Investigation of the thermoluminescence properties Ti4+ doped MgO synthesized solid-state assisted solution combustion synthesis method
Abstract
In this study, undoped MgO and titanium (Ti4+) doped MgO ceramics were synthesized using the solid state-assisted solution combustion synthesis method. The structural characteristics were investigated using X-ray diffraction (XRD) and scanning electron microscope (SEM). TL curves of the MgO:Ti4+(0.1%wt) ceramic consist of three TL peaks located at 70, 250 and 290 oC with a heating rate of 2 oC/s after 1 Gy beta dose. Radioluminescence (RL) characteristic of the MgO:Ti4+(0.1%wt) ceramic was studied with excitations between 200 - 1000 nm. It was found to be the four emission bands the maximums located at 327 nm (~3.79 eV), 694 nm (~1.78 eV), 715 (~1.73 eV), and 745 (~1.66 eV). Some dosimetric characteristics such as TL curve, reusability, dose-response, of the ceramic were investigated using the thermoluminescence (TL) technique using beta radiation of 90Sr/90Y. Dose-response characteristics showed the integrated TL signals between 170-350 oC exhibited a linear up to 20 Gy. The experimental results showed that if it is developed of the MgO:Ti4+(0.1%wt) ceramic can be considered as a dosimetric material with suitable properties in personal and medical applications.
Keywords
Thermoluminescence dosimetry Titanium doped Magnesium oxide radioluminescence beta dose response
Supporting Institution
North Atlantic Treaty Organization (NATO)
Project Number
G5647
Thanks
This research was supported by the NATO Science for Peace and Security program (G5647).
References
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- [7] Wang W., Qiao X., Chen J., Tan F., Li H., Influence of titanium doping on the structure and morphology of MgO prepared by coprecipitation method, Mater. Charac., 60 (2009) 858-862.
- [8] Bokhimi X, Boldú J,Munoz E., Novaro O.,, López T, Hernández J., Gómez R., García-Ruiz A., Structure and composition of the nanocrystalline phases in a MgO− TiO2 system prepared via Sol− Gel technique, Chem. Mater., 11 (1999) 2716-2721.
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- [10] Furetta C, Handbook of thermoluminescence, Singapore: World Scientific, (2010).
Abstract
Project Number
G5647
References
- [1] Alajerami Y., Hashim S., Ghoshal S., Saleh S., Kadni T.,Saripan M., Alzimami K., Ibrahim Z., Bradley D., The effect of TiO2 and MgO on the thermoluminescence properties of a lithium potassium borate glass system, J. Phys. Chem. Solıds., 74 (2013) 1816-1822.
- [2] Barrón V.R.O., Ochoa F.M.E,. Vázquez C.C., Bernal R., Thermoluminescence of novel MgO–CeO2 obtained by a glycine-based solution combustion method, Appl. Radıat. Isotopes., 117 (2016) 86-90.
- [3] Guckan V., Altunal V. Ozdemir A., Yegingil. Z., Optically stimulated luminescence of MgO:Na,Li phosphor prepared using solution combustion method, J. Alloy. Compd., 835 (2020) 155253.
- [4] Mofokeng S., Noto L., Mlotswa D., Orante-Barrón V., Dhlamini M., Thermoluminescence properties of MgO:Al3+,Li+ prepared by microwave-assisted solution combustion method, Physica B., (2020) 412008.
- [5] Oliveira L., Yukihara E, Baffa O., Lanthanide-doped MgO: A case study on how to design new phosphors for dosimetry with tailored luminescent properties, J. Lumin., 209 (2019) 21-30.
- [6] Rao R., Duley W., Preparation and luminescence of MgO:Tb phosphors, J. Mater. sci, 27 (1992) 5883-5886.
- [7] Wang W., Qiao X., Chen J., Tan F., Li H., Influence of titanium doping on the structure and morphology of MgO prepared by coprecipitation method, Mater. Charac., 60 (2009) 858-862.
- [8] Bokhimi X, Boldú J,Munoz E., Novaro O.,, López T, Hernández J., Gómez R., García-Ruiz A., Structure and composition of the nanocrystalline phases in a MgO− TiO2 system prepared via Sol− Gel technique, Chem. Mater., 11 (1999) 2716-2721.
- [9] Orante-Barrón V., Oliveira L, Kelly J., Milliken E., Denis G, Jacobsohn L., Puckette J., Yukihara E., Luminescence properties of MgO produced by solution combustion synthesis and doped with lanthanides and Li, J. Lumin., 131 (2011) 1058-1065.
- [10] Furetta C, Handbook of thermoluminescence, Singapore: World Scientific, (2010).
Details
| Primary Language | English |
|---|---|
| Subjects | Classical Physics (Other) |
| Journal Section | Natural Sciences |
| Authors | |
| Project Number | G5647 |
| Publication Date | March 29, 2021 |
| Submission Date | May 14, 2020 |
| Acceptance Date | January 19, 2021 |
| Published in Issue | Year 2021 |