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Removal of Bromophenol Blue from Aqueous Solution Using Bentonite, Zeolite and Graphene Oxide

Year 2024, Volume: 45 Issue: 1, 64 - 72, 28.03.2024

Nuket Kartal Temel , İbrahim Gökçe Erdem

https://doi.org/10.17776/csj.1424592

Abstract

In this study, an anionic dyestuff bromophenol blue (BrPB) from the aqueous solution was removed by adsorption in the presence of bentonite (B), zeolite (Z) and graphene oxide (GO). The effects of pH, adsorbent amount, initial concentration of BrPB, temperature and time on adsorption were investigated. After the adsorption process, ultraviolet-visible region spectrophotometer (UV-VIS) was used to measure the amount of dyestuff remaining in the solution which is not adsorbed. It’s found that; the optimum values obtained for the adsorption process; the optimum pH value 5 for B and Z, 4 for GO; 0.03 g amount of adsorbent and 60 minutes for the equilibrium time. The compatibility of Langmiur and Freundlich isotherm models was found as Z> GO> B and GO> B> Z respectively. In terms of kinetics aspect, it was observed that all adsorbents were comply with pseudo-second order reaction kinetics. To be positive of ΔG° value for B and Z is of physical nature of adsorption, to be negative of ΔG° value for GO requires to be chemical nature of adsorption. When the obtained ΔH° values were examined, it was observed that the reaction was endothermic for B and Z and exothermic for GO. The negative value of ΔS° for B and Z adsorbent species indicates that the randomness between solid and liquid decreases, whereas the positive ΔS° value for GO indicates that the randomness between solid and liquid increases. The highest adsorption capacity value obtained after the measurements made under optimum conditions is 589 mg g-1 for GO and 15.7 and 19.8 mg g-1 for B and Z, respectively.

Keywords

Adsorption Bentonite Bromophenol blue Graphene oxide Zeolite.

Project Number

F-497

References

  • [1] Rai H. S., Bhattacharyya M. S., Singh J., Bansal T. K., Vats P., Banerjee U. C., Removal of dyes from the effluent of textile and dyestuff manufacturing industry: a review of emerging techniques with reference to biological treatment. Critical Reviews in Environmental Science And Technology, 35(3) (2005) 219-238.
  • [2] Ada K., Ergene A., Tan S., Yalçın E., Adsorption of Remazol Brilliant Blue R using ZnO fine powder: Equilibrium, kinetic and thermodynamic modeling studies. Journal of Hazardous Materials, 165(1-3) (2009) 637-644.
  • [3] Nigam P., Armour G., Banat I. M., Singh D., Marchant R., Physical removal of textile dyes from effluents and solid-state fermentation of dye-adsorbed agricultural residues. Bioresource Technology, 72(3) (2000) 219-226.
  • [4] Banat I. M., Nigam P., Singh D., Marchant R., Microbial decolorization of textile-dye-containing effluents: A review (vol 58, pg 217, 1996). Bioresource Technology, 61(1) (1997) 103-103.
  • [5] Brown M. A., De Vito S. C., Predicting azo dye toxicity. Critical Reviews İn Environmental Science And Technology, 23(3) (1993) 249-324.
  • [6] Wang S., Boyjoo Y., Choueib A., Zhu Z. H., Removal of dyes from aqueous solution using fly ash and red mud. Water Research, 39(1) (2005) 129-138.
  • [7] Annadurai G. Adsorption of basic dye on strongly chelating polymer: batch kinetics studies. Iranian Polynter Jourual 11(4) (2002) 1026-1265.
  • [8] Soylu M., Gökkuş Ö.,Türkiye'deki Doğal Zeolitler Ve İyon Değışimi Uygulamaları. Ömer Halisdemir Üniversitesi Mühendislik Bilimleri Dergisi, 6(1) (2017) 11-20.
  • [9] İşçi S. Bentonit dispersiyonlarına organik ve inorganik katkıların adsorbsiyonunun reolojik özellikleri üzerine etkisi, İstanbul Teknik Üniversitesi, Fen Bilimleri Enstitüsü, (2002).
  • [10] Tiyek İ., Dönmez U., Yıldırım B., Alma M. H., Ersoy M. S., Karataş Ş., Kimyasal yöntem ile indirgenmiş grafen oksit sentezi ve karakterizasyonu. Sakarya University Journal of Science, 20(2) (2016) 349-357.
  • [11] Zhang W., Zhou C., Zhou W., Lei A., Zhang Q., Wan Q., Zou B., Fast and considerable adsorption of methylene blue dye onto graphene oxide. Bulletin of Environmental Contamination and Toxicology, 87(1) (2011) 86.
  • [12] Li Y, Du Q, Liu T, Peng X, Wang J, Sun J, Wang Y, Wu S, Wang Z, Xia Y, Xia L. Comparative study of methylene blue dye adsorption onto activated carbon, graphene oxide, and carbon nanotubes. Chemical Engineering Research and Design, 91(2) (2013) 361-368.
  • [13] Kartal Temel N. Sertakan K., Temel Ü.N. Grafen Oksitin Hummers Metodu ile Sentezlenmesine Etki Eden Parametrelerin İyileştirilmesi. Cumhuriyet Science Journal, 38(4) (2017) 674-680.
  • [14] Hummers Jr. W.S., Offeman R. E. Preparation of graphitic oxide. Journal of The American Chemical Society, 80(6) (1958) 1339-1339.
  • [15] Liu J., Yao S., Wang L., Zhu W., Xu J., Song H. Adsorption of bromophenol blue from aqueous samples by novel supported ionic liquids. Journal of Chemical Technology & Biotechnology, 89(2) (2014) 230-238.
  • [16] Okoye C.C. Adsorptive Removal of Bromophenol Blue Dye from Aqueous Solution using Acid Activated Clay. International Journal of Scientific Research and Management, 6(03) (2018).
  • [17] El-Sayed G.O. Removal of methylene blue and crystal violet from aqueous solutions by palm kernel fiber. Desalination, 272(1-3) (2011) 225-232.
  • [18] Dhananasekaran S., Palanivel R., Pappu S., Adsorption of methylene blue, bromophenol blue, and coomassie brilliant blue by α-chitin nanoparticles. Journal of Advanced Research, 7(1) (2016) 113-124.
  • [19] El-Dars F.M., Ibrahim H.M., Farag H.A., Abdelwahhab M.Z., Shalabi, M.E.H. Adsorption kinetics of bromophenol blue and eriochrome black t using bentonite carbon composite material. International Journal Of Scientific & Engineering Research, 6(5) (2015) 679-688.
  • [20] Akpomie K. G., Adegoke K. A., Oyedotun K. O., Ighalo J. O., Amaku J. F., Olisah C., Conradie J. Removal of bromophenol blue dye from water onto biomass, activated carbon, biochar, polymer, nanoparticle, and composite adsorbents. Biomass Conversion and Biorefinery, (2022) 1-29.
  • [21] Khan H., Khalil A. K., Khan A., Saeed K., Ali N. Photocatalytic degradation of bromophenol blue in aqueous medium using chitosan conjugated magnetic nanoparticles. Korean Journal of Chemical Engineering, 33 (2016) 2802-2807.
  • [22] Shah T., Gul T., Saeed K. Photodegradation of bromophenol blue in aqueous medium using graphene nanoplates-supported TiO2. Applied Water Science, 9(4) (2019) 1-7.
  • [23] Saha B., Das S., Saikia J., Das G., Preferential and enhanced adsorption of different dyes on iron oxide nanoparticles: a comparative study. The Journal of Physical Chemistry C, 115(16) (2011) 8024-8033.
  • [24] Mazaheri H., Ghaedi M., Asfaram A., Hajati S., Performance of CuS nanoparticle loaded on activated carbon in the adsorption of methylene blue and bromophenol blue dyes in binary aqueous solutions: using ultrasound power and optimization by central composite design. Journal of Molecular Liquids, 219 (2016) 667-676.
  • [25] Ghaedi M., Ghaedi A.M., Negintaji E., Ansari A., Vafaei A., Rajabi M., Random forest model for removal of bromophenol blue using activated carbon obtained from Astragalus bisulcatus tree. Journal of Industrial and Engineering Chemistry, 20(4) (2014) 1793-1803.
  • [26] El-Gamal S.M A., Amin M.S., Ahmed M.A., Removal of methyl orange and bromophenol blue dyes from aqueous solution using Sorel’s cement nanoparticles. Journal of Environmental Chemical Engineering, 3(3) (2015) 1702-1712.
  • [27] Mohammadzadeh A., Ramezani M., Ghaedi A.M., Synthesis and characterization of Fe2O3–ZnO–ZnFe2O4/carbon nanocomposite and its application to removal of bromophenol blue dye using ultrasonic assisted method: optimization by response surface methodology and genetic algorithm. Journal of the Taiwan Institute of Chemical Engineers, 59 (2016) 275-284.
  • [28] El-Zahhar Adel A., Awwad Nasser S., El-Katori Emad E., Removal of bromophenol blue dye from industrial waste water by synthesizing polymer-clay composite. Journal of Molecular Liquids, 199 (2014) 454-461.
  • [29] Haider S., Bukhari N., Park S.Y., Iqbal Y., Al-Masry W.A. Adsorption of bromo-phenol blue from an aqueous solution onto thermally modified granular charcoal. Chemical Engineering Research and Design, 89 (1) (2011) 23-28.
  • [30] You L., Wu Z., Kim T., Lee K. Kinetics and thermodynamics of bromophenol blue adsorption by a mesoporous hybrid gel derived from tetraethoxysilane and bis (trimethoxysilyl) hexane. Journal of colloid and interface science, 300 (2) (2006) 526-53

Year 2024, Volume: 45 Issue: 1, 64 - 72, 28.03.2024

Nuket Kartal Temel , İbrahim Gökçe Erdem

https://doi.org/10.17776/csj.1424592

Abstract

Project Number

F-497

References

  • [1] Rai H. S., Bhattacharyya M. S., Singh J., Bansal T. K., Vats P., Banerjee U. C., Removal of dyes from the effluent of textile and dyestuff manufacturing industry: a review of emerging techniques with reference to biological treatment. Critical Reviews in Environmental Science And Technology, 35(3) (2005) 219-238.
  • [2] Ada K., Ergene A., Tan S., Yalçın E., Adsorption of Remazol Brilliant Blue R using ZnO fine powder: Equilibrium, kinetic and thermodynamic modeling studies. Journal of Hazardous Materials, 165(1-3) (2009) 637-644.
  • [3] Nigam P., Armour G., Banat I. M., Singh D., Marchant R., Physical removal of textile dyes from effluents and solid-state fermentation of dye-adsorbed agricultural residues. Bioresource Technology, 72(3) (2000) 219-226.
  • [4] Banat I. M., Nigam P., Singh D., Marchant R., Microbial decolorization of textile-dye-containing effluents: A review (vol 58, pg 217, 1996). Bioresource Technology, 61(1) (1997) 103-103.
  • [5] Brown M. A., De Vito S. C., Predicting azo dye toxicity. Critical Reviews İn Environmental Science And Technology, 23(3) (1993) 249-324.
  • [6] Wang S., Boyjoo Y., Choueib A., Zhu Z. H., Removal of dyes from aqueous solution using fly ash and red mud. Water Research, 39(1) (2005) 129-138.
  • [7] Annadurai G. Adsorption of basic dye on strongly chelating polymer: batch kinetics studies. Iranian Polynter Jourual 11(4) (2002) 1026-1265.
  • [8] Soylu M., Gökkuş Ö.,Türkiye'deki Doğal Zeolitler Ve İyon Değışimi Uygulamaları. Ömer Halisdemir Üniversitesi Mühendislik Bilimleri Dergisi, 6(1) (2017) 11-20.
  • [9] İşçi S. Bentonit dispersiyonlarına organik ve inorganik katkıların adsorbsiyonunun reolojik özellikleri üzerine etkisi, İstanbul Teknik Üniversitesi, Fen Bilimleri Enstitüsü, (2002).
  • [10] Tiyek İ., Dönmez U., Yıldırım B., Alma M. H., Ersoy M. S., Karataş Ş., Kimyasal yöntem ile indirgenmiş grafen oksit sentezi ve karakterizasyonu. Sakarya University Journal of Science, 20(2) (2016) 349-357.
  • [11] Zhang W., Zhou C., Zhou W., Lei A., Zhang Q., Wan Q., Zou B., Fast and considerable adsorption of methylene blue dye onto graphene oxide. Bulletin of Environmental Contamination and Toxicology, 87(1) (2011) 86.
  • [12] Li Y, Du Q, Liu T, Peng X, Wang J, Sun J, Wang Y, Wu S, Wang Z, Xia Y, Xia L. Comparative study of methylene blue dye adsorption onto activated carbon, graphene oxide, and carbon nanotubes. Chemical Engineering Research and Design, 91(2) (2013) 361-368.
  • [13] Kartal Temel N. Sertakan K., Temel Ü.N. Grafen Oksitin Hummers Metodu ile Sentezlenmesine Etki Eden Parametrelerin İyileştirilmesi. Cumhuriyet Science Journal, 38(4) (2017) 674-680.
  • [14] Hummers Jr. W.S., Offeman R. E. Preparation of graphitic oxide. Journal of The American Chemical Society, 80(6) (1958) 1339-1339.
  • [15] Liu J., Yao S., Wang L., Zhu W., Xu J., Song H. Adsorption of bromophenol blue from aqueous samples by novel supported ionic liquids. Journal of Chemical Technology & Biotechnology, 89(2) (2014) 230-238.
  • [16] Okoye C.C. Adsorptive Removal of Bromophenol Blue Dye from Aqueous Solution using Acid Activated Clay. International Journal of Scientific Research and Management, 6(03) (2018).
  • [17] El-Sayed G.O. Removal of methylene blue and crystal violet from aqueous solutions by palm kernel fiber. Desalination, 272(1-3) (2011) 225-232.
  • [18] Dhananasekaran S., Palanivel R., Pappu S., Adsorption of methylene blue, bromophenol blue, and coomassie brilliant blue by α-chitin nanoparticles. Journal of Advanced Research, 7(1) (2016) 113-124.
  • [19] El-Dars F.M., Ibrahim H.M., Farag H.A., Abdelwahhab M.Z., Shalabi, M.E.H. Adsorption kinetics of bromophenol blue and eriochrome black t using bentonite carbon composite material. International Journal Of Scientific & Engineering Research, 6(5) (2015) 679-688.
  • [20] Akpomie K. G., Adegoke K. A., Oyedotun K. O., Ighalo J. O., Amaku J. F., Olisah C., Conradie J. Removal of bromophenol blue dye from water onto biomass, activated carbon, biochar, polymer, nanoparticle, and composite adsorbents. Biomass Conversion and Biorefinery, (2022) 1-29.
  • [21] Khan H., Khalil A. K., Khan A., Saeed K., Ali N. Photocatalytic degradation of bromophenol blue in aqueous medium using chitosan conjugated magnetic nanoparticles. Korean Journal of Chemical Engineering, 33 (2016) 2802-2807.
  • [22] Shah T., Gul T., Saeed K. Photodegradation of bromophenol blue in aqueous medium using graphene nanoplates-supported TiO2. Applied Water Science, 9(4) (2019) 1-7.
  • [23] Saha B., Das S., Saikia J., Das G., Preferential and enhanced adsorption of different dyes on iron oxide nanoparticles: a comparative study. The Journal of Physical Chemistry C, 115(16) (2011) 8024-8033.
  • [24] Mazaheri H., Ghaedi M., Asfaram A., Hajati S., Performance of CuS nanoparticle loaded on activated carbon in the adsorption of methylene blue and bromophenol blue dyes in binary aqueous solutions: using ultrasound power and optimization by central composite design. Journal of Molecular Liquids, 219 (2016) 667-676.
  • [25] Ghaedi M., Ghaedi A.M., Negintaji E., Ansari A., Vafaei A., Rajabi M., Random forest model for removal of bromophenol blue using activated carbon obtained from Astragalus bisulcatus tree. Journal of Industrial and Engineering Chemistry, 20(4) (2014) 1793-1803.
  • [26] El-Gamal S.M A., Amin M.S., Ahmed M.A., Removal of methyl orange and bromophenol blue dyes from aqueous solution using Sorel’s cement nanoparticles. Journal of Environmental Chemical Engineering, 3(3) (2015) 1702-1712.
  • [27] Mohammadzadeh A., Ramezani M., Ghaedi A.M., Synthesis and characterization of Fe2O3–ZnO–ZnFe2O4/carbon nanocomposite and its application to removal of bromophenol blue dye using ultrasonic assisted method: optimization by response surface methodology and genetic algorithm. Journal of the Taiwan Institute of Chemical Engineers, 59 (2016) 275-284.
  • [28] El-Zahhar Adel A., Awwad Nasser S., El-Katori Emad E., Removal of bromophenol blue dye from industrial waste water by synthesizing polymer-clay composite. Journal of Molecular Liquids, 199 (2014) 454-461.
  • [29] Haider S., Bukhari N., Park S.Y., Iqbal Y., Al-Masry W.A. Adsorption of bromo-phenol blue from an aqueous solution onto thermally modified granular charcoal. Chemical Engineering Research and Design, 89 (1) (2011) 23-28.
  • [30] You L., Wu Z., Kim T., Lee K. Kinetics and thermodynamics of bromophenol blue adsorption by a mesoporous hybrid gel derived from tetraethoxysilane and bis (trimethoxysilyl) hexane. Journal of colloid and interface science, 300 (2) (2006) 526-53
There are 30 citations in total.

Details

Primary Language English
Subjects Analytical Chemistry (Other)
Journal Section Natural Sciences
Authors

Nuket Kartal Temel 0000-0002-3539-4930

İbrahim Gökçe Erdem 0000-0002-3765-2307

Project Number F-497
Publication Date March 28, 2024
Submission Date January 23, 2024
Acceptance Date March 23, 2024
Published in Issue Year 2024Volume: 45 Issue: 1

Cite

APA Kartal Temel, N., & Erdem, İ. G. (2024). Removal of Bromophenol Blue from Aqueous Solution Using Bentonite, Zeolite and Graphene Oxide. Cumhuriyet Science Journal, 45(1), 64-72. https://doi.org/10.17776/csj.1424592
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