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Seryum, Demir ve Bakır Emdirmenin, Ti-Sütunlu Bentonitlerin Yapısal Özellikleri ve Aktiviteleri Üzerine Etkileri

Year 2018, Volume: 39 Issue: 2, 477 - 495, 29.06.2018
https://doi.org/10.17776/csj.343221

Abstract

Orta
Anadolu yöresi (Hançılı) bentoniti kullanılarak, Ti-sütunlu bentonit (Ti-SB)
sentezlenmiştir. Ti-SB’e demir ya da bakır, çözeltiden emdirilmiş ve devamında
seryum, ıslak emdirmeyle demirli ve bakırlı Ti-SB’e ilave edilmiştir. B
akırlı
titanyumlu sütunlu bentonitler, Cu/(Cu+Ti) 0,1 ve 0,2 oranlarında hidrotermal
olarak sentezlenmiştir. Bütün numunelerde titanyum dioksit, anataz fazda
görülmüştür.
500 °C de kalsine
edilmiş Ti-SB için 4.41 nm bazal boşluk değeri, 348 m2 g-1
spesifik BET yüzey alanı, 0.093 cm3g-1 mikrogözenek hacim
değeri elde edilmiştir.  Demir ve bakırın
sonradan ilave edilmesi, elde edilen örneklerin mikrogözenek özelliklerinde
azalmaya sebep olurken, hidrotermal yöntemle sentezlenen bakır titanyumlu örnekler,
Ti-SB ile benzer davranış sergilemişlerdir. 
Enerji dağılımlı X-ışını spektroskopisi (EDS) analizi, bütün örneklerin
TiO2 içeriğinin ağırlıkça yaklaşık % 40 civarında olduğunu ve
Ti-SB’e metal emdirmenin başarılı bir şekilde gerçekleştiğini göstermiştir.
Ti-SB örneklerinde hem Lewis hem de
Brønsted asitliği gözlenmiştir. Bakır emdirme, Lewis asitlikte artışa
neden olmuştur. Hidrotermal olarak sentezlenmiş bakır içeren örneklerde, seryum
demir ve seryum bakırlı örneklerde Bronsted asitliğinin arttığı gözlenmiştir.
Seryum ve demir içeren örnekle gerçekleştirilen reaksiyon çalışmalarında
yaklaşık % 90 fenol dönüşümü, 30
°C de 1 saat içinde elde edilmiş ve fotokatalitik oksidasyonun
tamamlanması 2 saatde gerçekleşmiştir. Sıcaklığın artması, fenol dönüşümünü
artırmış ve demir içeren örnekle,
50 °C de 1 saat içinde yaklaşık % 100 dönüşüm elde
edilmiştir. Hidrokinon, benzokinon, katekol ve formic, malik, fumarik asitler
reaksiyon ara ürünleri olarak gözlenmiştir. Düşük değerlerde metal salınımı ve
demirin bakıra göre 6 kat daha fazla kararlılık gösterdiği gözlenmiştir. 

References

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Effects of Cerium, Iron and Copper Incorporation on the Structural Properties and Activities of Ti-Pillared Bentonites

Year 2018, Volume: 39 Issue: 2, 477 - 495, 29.06.2018
https://doi.org/10.17776/csj.343221

Abstract

Ti-pillared
bentonite (
Ti-PB) using bentonite from the Middle Anatolia region
(Hançılı) was synthesized. Iron or copper was
impregnated to Ti-PB from the solution and subsequent cerium
incorporation was done by wet impregnation.
The hydrothermal syntheses were carried out with a Cu/(Cu+Ti)
ratios
of 0.1
and 0.2. T
he anatase phase of titanium dioxide was found for all of
the samples. The Ti-PB calcined at 500
°C gave a basal spacing value of 4.41 nm, a specific BET surface area of 348 m2
g-1, and a micropore volume of 0.093 cm3g-1.
While the post
incorporation of copper and iron caused decrease in the micropore properties,
the hydrothermally synthesized copper titanium samples reflected the similar
behavior with Ti-PB. E
nergy dispersive X-ray spectroscopy (EDS) analyses
indicated that
TiO2 content of all PBs was near 40 wt % and metal
incorporation to Ti-PB was succesfully performed by the impregnation method.
Ti-PB exhibited both
the Lewis and Brønsted acidities. The copper impregnation
resulted in an increase in the Lewis
acidity.
The hydrotermally synthesised copper containing
sample and cerium-iron and cerium-copper impregnated samples yielded an
increase in the Br
ønsted acidity. Approximately 90 % phenol conversion at 30 °C in an hour was achived with the cerium and iron containing sample and the completion of photocatalytic
oxidation was reached at 2 hours. An increase of temperature rised the
conversion of phenol,
and the iron
containing sample resulted in approximately 100 % conversion at an hour at 50
°C.
Hydroquinone, benzoquinone and catechol and
formic, malic, fumaric acids were observed as the reaction intermediates. The
leaching of metals was observed at low values and the stability of iron was
found six times higher than the copper.

References

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  • [29] Li Z., Sheng J., Zhang Y., Li X. and Xu Y., Role of CeO2 as oxygen promoter in the accelerated photocatalytic degradation of phenol over rutile TiO2, Appl. Catal. B Environ., 166-167 (2015) 313-319.
  • [30] Mnasri-Ghnimi S. and Frini-Srasra N., Effect of Al and Ce on Zr-pillared bentonite and their performance in catalytic oxidation of phenol, Russian J. Phys. Chem. A, 90-9 (2016) 1766-1773.
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There are 60 citations in total.

Details

Primary Language English
Journal Section Engineering Sciences
Authors

Funda Turgut Başoğlu

Publication Date June 29, 2018
Submission Date October 13, 2017
Acceptance Date April 27, 2018
Published in Issue Year 2018Volume: 39 Issue: 2

Cite

APA Turgut Başoğlu, F. (2018). Effects of Cerium, Iron and Copper Incorporation on the Structural Properties and Activities of Ti-Pillared Bentonites. Cumhuriyet Science Journal, 39(2), 477-495. https://doi.org/10.17776/csj.343221