Removal of Bromophenol Blue from Aqueous Solution Using Bentonite, Zeolite and Graphene Oxide

Nuket Kartal Temel; İbrahim Gökçe Erdem

doi:10.17776/csj.1424592

EN

Removal of Bromophenol Blue from Aqueous Solution Using Bentonite, Zeolite and Graphene Oxide

Abstract

In this study, an anionic dyestuff bromophenol blue (BrPB) from the aqueous solution was removed by adsorption in the presence of bentonite (B), zeolite (Z) and graphene oxide (GO). The effects of pH, adsorbent amount, initial concentration of BrPB, temperature and time on adsorption were investigated. After the adsorption process, ultraviolet-visible region spectrophotometer (UV-VIS) was used to measure the amount of dyestuff remaining in the solution which is not adsorbed. It’s found that; the optimum values obtained for the adsorption process; the optimum pH value 5 for B and Z, 4 for GO; 0.03 g amount of adsorbent and 60 minutes for the equilibrium time. The compatibility of Langmiur and Freundlich isotherm models was found as Z> GO> B and GO> B> Z respectively. In terms of kinetics aspect, it was observed that all adsorbents were comply with pseudo-second order reaction kinetics. To be positive of ΔG° value for B and Z is of physical nature of adsorption, to be negative of ΔG° value for GO requires to be chemical nature of adsorption. When the obtained ΔH° values were examined, it was observed that the reaction was endothermic for B and Z and exothermic for GO. The negative value of ΔS° for B and Z adsorbent species indicates that the randomness between solid and liquid decreases, whereas the positive ΔS° value for GO indicates that the randomness between solid and liquid increases. The highest adsorption capacity value obtained after the measurements made under optimum conditions is 589 mg g-1 for GO and 15.7 and 19.8 mg g-1 for B and Z, respectively.

Keywords

Project Number

F-497

References

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Details

Primary Language

English

Subjects

Analytical Chemistry (Other)

Journal Section

Research Article

Authors

Nuket Kartal Temel ^*
0000-0002-3539-4930
Türkiye

İbrahim Gökçe Erdem
0000-0002-3765-2307
Türkiye

Publication Date

March 28, 2024

Submission Date

January 23, 2024

Acceptance Date

March 23, 2024

Published in Issue

Year 2024 Volume: 45 Number: 1

DOI

https://doi.org/10.17776/csj.1424592

IZ

https://izlik.org/JA99LY83EP

Cite

RIS / Bibtex

APA

Kartal Temel, N., & Erdem, İ. G. (2024). Removal of Bromophenol Blue from Aqueous Solution Using Bentonite, Zeolite and Graphene Oxide. Cumhuriyet Science Journal, 45(1), 64-72. https://doi.org/10.17776/csj.1424592

Cited By

Review: adsorption of dyes from wastewater by graphene oxide and its composites

Journal of Materials Science

https://doi.org/10.1007/s10853-025-10944-0

Öz

Removal of Bromophenol Blue from Aqueous Solution Using Bentonite, Zeolite and Graphene Oxide

Abstract

Keywords

Project Number

References

Details

Primary Language

Subjects

Journal Section

Authors

Publication Date

Submission Date

Acceptance Date

Published in Issue

DOI

IZ

Cite

Cited By

Review: adsorption of dyes from wastewater by graphene oxide and its composites