical stability of structured ZnO films in aqueous solutions of varying conditions, Thin Solid Films. 638 (2017) 410–419.
  • [13] T. Theivasanthi, M. Alagar, Electrolytic Synthesis and Characterization of Silver Nanopowder, Nano Biomedicine and Engineering. 4 (2012). doi:10.5101/nbe.v4i2.p58-65.
  • [14] B.D. Cullity, C.D. Graham, Introduction to Magnetic Materials, John Wiley & Sons, Inc., Hoboken, NJ, USA, 2008.
  • [15] N.D. Jayram, S. Sonia, S. Poongodi, P.S. Kumar, Y. Masuda, D. Mangalaraj, N. Ponpandian, C. Viswanathan, Superhydrophobic Ag decorated ZnO nanostructured thin film as effective surface enhanced Raman scattering substrates, Applied Surface Science. 355 (2015) 969–977..
  • [16] S. Nie, S.R. Emory, Probing Single Molecules and Single Nanoparticles by Surface-Enhanced Raman Scattering, Science. 275 (1997) 1102–1106..
  • [17] C. Jiang, S. Markutsya, V. V. Tsukruk, Collective and Individual Plasmon Resonances in Nanoparticle Films Obtained by Spin-Assisted Layer-by-Layer Assembly, Langmuir. 20 (2004) 882–890.
  • [18] D. Cheng, Y. Zhang, C. Yan, Z. Deng, X. Tang, G. Cai, X. Wang, Polydopamine-assisted in situ growth of three-dimensional ZnO/Ag nanocomposites on PET films for SERS and catalytic properties, Journal of Molecular Liquids. 338 (2021) 116639.
  • [19] E.C. Le Ru, E. Blackie, M. Meyer, P.G. Etchegoin, Surface enhanced Raman scattering enhancement factors: a comprehensive study, The Journal of Physical Chemistry C. 111 (2007) 13794–13803.
  • [20] Y.C. Kao, X. Han, Y.H. Lee, H.K. Lee, G.C. Phan-Quang, C.L. Lay, H.Y.F. Sim, V.J.X. Phua, L.S. Ng, C.W. Ku, T.C. Tan, I.Y. Phang, N.S. Tan, X.Y. Ling, Multiplex Surface-Enhanced Raman Scattering Identification and Quantification of Urine Metabolites in Patient Samples within 30 min, ACS Nano. 14 (2020) 2542–2552.
There are 20 citations in total.

Details

Primary Language English
Subjects Materials Engineering (Other)
Journal Section Natural Sciences
Authors

Sami Pekdemir 0000-0002-7929-6849

Publication Date June 30, 2024
Submission Date August 28, 2023
Acceptance Date May 30, 2024
Published in Issue Year 2024Volume: 45 Issue: 2

Cite

APA Pekdemir, S. (2024). Polydopamine-mediated facile Silver grown on ZnO Thin Films as High Performance SERS Substrates for R6G Detection. Cumhuriyet Science Journal, 45(2), 352-359. https://doi.org/10.17776/csj.1351460
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