Research Article
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Year 2020, Volume: 41 Issue: 3, 651 - 658, 30.09.2020

Adnan Aldemir , Ali Rıza Kul

https://doi.org/10.17776/csj.720332
Cited By: 1

Abstract

Supporting Institution

Van Yüzüncü Yıl Üniversitesi, Bilimsel Araştırma Projeleri Başkanlığı

Project Number

FAP-2019-8615

Thanks

Yazarlar, bu çalışmaya maddi olarak desteklerinden dolayı Van Yüzüncü Yıl Üniversitesi Bilimsel Araştırma Projeleri Başkanlığı'na (proje no: FAP-2019-8615) teşekkür eder.

References

  • Peydayesh M., Rahbar-Kelishami A., Adsorption of methylene blue onto platanus orientalis leaf powder: kinetic, equilibrium and thermodynamic studies. J. Ind. Eng. Chem., 21 (2015) 1014-1019.
  • Weng C. H., Lin Y. T., Tzeng T. W., Removal of methylene blue from aqueous solution by adsorption onto pineapple leaf powder. J. Hazard. Mater., 170(1) (2009) 417-424.
  • Kallel F., Chaari F., Bouaziz F., Bettaieb F., Ghorbel R., Chaabouni S. E., Sorption and desorption characteristics for the removal of a toxic dye, methylene blue from aqueous solution by a low cost agricultural by-product. J. Mol. Liq., 219 (2016) 279-288.
  • Gupta V. K., Suhas., Application of low-cost adsorbents for dye removal – A review. J. Environ. Manage., 90 (2009) 2313-2342.
  • Yagub M. T., Sen T. K., Afroze S., Ang H. M., Dye and its removal from aqueous solution by adsorption: a review. Adv. Colloid Interface Sci., 209 (2014) 172-184.
  • Forgacs E., Cserhati T., Oros G., Removal of synthetic dyes from wastewaters: a review. Env. Int., 30 (2004) 953-971.
  • Zhou Y., Lu J., Zhou Y., Liu Y., Recent advances for dyes removal using novel adsorbents: a review. Env. Poll., 252 (2019) 352-365.
  • Bouaziz F., Koubaa M., Kallel F., Chaari F., Driss D., Ghorbel R. E., Chaabouni S. E., Efficiency of almond gum as a low-cost adsorbent for methylene blue dye removal from aqueous solutions. Ind. Crops and Products, 74 (2015) 903-911.
  • Kausar A., Iqbal M., Javeda A., Aftab K., Nazli Z. H., Bhatti H. N., Nouren S., Adsorption using clay and modified clay: a review. J. Mol. Liq., 256 (2018) 395-407.
  • Mahmoodi N. M., Hayati B., Arami M., Lan C., Adsorption of textile dyes on pine cone from colored wastewater: kinetic, equilibrium and thermodynamic studies. Desalination, 268(1-3) (2011) 117-125.
  • Debnath S., Ballav N., Maity A., Pillay K., Competitive adsorption of ternary dye mixture using pine cone powder modified with β-cyclodextrin. J. Mol. Liq., 225 (2017) 679-688.
  • Miyah Y., Lahrichi A., Idrissi M., Khalil A., Zerrouq F., Adsorption of methylene blue dye from aqueous solutions onto walnut shells powder: Equilibrium and kinetic studies. Surfaces and Interfaces, 11 (2018) 74-81.
  • Singh N. B., Nagpal G., Agrawal S., Rachna., Water purification by using adsorbents: a review. Env. Tech. & Innov., 11 (2018) 187-240.
  • Jin Y., Zeng C., Lü Q-F, Yu Y., Efficient adsorption of methylene blue and lead ions in aqueous solutions by 5-sulfosalicylic acid modified lignin. Int. J. Biol. Macromol., 123 (2019) 50-58.
  • De Gisi S., Lofrano G., Grassi M., Notarnicola M., Characteristics and adsorption capacities of low-cost sorbents for wastewater treatment: a review. Sust. Materials Tech., 9 (2016) 10-40.
  • Değermenci G. D., Değermenci N., Ayvaoğlu V., Durmaz E., Çakır D., Akan E., Adsorption of reactive dyes on lignocellulosic waste; characterization, equilibrium, kinetic and thermodynamic studies. J. Clean. Prod., 225 (2019) 1220-1229.
  • Bouaziz F., Koubaa M., Kallel F., Ghorbel R. E., Chaabouni S. E. Adsorptive removal of malachite green from aqueous solutions by almond gum: kinetic study and equilibrium isotherms. Int. J. Biol. Macromol., 105(1) (2017) 56-65.
  • Adegoke K. A., Bello, O. S., Dye sequestration using agricultural wastes as adsorbents. Water Resour. Ind., 12 (2015) 8-24.
  • Bulgariu L., Escudero L. B., Bello O. S., Iqbal M., Nisar J., Adegoke K. A., Alakhras F., Kornaros M., Anastopoulos I., The utilization of leaf-based adsorbents for dyes removal: a review. J. Mol. Liq, 276 (2019) 728-747.
  • Bedin K. C., Martins A. C., Cazetta A. L., Pezoti O., Almeida V. C., KOH-activated carbon prepared from sucrose spherical carbon: adsorption equilibrium, kinetic and thermodynamic studies for methylene blue removal. Chem. Eng. J., 286 (2016) 476-484.
  • Hamed M. M., Ahmed I. M., Metwally S. S., Adsorptive removal of methylene blue as organic pollutant by marble dust as eco-friendly sorbent. J. Ind. Eng. Chem., 20(4) (2014) 2370-2377.
  • Liu T., Li Y., Du Q., Sun J., Jiao Y., Yang G., Wang Z., Xia Y., Zhang W., Wang K., Zhu H., Wu D., Adsorption of methylene blue from aqueous solution by graphene. Colloids Surf. B Bio., 90 (2012) 197-203.
  • Ojha A. K., Bulasara V. K., Adsorption characteristics of jackfruit leaf powder for the removal of Amido black 10B dye. Env. Prog. & Sust. Energy, 34(2) (2015) 461-470.
  • Han X., Wang W., Ma X., Adsorption characteristics of methylene blue onto low cost biomass material lotus leaf. Chem. Eng. J., 171(1) (2011) 1-8.
  • Gouamid M., Ouahrani M. R., Bensaci M. B., Adsorption equilibrium, kinetics and thermodynamics of methylene blue from aqueous solutions using date palm leaves. Enrgy. Proced., 36 (2013) 898-907.
  • Setiabudi H. D., Jusoh R., Suhaimi S. F. R. M., Masrur S. F., Adsorption of methylene blue onto oil palm (Elaeis guineensis) leaves: process optimization, isotherm, kinetics and thermodynamic studies. J. Taiwan Inst. of Chem. Eng., 63 (2016) 363-370.
  • Bhattacharyya K., Sharma A., Kinetics and thermodynamics of methylene blue adsorption on neem leaf powder. Dyes and Pigments, 65(1) (2005) 51-59.
  • Franca A. S., Oliveira L. S., Ferreira M. E., Kinetics and equilibrium studies of methylene blue adsorption by spent coffee grounds. Desalination, 249(1) (2009) 267-272.
  • Rangabhashiyam S., Anu N., Nandagopal M. S. G., Selvaraju N., Relevance of isotherm models in biosorption of pollutants by agricultural by products. J. Env. Chem. Eng., 2(1) (2014) 398-414.
  • Khodabandehloo A., Rahbar-Kelishami A., Shayesteh H., Methylene blue removal using salix babylonica (weeping willow) leaves powder as a low-cost biosorbent in batch mode: Kinetic, equilibrium, and thermodynamic studies. J. Mol. Liq., 244 (2017) 540-548.
  • Rida K., Bouraoui S., Hadnine S., Adsorption of methylene blue from aqueous solution by kaolin and zeolite. App. Clay. Sci., 83 (2013) 99-105.
  • Rafatullah M., Sulaiman O., Hashim R., Ahmad A., Adsorption of methylene blue on low-cost adsorbents: a review. J. Hazard. Mater., 177(1-3) (2010) 70-80.
  • Ponnusami V., Gunasekar V., Srivastava S. N., Kinetics of methylene blue removal from aqueous solution using gulmohar (Delonix regia) plant leaf powder: Multivariate regression analysis. J. Hazard. Mater., 169 (2009) 119-127.
  • Kul A., Koyuncu H., Adsorption of Pb(II) ions from aqueous solution by native and activated bentonite: Kinetic, equilibrium and thermodynamic study. J. Hazard. Mater., 179 (2010) 332-339.

Isotherm, kinetic and thermodynamic studies for the adsorption of methylene blue on almond leaf powder

Year 2020, Volume: 41 Issue: 3, 651 - 658, 30.09.2020

Adnan Aldemir , Ali Rıza Kul

https://doi.org/10.17776/csj.720332
Cited By: 1

Abstract

In this study almond leaf powder (ALP) was used as an adsorbent for the methylene blue (MB) removal. The initial MB concentration, interaction time and temperature effects were investigated in a batch experimental system. The equilibrium data was modelled using Langmuir, Freundlich and Temkin adsorption isotherms, while kinetic parameters were determined using the pseudo first order (PFO), pseudo second order (PSO) and intra-particle diffusion (IPD) models. It was noted that the Freundlich model was the most convenient option compared to the Langmuir and Temkin models. The Freundlich model coefficients increased as the temperature increased, proving that adsorption process is favorable at higher temperatures. The results also indicated that the experimental and calculated qe values were close to each other, which shows that this process fits the PSO kinetic model with higher R2 values than other two models. Kinetic constants became closer to both temperatures and the initial concentrations and qe values increased with the increase in the concentration of MB. The initial MB concentration increased from 10 to 60 mg/L, while the adsorption capacity on ALP increased from 1.46 to 9.24 mg/g, 1.61 to 9.71 mg/g and 1.89 to 10.71 mg/g for 298, 308 and 323 K, respectively. Gibbs free energy, enthalpy and entropy of this separation process were determined as -1737.1 J/mol, 14.776 kJ/mol and 55.413 J/mol, respectively. Results of this study showed that ALP can be an alternative material for dye removal.

Keywords

Almond leaf powder Dye adsorption Methylene blue Isotherm model Kinetic coefficient

Project Number

FAP-2019-8615

References

  • Peydayesh M., Rahbar-Kelishami A., Adsorption of methylene blue onto platanus orientalis leaf powder: kinetic, equilibrium and thermodynamic studies. J. Ind. Eng. Chem., 21 (2015) 1014-1019.
  • Weng C. H., Lin Y. T., Tzeng T. W., Removal of methylene blue from aqueous solution by adsorption onto pineapple leaf powder. J. Hazard. Mater., 170(1) (2009) 417-424.
  • Kallel F., Chaari F., Bouaziz F., Bettaieb F., Ghorbel R., Chaabouni S. E., Sorption and desorption characteristics for the removal of a toxic dye, methylene blue from aqueous solution by a low cost agricultural by-product. J. Mol. Liq., 219 (2016) 279-288.
  • Gupta V. K., Suhas., Application of low-cost adsorbents for dye removal – A review. J. Environ. Manage., 90 (2009) 2313-2342.
  • Yagub M. T., Sen T. K., Afroze S., Ang H. M., Dye and its removal from aqueous solution by adsorption: a review. Adv. Colloid Interface Sci., 209 (2014) 172-184.
  • Forgacs E., Cserhati T., Oros G., Removal of synthetic dyes from wastewaters: a review. Env. Int., 30 (2004) 953-971.
  • Zhou Y., Lu J., Zhou Y., Liu Y., Recent advances for dyes removal using novel adsorbents: a review. Env. Poll., 252 (2019) 352-365.
  • Bouaziz F., Koubaa M., Kallel F., Chaari F., Driss D., Ghorbel R. E., Chaabouni S. E., Efficiency of almond gum as a low-cost adsorbent for methylene blue dye removal from aqueous solutions. Ind. Crops and Products, 74 (2015) 903-911.
  • Kausar A., Iqbal M., Javeda A., Aftab K., Nazli Z. H., Bhatti H. N., Nouren S., Adsorption using clay and modified clay: a review. J. Mol. Liq., 256 (2018) 395-407.
  • Mahmoodi N. M., Hayati B., Arami M., Lan C., Adsorption of textile dyes on pine cone from colored wastewater: kinetic, equilibrium and thermodynamic studies. Desalination, 268(1-3) (2011) 117-125.
  • Debnath S., Ballav N., Maity A., Pillay K., Competitive adsorption of ternary dye mixture using pine cone powder modified with β-cyclodextrin. J. Mol. Liq., 225 (2017) 679-688.
  • Miyah Y., Lahrichi A., Idrissi M., Khalil A., Zerrouq F., Adsorption of methylene blue dye from aqueous solutions onto walnut shells powder: Equilibrium and kinetic studies. Surfaces and Interfaces, 11 (2018) 74-81.
  • Singh N. B., Nagpal G., Agrawal S., Rachna., Water purification by using adsorbents: a review. Env. Tech. & Innov., 11 (2018) 187-240.
  • Jin Y., Zeng C., Lü Q-F, Yu Y., Efficient adsorption of methylene blue and lead ions in aqueous solutions by 5-sulfosalicylic acid modified lignin. Int. J. Biol. Macromol., 123 (2019) 50-58.
  • De Gisi S., Lofrano G., Grassi M., Notarnicola M., Characteristics and adsorption capacities of low-cost sorbents for wastewater treatment: a review. Sust. Materials Tech., 9 (2016) 10-40.
  • Değermenci G. D., Değermenci N., Ayvaoğlu V., Durmaz E., Çakır D., Akan E., Adsorption of reactive dyes on lignocellulosic waste; characterization, equilibrium, kinetic and thermodynamic studies. J. Clean. Prod., 225 (2019) 1220-1229.
  • Bouaziz F., Koubaa M., Kallel F., Ghorbel R. E., Chaabouni S. E. Adsorptive removal of malachite green from aqueous solutions by almond gum: kinetic study and equilibrium isotherms. Int. J. Biol. Macromol., 105(1) (2017) 56-65.
  • Adegoke K. A., Bello, O. S., Dye sequestration using agricultural wastes as adsorbents. Water Resour. Ind., 12 (2015) 8-24.
  • Bulgariu L., Escudero L. B., Bello O. S., Iqbal M., Nisar J., Adegoke K. A., Alakhras F., Kornaros M., Anastopoulos I., The utilization of leaf-based adsorbents for dyes removal: a review. J. Mol. Liq, 276 (2019) 728-747.
  • Bedin K. C., Martins A. C., Cazetta A. L., Pezoti O., Almeida V. C., KOH-activated carbon prepared from sucrose spherical carbon: adsorption equilibrium, kinetic and thermodynamic studies for methylene blue removal. Chem. Eng. J., 286 (2016) 476-484.
  • Hamed M. M., Ahmed I. M., Metwally S. S., Adsorptive removal of methylene blue as organic pollutant by marble dust as eco-friendly sorbent. J. Ind. Eng. Chem., 20(4) (2014) 2370-2377.
  • Liu T., Li Y., Du Q., Sun J., Jiao Y., Yang G., Wang Z., Xia Y., Zhang W., Wang K., Zhu H., Wu D., Adsorption of methylene blue from aqueous solution by graphene. Colloids Surf. B Bio., 90 (2012) 197-203.
  • Ojha A. K., Bulasara V. K., Adsorption characteristics of jackfruit leaf powder for the removal of Amido black 10B dye. Env. Prog. & Sust. Energy, 34(2) (2015) 461-470.
  • Han X., Wang W., Ma X., Adsorption characteristics of methylene blue onto low cost biomass material lotus leaf. Chem. Eng. J., 171(1) (2011) 1-8.
  • Gouamid M., Ouahrani M. R., Bensaci M. B., Adsorption equilibrium, kinetics and thermodynamics of methylene blue from aqueous solutions using date palm leaves. Enrgy. Proced., 36 (2013) 898-907.
  • Setiabudi H. D., Jusoh R., Suhaimi S. F. R. M., Masrur S. F., Adsorption of methylene blue onto oil palm (Elaeis guineensis) leaves: process optimization, isotherm, kinetics and thermodynamic studies. J. Taiwan Inst. of Chem. Eng., 63 (2016) 363-370.
  • Bhattacharyya K., Sharma A., Kinetics and thermodynamics of methylene blue adsorption on neem leaf powder. Dyes and Pigments, 65(1) (2005) 51-59.
  • Franca A. S., Oliveira L. S., Ferreira M. E., Kinetics and equilibrium studies of methylene blue adsorption by spent coffee grounds. Desalination, 249(1) (2009) 267-272.
  • Rangabhashiyam S., Anu N., Nandagopal M. S. G., Selvaraju N., Relevance of isotherm models in biosorption of pollutants by agricultural by products. J. Env. Chem. Eng., 2(1) (2014) 398-414.
  • Khodabandehloo A., Rahbar-Kelishami A., Shayesteh H., Methylene blue removal using salix babylonica (weeping willow) leaves powder as a low-cost biosorbent in batch mode: Kinetic, equilibrium, and thermodynamic studies. J. Mol. Liq., 244 (2017) 540-548.
  • Rida K., Bouraoui S., Hadnine S., Adsorption of methylene blue from aqueous solution by kaolin and zeolite. App. Clay. Sci., 83 (2013) 99-105.
  • Rafatullah M., Sulaiman O., Hashim R., Ahmad A., Adsorption of methylene blue on low-cost adsorbents: a review. J. Hazard. Mater., 177(1-3) (2010) 70-80.
  • Ponnusami V., Gunasekar V., Srivastava S. N., Kinetics of methylene blue removal from aqueous solution using gulmohar (Delonix regia) plant leaf powder: Multivariate regression analysis. J. Hazard. Mater., 169 (2009) 119-127.
  • Kul A., Koyuncu H., Adsorption of Pb(II) ions from aqueous solution by native and activated bentonite: Kinetic, equilibrium and thermodynamic study. J. Hazard. Mater., 179 (2010) 332-339.
There are 34 citations in total.

Details

Primary Language English
Subjects Engineering
Journal Section Natural Sciences
Authors

Adnan Aldemir 0000-0001-9884-0961

Ali Rıza Kul 0000-0001-9331-775X

Project Number FAP-2019-8615
Publication Date September 30, 2020
Submission Date April 15, 2020
Acceptance Date July 2, 2020
Published in Issue Year 2020Volume: 41 Issue: 3

Cite

APA Aldemir, A., & Kul, A. R. (2020). Isotherm, kinetic and thermodynamic studies for the adsorption of methylene blue on almond leaf powder. Cumhuriyet Science Journal, 41(3), 651-658. https://doi.org/10.17776/csj.720332

Cited By

Removal of crystal Violet From Aqueous Solutions by A Newly Developed Adsorbent: İsotherm, Kinetics, and Thermodynamics
Journal of the Institute of Science and Technology
https://doi.org/10.21597/jist.1275258