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The effect of strontium carbonate additive on the production of graphitic boron nitride using modified O'connor method

Year 2021, Volume: 42 Issue: 4, 836 - 842, 29.12.2021

Muhammed Öz

Abstract

In this study, it was investigated that whether the graphitic boron nitride was successfully synthesized by adding strontium carbonate (within the different amount of 20-40%) using O'Connor method which is the one of the solid-state methods or not. Fourier transform infrared spectroscopy FTIR, powder X-ray diffraction (XRD), energy-dispersive X-ray spectroscopy (EDS) and scanning electron microscopy (SEM) methods were used to clarify the formation of boron nitride structure. Inter and intra-layer BN vibration movements of gBN were determined by FTIR method. Also, peaks belonging to the gBN formation were observed in the XRD analysis, and the distance between the layers was found to be close to both the theoretical values and data of commercially produced BN structure. The morphological examination was performed with SEM, and the planar properties of structure were determined. In addition, the EDS measurements supported that the crystal structure of powders include only nitrogen and boron atoms. In the light of these methods, it has been determined that the graphitic BN was able to synthesize at a lower temperature and in a more regular crystal structure compared to the O'Connor method with strontium carbonate additives.

Keywords

gBN Strontium carbonate Crystallinity O

Thanks

We would like to thank the Department of Physics (Bolu Abant Izzet Baysal University) for XRD and SEM measurements.

References

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  • [11] Öz M., Temperature dependency on crystallinity and durability of mineral dolomite doped nanocrystalline hexagonal boron nitride, Journal of Inorganic and Organometallic Polymers and Materials, 30(3) (2020) 758-766.
  • [12] Öz M., Bozkurt Ç., Kanbur Yılmaz B., Yıldırım G., Effect of borates on the synthesis of nanoscale hexagonal boron nitride by a solid‐state method, Microscopy Research and Technique, 84(11) (2021) 2677–2684.
  • [13] Hubáček M., Sato T., Preparation and properties of a compound in the BCN system, Journal of Solid State Chemistry, 114(1) (1995) 258-264.
  • [14] Bartnitskaya T. S., Lyashenko V. I., Kurdyumov A. V., Ostrovskaya N. F., Rogovaya I. G., Effect of lithium on structure formation of graphite-like boron nitride with carbothermal synthesis, Powder Metallurgy and Metal Ceramics, 33(7) (1995) 335-340.
  • [15] Öz M., Characterization of Caesium Carbonate-Doped Porous Non-Activated Graphitic (Hexagonal) Boron Nitride and Adsorption Properties, Arabian Journal for Science and Engineering, 46(6) (2021) 5671-5680.
  • [16] Hagio T., Nonaka K., Sato T., Microstructural development with crystallization of hexagonal boron nitride, Journal of Materials Science Letters, 16(10) (1997) 795-798.
  • [17] Warren B. E., X-ray Diffraction, Courier Corporation, Dover Publications Inc., New York, (1990), 20-80.
  • [18] Pease R. S., An X-ray study of boron nitride, Acta Crystallographica, 3 (1952) 356-361.
  • [19] Hubáček M., Ueki M., Chemical reactions in hexagonal boron nitride system, Journal of Solid State Chemistry, 123(2) (1996) 215-222.
  • [20] Scherrer P., Bestimmung der Größe und der inneren Struktur von Kolloidteilchen mittels Röntgenstrahlen, Nachrichten von der Gesellschaft der Wissenschaften zu Göttingen Math.-Phys. Kl., 26(2) (1918) 98–100.
  • [21] Shimomura J., Funahashi T., Koitabashi T., Electron microscopy of hexagonal boron nitride powder, Journal of Materials Science, 30(12) (1995) 3193-3199.

Year 2021, Volume: 42 Issue: 4, 836 - 842, 29.12.2021

Muhammed Öz

Abstract

References

  • [1] Mishima O., Era K., Electric Refractory Materials, ed. Y. Kumashiro, Marcel Dekker, Inc., New York (2000), 495.
  • [2] Lin Y., Connell J. W., Advances in 2D boron nitride nanostructures: nanosheets, nanoribbons, nanomeshes, and hybrids with graphene, Nanoscale, 4(22) (2012) 6908-6939.
  • [3] Zhi C., Bando Y., Tang C., Golberg D., Boron nitride nanotubes, Materials Science and Engineering: R: Reports, 70(3-6) (2010) 92-111.
  • [4] Paine R. T., Narula C. K., Synthetic routes to boron nitride, Chemical Reviews, 90(1) (1990) 73-91.
  • [5] Haubner R., Wilhelm M., Weissenbacher R., Lux B., High performance non-oxide ceramics II, in Boron Nitride Properties, Synthesis and Applications. Structure and Bonding Series, vol. 102 Springer, Berlin, (2002), 1–45.
  • [6] Kimura Y., Wakabayashi T., Okada K., Wada T., Nishikawa H., Boron nitride as a lubricant additive, Wear, 232(2) (1999) 199-206.
  • [7] O'connor T. E., Synthesis of boron nitride, Journal of the American Chemical Society, 84(9) (1962) 1753-1754.
  • [8] Thomas J. R., Weston N. E., O'connor T. E., Turbostratic1 boron nitride, thermal transformation to ordered-layer-lattice boron nitride, Journal of the American Chemical Society, 84(24) (1962) 4619-4622.
  • [9] Niedenzu K., Boron- Nitrogen Compounds, Academic Pres. Inc., Springer Verlag, (1965), 147-153.
  • [10] Öz M., Saritekin N. K., Bozkurt Ç., Yildirim G., Synthesis of highly ordered hBN in presence of group I/IIA carbonates by solid state reaction, Crystal Research and Technology, 51(6) (2016) 380-392.
  • [11] Öz M., Temperature dependency on crystallinity and durability of mineral dolomite doped nanocrystalline hexagonal boron nitride, Journal of Inorganic and Organometallic Polymers and Materials, 30(3) (2020) 758-766.
  • [12] Öz M., Bozkurt Ç., Kanbur Yılmaz B., Yıldırım G., Effect of borates on the synthesis of nanoscale hexagonal boron nitride by a solid‐state method, Microscopy Research and Technique, 84(11) (2021) 2677–2684.
  • [13] Hubáček M., Sato T., Preparation and properties of a compound in the BCN system, Journal of Solid State Chemistry, 114(1) (1995) 258-264.
  • [14] Bartnitskaya T. S., Lyashenko V. I., Kurdyumov A. V., Ostrovskaya N. F., Rogovaya I. G., Effect of lithium on structure formation of graphite-like boron nitride with carbothermal synthesis, Powder Metallurgy and Metal Ceramics, 33(7) (1995) 335-340.
  • [15] Öz M., Characterization of Caesium Carbonate-Doped Porous Non-Activated Graphitic (Hexagonal) Boron Nitride and Adsorption Properties, Arabian Journal for Science and Engineering, 46(6) (2021) 5671-5680.
  • [16] Hagio T., Nonaka K., Sato T., Microstructural development with crystallization of hexagonal boron nitride, Journal of Materials Science Letters, 16(10) (1997) 795-798.
  • [17] Warren B. E., X-ray Diffraction, Courier Corporation, Dover Publications Inc., New York, (1990), 20-80.
  • [18] Pease R. S., An X-ray study of boron nitride, Acta Crystallographica, 3 (1952) 356-361.
  • [19] Hubáček M., Ueki M., Chemical reactions in hexagonal boron nitride system, Journal of Solid State Chemistry, 123(2) (1996) 215-222.
  • [20] Scherrer P., Bestimmung der Größe und der inneren Struktur von Kolloidteilchen mittels Röntgenstrahlen, Nachrichten von der Gesellschaft der Wissenschaften zu Göttingen Math.-Phys. Kl., 26(2) (1918) 98–100.
  • [21] Shimomura J., Funahashi T., Koitabashi T., Electron microscopy of hexagonal boron nitride powder, Journal of Materials Science, 30(12) (1995) 3193-3199.
There are 21 citations in total.

Details

Primary Language English
Journal Section Natural Sciences
Authors

Muhammed Öz 0000-0003-0049-0161

Publication Date December 29, 2021
Submission Date February 1, 2021
Acceptance Date December 19, 2021
Published in Issue Year 2021Volume: 42 Issue: 4

Cite

APA Öz, M. (2021). The effect of strontium carbonate additive on the production of graphitic boron nitride using modified O’connor method. Cumhuriyet Science Journal, 42(4), 836-842.