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Year 2019, Volume: 40 Issue: 4, 928 - 938, 31.12.2019

Nilay Baylan

https://doi.org/10.17776/csj.586822
Cited By: 3

Abstract

References

  • [1] A. Keshav, K.L. Wasewar, Back extraction of propionic acid from loaded organic phase, Chemical Engineering Science, 65 (2010) 2751-2757.
  • [2] S. Kumar, B. Babu, Process intensification for separation of carboxylic acids from fermentation broths using reactive extraction, Journal on Future Engineering & Technology, 3 (2008) 19-26.
  • [3] H. Song, S.Y. Lee, Production of succinic acid by bacterial fermentation, Enzyme and Microbial Technology, 39 (2006) 352-361.
  • [4] S. Çehreli, B. Tatlı, P. Bagˇman, (Liquid+ liquid) equilibria of (water+ propionic acid+ cyclohexanone) at several temperatures, The Journal of Chemical Thermodynamics, 37 (2005) 1288-1293.
  • [5] V. Taghikhani, G. Vakili-Nezhaad, M. Khoshkbarchi, M. Shariaty-Niassar, Liquid− Liquid Equilibria of Water+ Propionic Acid+ Methyl Butyl Ketone and of Water+ Propionic Acid+ Methyl Isopropyl Ketone, Journal of Chemical & Engineering Data, 46 (2001) 1107-1109.
  • [6] A.J. Weier, B.A. Glatz, C.E. Glatz, Recovery of propionic and acetic acids from fermentation broth by electrodialysis, Biotechnology Progress, 8 (1992) 479-485.
  • [7] R.A. Diltz, T.V. Marolla, M.V. Henley, L. Li, Reverse osmosis processing of organic model compounds and fermentation broths, Bioresource Technology, 98 (2007) 686-695.
  • [8] A.H. da Silva, E.A. Miranda, Adsorption/desorption of organic acids onto different adsorbents for their recovery from fermentation broths, Journal of Chemical & engineering data, 58 (2013) 1454-1463.
  • [9] A. Freitas, M. Mendes, G. Coelho, Thermodynamic study of fatty acids adsorption on different adsorbents, The Journal of Chemical Thermodynamics, 39 (2007) 1027-1037.
  • [10] İ. İnci, Ş.S. Bayazit, H. Uslu, Investigation of adsorption equilibrium and kinetics of propionic acid and glyoxylic acid from aqueous solution by alumina, Journal of Chemical & Engineering Data, 56 (2011) 3301-3308.
  • [11] H. Uslu, İ. İnci, S.S. Bayazit, G.K. Demir, Comparison of solid− liquid equilibrium data for the adsorption of propionic acid and tartaric acid from aqueous solution onto Amberlite IRA-67, Industrial & Engineering Chemistry Research, 48 (2009) 7767-7772.
  • [12] R. Wodzki, J. Nowaczyk, M. Kujawski, Separation of propionic and acetic acid by pertraction in a multimembrane hybrid system, Separation and Purification Technology, 21 (2000) 39-54.
  • [13] A. Keshav, K.L. Wasewar, S. Chand, Reactive extraction of propionic acid using tri-n-octylamine, Chemical Engineering Communications, 197 (2009) 606-626.
  • [14] S. Kumar, D. Datta, B. Babu, Estimation of equilibrium parameters using differential evolution in reactive extraction of propionic acid by tri-n-butyl phosphate, Chemical Engineering and Processing: Process Intensification, 50 (2011) 614-622.
  • [15] H. Uslu, İ. İnci, (Liquid+ liquid) equilibria of the (water+ propionic acid+ Aliquat 336+ organic solvents) at T= 298.15 K, The Journal of Chemical Thermodynamics, 39 (2007) 804-809.
  • [16] M. Rodriguez, S. Luque, J. Alvarez, J. Coca, Extractive ultrafiltration for the removal of valeric acid, Journal of Membrane Science, 120 (1996) 35-43.
  • [17] M.O. Ruiz, J.L. Cabezas, I. Escudero, J. Coca, Valeric Acid Extraction with Tri‐N‐butyl Phosphate Impregnated in a Macroporous Resin. I. Equilibrium and Mass Transfer Rates, Separation Science and Technology, 39 (2005) 77-95.
  • [18] Z. Li, W. Qin, Y. Dai, Liquid− liquid equilibria of acetic, propionic, butyric, and valeric acids with trioctylamine as extractant, Journal of Chemical & Engineering Data, 47 (2002) 843-848.
  • [19] K. Ghandi, A review of ionic liquids, their limits and applications, Green and Sustainable Chemistry, 4 (2014) 44-53.
  • [20] K. Mikami, Green reaction media in organic synthesis, Wiley Online Library, 2005.
  • [21] L. Sprakel, B. Schuur, Solvent developments for liquid-liquid extraction of carboxylic acids in perspective, Separation and Purification Technology, 211 (2019) 935-957.
  • [22] Y.S. Aşçı, İ. İnci, Extraction equilibria of propionic acid from aqueous solutions by Amberlite LA-2 in diluent solvents, Chemical Engineering Journal, 155 (2009) 784-788.
  • [23] A. Keshav, K.L. Wasewar, S. Chand, Extraction of propionic acid with tri-n-octyl amine in different diluents, Separation and Purification Technology, 63 (2008) 179-183.
  • [24] A.I. Galaction, A. Carlescu, M. Turnea, D. Caşcaval, Direct Extraction of Propionic Acid from Propionibacterium acidipropionici Broths with Tri‐n‐octylamine, Chemical Engineering & Technology, 35 (2012) 1657-1663.
  • [25] A. Keshav, S. Chand, K.L. Wasewar, Equilibrium studies for extraction of propionic acid using tri-n-butyl phosphate in different solvents, Journal of Chemical & Engineering Data, 53 (2008) 1424-1430.
  • [26] S. Kumar, D. Datta, B. Babu, Differential evolution approach for reactive extraction of propionic acid using tri-n-butyl phosphate (TBP) in kerosene and 1-decanol, Materials and Manufacturing Processes, 26 (2011) 1222-1228.
  • [27] A. Keshav, K.L. Wasewar, S. Chand, Recovery of propionic acid from an aqueous stream by reactive extraction: Effect of diluents, Desalination, 244 (2009) 12-23.
  • [28] A. Keshav, K.L. Wasewar, S. Chand, Extraction of propionic acid using different extractants (tri-n-butylphosphate, tri-n-octylamine, and Aliquat 336), Industrial & Engineering Chemistry Research, 47 (2008) 6192-6196.
  • [29] M. Matsumoto, T. Otono, K. Kondo, Synergistic extraction of organic acids with tri-n-octylamine and tri-n-butylphosphate, Separation and Purification Technology, 24 (2001) 337-342.
  • [30] A. Keshav, K.L. Wasewar, S. Chand, Equilibrium and Kinetics of the Extraction of Propionic Acid Using Tri‐n‐Octylphosphineoxide, Chemical Engineering & Technology: Industrial Chemistry‐Plant Equipment‐Process Engineering‐Biotechnology, 31 (2008) 1290-1295.
  • [31] Y. Wang, Y. Li, Y. Li, J. Wang, Z. Li, Y. Dai, Extraction equilibria of monocarboxylic acids with trialkylphosphine oxide, Journal of Chemical & Engineering Data, 46 (2001) 831-837.
  • [32] H. Uslu, Linear solvation energy relationship (LSER) Modeling and kinetic studies on propionic acid reactive extraction using Alamine 336 in a toluene solution, Industrial & Engineering Chemistry Research, 45 (2006) 5788-5795.
  • [33] A. Keshav, K.L. Wasewar, S. Chand, Reactive extraction of propionic acid using Aliquat 336 in MIBK: Linear solvation energy relationship (LSER) modeling and kinetics study, Journal of Scientific and Industrial Research 2009; 68: 708-713.
  • [34] A. Keshav, K. Wasewar, S. Chand, H. Uslu, Reactive extraction of propionic acid using Aliquat-336 in 2-octanol: Linear solvation energy relationship (LSER) modeling and kinetics study, Chemical and Biochemical Engineering Quarterly, 24 (2010) 67-73.
  • [35] K. Wang, Z. Chang, Y. Ma, C. Lei, S. Jin, Y. Wu, I. Mahmood, C. Hua, H. Liu, Equilibrium study on reactive extraction of propionic acid with N1923 in different diluents, Fluid Phase Equilibria, 278 (2009) 103-108.
  • [36] N. Baylan, S. Çehreli, Ionic liquids as bulk liquid membranes on levulinic acid removal: A design study, Journal of Molecular Liquids, 266 (2018) 299-308.
  • [37] N. Baylan, S. Çehreli, Removal of acetic acid from aqueous solutions using bulk ionic liquid membranes: A transport and experimental design study, Separation and Purification Technology, 224 (2019) 51-61.
  • [38] D. Granato, V.M. de Araújo Calado, The use and importance of design of experiments (DOE) in process modelling in food science and technology, Mathematical and statistical methods in food science and technology, 1 (2014) 1-18.
  • [39] İ. İnci, Linear solvation energy relationship modeling and kinetic studies on reactive extraction of succinic acid by tridodecylamine dissolved in MIBK, Biotechnology Progress, 23 (2007) 1171-1179.
  • [40] C.-C. Chen, K.-T. Chiang, C.-C. Chou, Y.-C. Liao, The use of D-optimal design for modeling and analyzing the vibration and surface roughness in the precision turning with a diamond cutting tool, The International Journal of Advanced Manufacturing Technology, 54 (2011) 465-478.
  • [41] M.D. Turan, Statistical Approach to Mineral Engineering and Optimization, Contributions to Mineralization, IntechOpen, 2018.
  • [42] A. Asghar, A. Raman, A. Aziz, W.M.A.W. Daud, A comparison of central composite design and Taguchi method for optimizing Fenton process, The Scientific World Journal, 2014 (2014) 1-14.
  • [43] T. Rajmohan, K. Palanikumar, Modeling and analysis of performances in drilling hybrid metal matrix composites using D-optimal design, The International Journal of Advanced Manufacturing Technology, 64 (2013) 1249-1261.
  • [44] M. Djas, M. Henczka, Reactive extraction of carboxylic acids using organic solvents and supercritical fluids: a review, Separation and Purification Technology, 201 (2018) 106-119.
  • [45] K.L. Wasewar, D. Shende, A. Keshav, Reactive extraction of itaconic acid using tri‐n‐butyl phosphate and aliquat 336 in sunflower oil as a non‐toxic diluent, Journal of Chemical Technology & Biotechnology, 86 (2011) 319-323.
  • [46] K.K. Athankar, K.L. Wasewar, M.N. Varma, D.Z. Shende, Reactive extraction of gallic acid with tri-n-caprylylamine, New Journal of Chemistry, 40 (2016) 2413-2417.

Reactive Extraction of Propionic Acid Using Tributyl Phosphate in Imidazolium-Based Ionic Liquids: Optimization Study Using Response Surface Methodology

Year 2019, Volume: 40 Issue: 4, 928 - 938, 31.12.2019

Nilay Baylan

https://doi.org/10.17776/csj.586822
Cited By: 3

Abstract

In this work, the reactive extraction of propionic acid from aqueous solutions
using imidazolium-based ionic liquids was examined. Ionic liquids,
1-butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide ([BMIM][Tf2N]),
and 1-butyl-3-methylimidazolium hexafluorophosphate ([BMIM][PF6])
were utilized as diluents. Tributyl phosphate (TBP) as an extractant in ionic
liquids was used. D-optimal design based on the response surface methodology
(RSM) has been exerted to specify the effect of different variables on the
reactive extraction process. Initial propionic acid concentration (2-10% w/w),
extractant (TBP) concentration (0-3.00 mol.L-1) and temperature
(25-45 ℃) were chosen as numerical variables, and type of ionic liquid was
chosen as a categorical variable. Extraction efficiency, selected as a
dependent variable, was calculated from the experimental data. In addition to,
the model equation for the extraction efficiency was created. The optimum
extraction conditions were obtained as the initial propionic acid concentration
of approximately 5% (w/w), TBP concentration in ionic liquids of 3 mol.L-1
and temperature of 45○C. Under these conditions,
the values of extraction efficiency were determined as 85.64% for [BMIM][PF6],
and 81.91% for [BMIM][Tf2N]. This study has indicated that the
systems of TBP in ionic liquids is an efficient and green reactive extraction
method for the removal of propionic acid from the aqueous media.

Keywords

Propionic acid Imidazolium-Based Ionic Liquids Tributyl phosphate Reactive extraction Response surface methodology.

References

  • [1] A. Keshav, K.L. Wasewar, Back extraction of propionic acid from loaded organic phase, Chemical Engineering Science, 65 (2010) 2751-2757.
  • [2] S. Kumar, B. Babu, Process intensification for separation of carboxylic acids from fermentation broths using reactive extraction, Journal on Future Engineering & Technology, 3 (2008) 19-26.
  • [3] H. Song, S.Y. Lee, Production of succinic acid by bacterial fermentation, Enzyme and Microbial Technology, 39 (2006) 352-361.
  • [4] S. Çehreli, B. Tatlı, P. Bagˇman, (Liquid+ liquid) equilibria of (water+ propionic acid+ cyclohexanone) at several temperatures, The Journal of Chemical Thermodynamics, 37 (2005) 1288-1293.
  • [5] V. Taghikhani, G. Vakili-Nezhaad, M. Khoshkbarchi, M. Shariaty-Niassar, Liquid− Liquid Equilibria of Water+ Propionic Acid+ Methyl Butyl Ketone and of Water+ Propionic Acid+ Methyl Isopropyl Ketone, Journal of Chemical & Engineering Data, 46 (2001) 1107-1109.
  • [6] A.J. Weier, B.A. Glatz, C.E. Glatz, Recovery of propionic and acetic acids from fermentation broth by electrodialysis, Biotechnology Progress, 8 (1992) 479-485.
  • [7] R.A. Diltz, T.V. Marolla, M.V. Henley, L. Li, Reverse osmosis processing of organic model compounds and fermentation broths, Bioresource Technology, 98 (2007) 686-695.
  • [8] A.H. da Silva, E.A. Miranda, Adsorption/desorption of organic acids onto different adsorbents for their recovery from fermentation broths, Journal of Chemical & engineering data, 58 (2013) 1454-1463.
  • [9] A. Freitas, M. Mendes, G. Coelho, Thermodynamic study of fatty acids adsorption on different adsorbents, The Journal of Chemical Thermodynamics, 39 (2007) 1027-1037.
  • [10] İ. İnci, Ş.S. Bayazit, H. Uslu, Investigation of adsorption equilibrium and kinetics of propionic acid and glyoxylic acid from aqueous solution by alumina, Journal of Chemical & Engineering Data, 56 (2011) 3301-3308.
  • [11] H. Uslu, İ. İnci, S.S. Bayazit, G.K. Demir, Comparison of solid− liquid equilibrium data for the adsorption of propionic acid and tartaric acid from aqueous solution onto Amberlite IRA-67, Industrial & Engineering Chemistry Research, 48 (2009) 7767-7772.
  • [12] R. Wodzki, J. Nowaczyk, M. Kujawski, Separation of propionic and acetic acid by pertraction in a multimembrane hybrid system, Separation and Purification Technology, 21 (2000) 39-54.
  • [13] A. Keshav, K.L. Wasewar, S. Chand, Reactive extraction of propionic acid using tri-n-octylamine, Chemical Engineering Communications, 197 (2009) 606-626.
  • [14] S. Kumar, D. Datta, B. Babu, Estimation of equilibrium parameters using differential evolution in reactive extraction of propionic acid by tri-n-butyl phosphate, Chemical Engineering and Processing: Process Intensification, 50 (2011) 614-622.
  • [15] H. Uslu, İ. İnci, (Liquid+ liquid) equilibria of the (water+ propionic acid+ Aliquat 336+ organic solvents) at T= 298.15 K, The Journal of Chemical Thermodynamics, 39 (2007) 804-809.
  • [16] M. Rodriguez, S. Luque, J. Alvarez, J. Coca, Extractive ultrafiltration for the removal of valeric acid, Journal of Membrane Science, 120 (1996) 35-43.
  • [17] M.O. Ruiz, J.L. Cabezas, I. Escudero, J. Coca, Valeric Acid Extraction with Tri‐N‐butyl Phosphate Impregnated in a Macroporous Resin. I. Equilibrium and Mass Transfer Rates, Separation Science and Technology, 39 (2005) 77-95.
  • [18] Z. Li, W. Qin, Y. Dai, Liquid− liquid equilibria of acetic, propionic, butyric, and valeric acids with trioctylamine as extractant, Journal of Chemical & Engineering Data, 47 (2002) 843-848.
  • [19] K. Ghandi, A review of ionic liquids, their limits and applications, Green and Sustainable Chemistry, 4 (2014) 44-53.
  • [20] K. Mikami, Green reaction media in organic synthesis, Wiley Online Library, 2005.
  • [21] L. Sprakel, B. Schuur, Solvent developments for liquid-liquid extraction of carboxylic acids in perspective, Separation and Purification Technology, 211 (2019) 935-957.
  • [22] Y.S. Aşçı, İ. İnci, Extraction equilibria of propionic acid from aqueous solutions by Amberlite LA-2 in diluent solvents, Chemical Engineering Journal, 155 (2009) 784-788.
  • [23] A. Keshav, K.L. Wasewar, S. Chand, Extraction of propionic acid with tri-n-octyl amine in different diluents, Separation and Purification Technology, 63 (2008) 179-183.
  • [24] A.I. Galaction, A. Carlescu, M. Turnea, D. Caşcaval, Direct Extraction of Propionic Acid from Propionibacterium acidipropionici Broths with Tri‐n‐octylamine, Chemical Engineering & Technology, 35 (2012) 1657-1663.
  • [25] A. Keshav, S. Chand, K.L. Wasewar, Equilibrium studies for extraction of propionic acid using tri-n-butyl phosphate in different solvents, Journal of Chemical & Engineering Data, 53 (2008) 1424-1430.
  • [26] S. Kumar, D. Datta, B. Babu, Differential evolution approach for reactive extraction of propionic acid using tri-n-butyl phosphate (TBP) in kerosene and 1-decanol, Materials and Manufacturing Processes, 26 (2011) 1222-1228.
  • [27] A. Keshav, K.L. Wasewar, S. Chand, Recovery of propionic acid from an aqueous stream by reactive extraction: Effect of diluents, Desalination, 244 (2009) 12-23.
  • [28] A. Keshav, K.L. Wasewar, S. Chand, Extraction of propionic acid using different extractants (tri-n-butylphosphate, tri-n-octylamine, and Aliquat 336), Industrial & Engineering Chemistry Research, 47 (2008) 6192-6196.
  • [29] M. Matsumoto, T. Otono, K. Kondo, Synergistic extraction of organic acids with tri-n-octylamine and tri-n-butylphosphate, Separation and Purification Technology, 24 (2001) 337-342.
  • [30] A. Keshav, K.L. Wasewar, S. Chand, Equilibrium and Kinetics of the Extraction of Propionic Acid Using Tri‐n‐Octylphosphineoxide, Chemical Engineering & Technology: Industrial Chemistry‐Plant Equipment‐Process Engineering‐Biotechnology, 31 (2008) 1290-1295.
  • [31] Y. Wang, Y. Li, Y. Li, J. Wang, Z. Li, Y. Dai, Extraction equilibria of monocarboxylic acids with trialkylphosphine oxide, Journal of Chemical & Engineering Data, 46 (2001) 831-837.
  • [32] H. Uslu, Linear solvation energy relationship (LSER) Modeling and kinetic studies on propionic acid reactive extraction using Alamine 336 in a toluene solution, Industrial & Engineering Chemistry Research, 45 (2006) 5788-5795.
  • [33] A. Keshav, K.L. Wasewar, S. Chand, Reactive extraction of propionic acid using Aliquat 336 in MIBK: Linear solvation energy relationship (LSER) modeling and kinetics study, Journal of Scientific and Industrial Research 2009; 68: 708-713.
  • [34] A. Keshav, K. Wasewar, S. Chand, H. Uslu, Reactive extraction of propionic acid using Aliquat-336 in 2-octanol: Linear solvation energy relationship (LSER) modeling and kinetics study, Chemical and Biochemical Engineering Quarterly, 24 (2010) 67-73.
  • [35] K. Wang, Z. Chang, Y. Ma, C. Lei, S. Jin, Y. Wu, I. Mahmood, C. Hua, H. Liu, Equilibrium study on reactive extraction of propionic acid with N1923 in different diluents, Fluid Phase Equilibria, 278 (2009) 103-108.
  • [36] N. Baylan, S. Çehreli, Ionic liquids as bulk liquid membranes on levulinic acid removal: A design study, Journal of Molecular Liquids, 266 (2018) 299-308.
  • [37] N. Baylan, S. Çehreli, Removal of acetic acid from aqueous solutions using bulk ionic liquid membranes: A transport and experimental design study, Separation and Purification Technology, 224 (2019) 51-61.
  • [38] D. Granato, V.M. de Araújo Calado, The use and importance of design of experiments (DOE) in process modelling in food science and technology, Mathematical and statistical methods in food science and technology, 1 (2014) 1-18.
  • [39] İ. İnci, Linear solvation energy relationship modeling and kinetic studies on reactive extraction of succinic acid by tridodecylamine dissolved in MIBK, Biotechnology Progress, 23 (2007) 1171-1179.
  • [40] C.-C. Chen, K.-T. Chiang, C.-C. Chou, Y.-C. Liao, The use of D-optimal design for modeling and analyzing the vibration and surface roughness in the precision turning with a diamond cutting tool, The International Journal of Advanced Manufacturing Technology, 54 (2011) 465-478.
  • [41] M.D. Turan, Statistical Approach to Mineral Engineering and Optimization, Contributions to Mineralization, IntechOpen, 2018.
  • [42] A. Asghar, A. Raman, A. Aziz, W.M.A.W. Daud, A comparison of central composite design and Taguchi method for optimizing Fenton process, The Scientific World Journal, 2014 (2014) 1-14.
  • [43] T. Rajmohan, K. Palanikumar, Modeling and analysis of performances in drilling hybrid metal matrix composites using D-optimal design, The International Journal of Advanced Manufacturing Technology, 64 (2013) 1249-1261.
  • [44] M. Djas, M. Henczka, Reactive extraction of carboxylic acids using organic solvents and supercritical fluids: a review, Separation and Purification Technology, 201 (2018) 106-119.
  • [45] K.L. Wasewar, D. Shende, A. Keshav, Reactive extraction of itaconic acid using tri‐n‐butyl phosphate and aliquat 336 in sunflower oil as a non‐toxic diluent, Journal of Chemical Technology & Biotechnology, 86 (2011) 319-323.
  • [46] K.K. Athankar, K.L. Wasewar, M.N. Varma, D.Z. Shende, Reactive extraction of gallic acid with tri-n-caprylylamine, New Journal of Chemistry, 40 (2016) 2413-2417.
There are 46 citations in total.

Details

Primary Language English
Journal Section Natural Sciences
Authors

Nilay Baylan 0000-0002-2910-495X

Publication Date December 31, 2019
Submission Date July 4, 2019
Acceptance Date October 12, 2019
Published in Issue Year 2019Volume: 40 Issue: 4

Cite

APA Baylan, N. (2019). Reactive Extraction of Propionic Acid Using Tributyl Phosphate in Imidazolium-Based Ionic Liquids: Optimization Study Using Response Surface Methodology. Cumhuriyet Science Journal, 40(4), 928-938. https://doi.org/10.17776/csj.586822

Cited By

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Optimization of feed and extractant concentration for the liquid–liquid extraction of volatile fatty acids from synthetic solution and landfill leachate
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Sameena Begum
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Imidazolium-Based Ionic Liquids for Acrylic Acid Separation from Water by Bulk Liquid Membrane and Extraction Methods: A Comparison Study
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Nilay Baylan
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