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Investigation of the thermoluminescence properties Ti4+ doped MgO synthesized solid-state assisted solution combustion synthesis method

Year 2021, Volume: 42 Issue: 1, 164 - 169, 29.03.2021
https://doi.org/10.17776/csj.737307

Abstract

In this study, undoped MgO and titanium (Ti4+) doped MgO ceramics were synthesized using the solid state-assisted solution combustion synthesis method. The structural characteristics were investigated using X-ray diffraction (XRD) and scanning electron microscope (SEM). TL curves of the MgO:Ti4+(0.1%wt) ceramic consist of three TL peaks located at 70, 250 and 290 oC with a heating rate of 2 oC/s after 1 Gy beta dose. Radioluminescence (RL) characteristic of the MgO:Ti4+(0.1%wt) ceramic was studied with excitations between 200 - 1000 nm. It was found to be the four emission bands the maximums located at 327 nm (~3.79 eV), 694 nm (~1.78 eV), 715 (~1.73 eV), and 745 (~1.66 eV). Some dosimetric characteristics such as TL curve, reusability, dose-response, of the ceramic were investigated using the thermoluminescence (TL) technique using beta radiation of 90Sr/90Y. Dose-response characteristics showed the integrated TL signals between 170-350 oC exhibited a linear up to 20 Gy. The experimental results showed that if it is developed of the MgO:Ti4+(0.1%wt) ceramic can be considered as a dosimetric material with suitable properties in personal and medical applications.


Supporting Institution

North Atlantic Treaty Organization (NATO)

Project Number

G5647

Thanks

This research was supported by the NATO Science for Peace and Security program (G5647).

References

  • [1] Alajerami Y., Hashim S., Ghoshal S., Saleh S., Kadni T.,Saripan M., Alzimami K., Ibrahim Z., Bradley D., The effect of TiO2 and MgO on the thermoluminescence properties of a lithium potassium borate glass system, J. Phys. Chem. Solıds., 74 (2013) 1816-1822.
  • [2] Barrón V.R.O., Ochoa F.M.E,. Vázquez C.C., Bernal R., Thermoluminescence of novel MgO–CeO2 obtained by a glycine-based solution combustion method, Appl. Radıat. Isotopes., 117 (2016) 86-90.
  • [3] Guckan V., Altunal V. Ozdemir A., Yegingil. Z., Optically stimulated luminescence of MgO:Na,Li phosphor prepared using solution combustion method, J. Alloy. Compd., 835 (2020) 155253.
  • [4] Mofokeng S., Noto L., Mlotswa D., Orante-Barrón V., Dhlamini M., Thermoluminescence properties of MgO:Al3+,Li+ prepared by microwave-assisted solution combustion method, Physica B., (2020) 412008.
  • [5] Oliveira L., Yukihara E, Baffa O., Lanthanide-doped MgO: A case study on how to design new phosphors for dosimetry with tailored luminescent properties, J. Lumin., 209 (2019) 21-30.
  • [6] Rao R., Duley W., Preparation and luminescence of MgO:Tb phosphors, J. Mater. sci, 27 (1992) 5883-5886.
  • [7] Wang W., Qiao X., Chen J., Tan F., Li H., Influence of titanium doping on the structure and morphology of MgO prepared by coprecipitation method, Mater. Charac., 60 (2009) 858-862.
  • [8] Bokhimi X, Boldú J,Munoz E., Novaro O.,, López T, Hernández J., Gómez R., García-Ruiz A., Structure and composition of the nanocrystalline phases in a MgO− TiO2 system prepared via Sol− Gel technique, Chem. Mater., 11 (1999) 2716-2721.
  • [9] Orante-Barrón V., Oliveira L, Kelly J., Milliken E., Denis G, Jacobsohn L., Puckette J., Yukihara E., Luminescence properties of MgO produced by solution combustion synthesis and doped with lanthanides and Li, J. Lumin., 131 (2011) 1058-1065.
  • [10] Furetta C, Handbook of thermoluminescence, Singapore: World Scientific, (2010).
Year 2021, Volume: 42 Issue: 1, 164 - 169, 29.03.2021
https://doi.org/10.17776/csj.737307

Abstract

Project Number

G5647

References

  • [1] Alajerami Y., Hashim S., Ghoshal S., Saleh S., Kadni T.,Saripan M., Alzimami K., Ibrahim Z., Bradley D., The effect of TiO2 and MgO on the thermoluminescence properties of a lithium potassium borate glass system, J. Phys. Chem. Solıds., 74 (2013) 1816-1822.
  • [2] Barrón V.R.O., Ochoa F.M.E,. Vázquez C.C., Bernal R., Thermoluminescence of novel MgO–CeO2 obtained by a glycine-based solution combustion method, Appl. Radıat. Isotopes., 117 (2016) 86-90.
  • [3] Guckan V., Altunal V. Ozdemir A., Yegingil. Z., Optically stimulated luminescence of MgO:Na,Li phosphor prepared using solution combustion method, J. Alloy. Compd., 835 (2020) 155253.
  • [4] Mofokeng S., Noto L., Mlotswa D., Orante-Barrón V., Dhlamini M., Thermoluminescence properties of MgO:Al3+,Li+ prepared by microwave-assisted solution combustion method, Physica B., (2020) 412008.
  • [5] Oliveira L., Yukihara E, Baffa O., Lanthanide-doped MgO: A case study on how to design new phosphors for dosimetry with tailored luminescent properties, J. Lumin., 209 (2019) 21-30.
  • [6] Rao R., Duley W., Preparation and luminescence of MgO:Tb phosphors, J. Mater. sci, 27 (1992) 5883-5886.
  • [7] Wang W., Qiao X., Chen J., Tan F., Li H., Influence of titanium doping on the structure and morphology of MgO prepared by coprecipitation method, Mater. Charac., 60 (2009) 858-862.
  • [8] Bokhimi X, Boldú J,Munoz E., Novaro O.,, López T, Hernández J., Gómez R., García-Ruiz A., Structure and composition of the nanocrystalline phases in a MgO− TiO2 system prepared via Sol− Gel technique, Chem. Mater., 11 (1999) 2716-2721.
  • [9] Orante-Barrón V., Oliveira L, Kelly J., Milliken E., Denis G, Jacobsohn L., Puckette J., Yukihara E., Luminescence properties of MgO produced by solution combustion synthesis and doped with lanthanides and Li, J. Lumin., 131 (2011) 1058-1065.
  • [10] Furetta C, Handbook of thermoluminescence, Singapore: World Scientific, (2010).
There are 10 citations in total.

Details

Primary Language English
Subjects Classical Physics (Other)
Journal Section Natural Sciences
Authors

Adnan Özdemir 0000-0002-2685-1562

Project Number G5647
Publication Date March 29, 2021
Submission Date May 14, 2020
Acceptance Date January 19, 2021
Published in Issue Year 2021Volume: 42 Issue: 1

Cite

APA Özdemir, A. (2021). Investigation of the thermoluminescence properties Ti4+ doped MgO synthesized solid-state assisted solution combustion synthesis method. Cumhuriyet Science Journal, 42(1), 164-169. https://doi.org/10.17776/csj.737307