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The Development of pH Modulated Solidified Homogeneous Liquid Phase Microextraction Methodology for Preconcentration and Determination of Nickel in Water Samples

Year 2019, , 917 - 925, 31.12.2019

Demirhan Çıtak , Rabia Demirok

https://doi.org/10.17776/csj.642319
Cited By: 1

Abstract

Abstract: In this work, a new, fast and green pH assisted
solidified homogeneous liquid phase microextraction method (pH-MS-HLPME) was
developed. Initially, the complex formation of Ni-1-Phenylthiosemicarbazide
(Ni-PTC) and the dissolution of the extraction solvent (caprylic acid) in water
were achieved by addition of NaOH. After base addition caprylic acid (CA)
become completely soluble as sodium caprylate in model solution. The phase
separation of extraction solvent was accessed by addition of HCl. The analyse
of nickel concentrations was carried out by micro-sampler adapted flame atomic
absorption spectrometer. Under optimized parameters, linear range (10.0-450 μg
L-1), detection limit (3.2 μg L-1), limit of quantification (10.0 μg L-1),
relative standard deviation (2.0 %), relative error (-3.9 %), and
preconcentration factor (45) were calculated, respectively. Finally, the
developed pH-MS -HLPME methodology was successfully applied to LGC 6010 hard
drinking water (CRM) and some water samples.

Keywords

nickel pH liquid phase microextraction drinking water samples microsampler system

Supporting Institution

Tokat Gaziosmanpaşa Üniversitesi Bilimsel Araştırma Projeleri Birimi

Project Number

2018/41

Thanks

The authors are grateful for the financial support of the Unit of the Scientific Research Projects of Tokat Gaziosmanpaşa University (project number: 2018/41).

References

  • [1] Barreto J.A., dos Santos de Assis R., Cassella, R.J., and Lemos, V.A., A novel strategy based on in-syringe dispersive liquid-liquid microextraction for the determination of nickel in chocolate samples, Talanta, 193 (2019) 23–28.
  • [2] Zdrojewicz Z., Popowicz E., and Winiarski J., Nickel - role in human organism and toxic effects, Polski Merkuriusz Lekarski : Organ Polskiego Towarzystwa Lekarskiego, (2016) 115–118.
  • [3] Baytak S., and Türker A., Determination of lead and nickel in environmental samples by flame atomic absorption spectrometry after column solid-phase extraction on Ambersorb-572 with EDTA. Journal of Hazardous Materials, 129-1,3 (2006) 130–136.
  • [4] Arkhipova A.A., Statkus M.A., Tsizin G.I., and Zolotov Y.A., Preconcentration of elements as hydrophobic complexes with low-polar adsorbents, Journal of Analytical Chemistry, 70-12 (2015) 1413–1431.
  • [5] Hashemi B., Zohrabi P., Kim K.H., Shamsipur M., Deep, A., and Hong J., Recent advances in liquid-phase microextraction techniques for the analysis of environmental pollutants, TrAC Trends in Analytical Chemistry, 97 (2017) 83–95.
  • [6] Lemos V., Baliza P., Santos J., Nunes L., Jesus A., and Rocha M., A new functionalized resin and its application in preconcentration system with multivariate optimization for nickel determination in food samples, Talanta, 66-1 (2005) 174–180.
  • [7] Yalçın M.S., Özdemir S., and Kılınç E., Preconcentrations of Ni(II) and Co(II) by using immobilized thermophilic Geobacillus stearothermophilus SO-20 before ICP-OES determinations, Food Chemistry, 266 (2018) 126–132.
  • [8] Naghizadeh M., Taher M.A., Abadi L.Z., and Moghaddam F.H., Synthesis, characterization and theoretical investigation of magnetite nanoclay modified as a new nanocomposite for simultaneous preconcentration of lead and nickel prior to ETAAS determination, Environmental Nanotechnology, Monitoring & Management, 7 (2017) 46–56. [9] ALOthman Z.A., Habila M.A., Yilmaz E., Soylak M., and Alfadul S.M., Ultrasonic supramolecular microextration of nickel (II) as N,N′-Dihydroxy-1,2-cyclohexanediimine chelates from water, tobacco and fertilizer samples before FAAS determination, Journal of Molecular Liquids, 221 (2016) 773–777.
  • [10] He Y. and Lee H.K., Liquid-Phase Microextraction in a Single Drop of Organic Solvent by Using a Conventional Microsyringe. Analytical Chemistry, 69-22 (1997) 4634–4640.
  • [11] Rykowska I., Ziemblińska J., and Nowak I., Modern approaches in dispersive liquid-liquid microextraction (DLLME) based on ionic liquids: A review, Journal of Molecular Liquids, 259 (2018) 319–339.
  • [12] De Almeida O.N., Luzardo F.H.M., Amorim F.A.C., Velasco F.G., and González L.N., Use of fiberglass support in the application of dried-spot technique with dispersion liquid-liquid microextraction for the determination of Co, Cr, Cu, Ni and Pb by Energy Dispersive X-Ray Fluorescence Spectrometry, Spectrochimica Acta Part B: Atomic Spectroscopy, 150 (2018) 92–98.
  • [13] Kocot K., Pytlakowska K., Zawisza B., and Sitko R., How to detect metal species preconcentrated by microextraction techniques, TrAC Trends in Analytical Chemistry, 82 (2016) 412–424.
  • [14] Giakisikli G. and Anthemidis A.N., An automatic stirring-assisted liquid–liquid microextraction system based on lab-in-syringe platform for on-line atomic spectrometric determination of trace metals, Talanta, 166 (2017) 364–368.
  • [15] Habila M.A., Yilmaz E., ALOthman Z.A., and Soylak M., Combination of dispersive liquid–liquid microextraction and multivariate optimization for separation-enrichment of traces lead by flame atomic absorption spectrometry, Journal of Industrial and Engineering Chemistry, 37 (2016) 306–311.
  • [16] Zhang S., Chen B., He M., and Hu B., Switchable solvent based liquid phase microextraction of trace lead and cadmium from environmental and biological samples prior to graphite furnace atomic absorption spectrometry detection, Microchemical Journal, 139 (2018) 380–385.
  • [17] Biata N.R., Nyaba L., Ramontja J., Mketo N., and Nomngongo P.N., Determination of antimony and tin in beverages using inductively coupled plasma-optical emission spectrometry after ultrasound-assisted ionic liquid dispersive liquid-liquid phase microextraction, Food Chemistry, 237 (2017) 904–911.
  • [18] Khazaeli E., Haddadi H., Zargar B., Hatamie A., and Semnani A., Ni(II) analysis in food and environmental samples by liquid-liquid microextraction combined with electro-thermal atomic absorption spectrometry, Microchemical Journal, 133 (2017) 311–319.
  • [19] Altunay N., Yıldırım E., and Gürkan R., Extraction and preconcentration of trace Al and Cr from vegetable samples by vortex-assisted ionic liquid-based dispersive liquid–liquid microextraction prior to atomic absorption spectrometric determination, Food Chemistry, 245 (2018) 586–594.
  • [20] Manzoori J.L., Amjadi M., and Abulhassani, J., Ultra-trace determination of lead in water and food samples by using ionic liquid-based single drop microextraction-electrothermal atomic absorption spectrometry, Analytica Chimica Acta, 644-1,2 (2009) 48–52.
  • [21] Xia L., Li, X., Wu Y., Hu B., and Chen R., Ionic liquids based single drop microextraction combined with electrothermal vaporization inductively coupled plasma mass spectrometry for determination of Co, Hg and Pb in biological and environmental samples. Spectrochimica Acta Part B: Atomic Spectroscopy, 63-11 (2008) 1290–1296.
  • [22] Dadfarnia S., and Haji Shabani A.M., Recent development in liquid phase microextraction for determination of trace level concentration of metals—A review, Analytica Chimica Acta, 658-2 (2010) 107–119.
  • [23] Jiang H., Hu B., Chen B., and Xia L., Hollow fiber liquid phase microextraction combined with electrothermal atomic absorption spectrometry for the speciation of arsenic (III) and arsenic (V) in fresh waters and human hair extracts, Analytica Chimica Acta, 634-1 (2009) 15–21.
  • [24] Ghambarian M., Yamini Y., and Esrafili A., Developments in hollow fiber based liquid-phase microextraction: principles and applications, Microchimica Acta, 177-3 (2012) 271–294.
  • [25] Shamsipur M., Ramezani M., and Miran Beigi A.A., Floating Organic Drop Microextraction Combined with Electrothermal Atomic Absorption Spectrometry for Trace Determination of Cobalt in Oil Refining Wastewaters, Energy Sources, Part A: Recovery, Utilization, and Environmental Effects, 37-11 (2015) 1164–1171.
  • [26] Mohammadi S.Z., Sheibani A., Abdollahi F., and Shahsavani E., Speciation of Tl(III) and Tl(I) in hair samples by dispersive liquid–liquid microextraction based on solidification of floating organic droplet prior to flame atomic absorption spectrometry determination, Arabian Journal of Chemistry, 9 (2016) 1510–S1515.
  • [27] Haji Shabani A.M., Dadfarnia S., and Nozohor M., Indirect spectrophotometric determination of ultra trace amounts of selenium based on dispersive liquid–liquid microextraction–solidified floating organic drop, Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 116 (2013) 1–5.
  • [28] Karadaş, C., and Kara, D., Dispersive liquid–liquid microextraction based on solidification of floating organic drop for preconcentration and determination of trace amounts of copper by flame atomic absorption spectrometry, Food Chemistry, 220 (2017) 242–248.
  • [29] Mohamadi M., and Mostafavi A., A novel solidified floating organic drop microextraction based on ultrasound-dispersion for separation and preconcentration of palladium in aqueous samples. Talanta, 81-2 (2010) 309–313.
  • [30] Pérez-Outeiral J., Millán E., and Garcia-Arrona, R., Determination of phthalates in food simulants and liquid samples using ultrasound-assisted dispersive liquid–liquid microextraction followed by solidification of floating organic drop, Food Control, 62 (2016) 171–177.
  • [31] Pelit F.O. and Yengin Ç., Application of solidified floating organic drop microextraction method for biomonitoring of chlorpyrifos and its oxon metabolite in urine samples, Journal of Chromatography B, 949–950 (2014) 109–114.
  • [32] Mansour F.R. and Danielson N.D., Solidification of floating organic droplet in dispersive liquid-liquid microextraction as a green analytical tool, Talanta, 170 (2017) 22–35.
  • [33] Mirzaei M., Behzadi M., Abadi N.M., and Beizaei A., Simultaneous separation/preconcentration of ultra trace heavy metals in industrial wastewaters by dispersive liquid–liquid microextraction based on solidification of floating organic drop prior to determination by graphite furnace atomic absorption spectrometer Journal of Hazardous Materials, 186-3 (2011) 1739–1743.
  • [34] Wang Y., Zhang J., Zhao B., Du X., Ma J., and Li J., Development of Dispersive Liquid–Liquid Microextraction Based on Solidification of Floating Organic Drop for the Determination of Trace Nickel, Biological Trace Element Research, 144-3 (2011) 1381–1393.
  • [35] Bidabadi M.S., Dadfarnia S., and Shabani A.M.H., Solidified floating organic drop microextraction (SFODME) for simultaneous separation/preconcentration and determination of cobalt and nickel by graphite furnace atomic absorption spectrometry (GFAAS), Journal of Hazardous Materials, 166-1 (2009) 291–296.
  • [36] Arpa Ç. and Arıdaşır I., Ultrasound assisted ion pair based surfactant-enhanced liquid–liquid microextraction with solidification of floating organic drop combined with flame atomic absorption spectrometry for preconcentration and determination of nickel and cobalt ions in vegeta, Food Chemistry, 284 (2019) 16–22.
  • [37] Amirkavei M., Dadfarnia S., and Shabani A.M.H., Dispersive liquid-liquid microextraction based on solidification of floating organic drop for simultaneous separation/preconcentration of nickel, cobalt and copper prior to determination by electrothermal atomic absorption spectrometry. Química Nova, 36-1 (2013) 63–68.
  • [38] Ezoddin M., Taghizadeh T., and Majidi B., Ultrasound-assisted surfactant-enhanced emulsification microextraction for the determination of Cd and Ni in tea and water samples. Environmental Technology, 35-19 (2014) 2401–2409.

Year 2019, , 917 - 925, 31.12.2019

Demirhan Çıtak , Rabia Demirok

https://doi.org/10.17776/csj.642319
Cited By: 1

Abstract

Project Number

2018/41

References

  • [1] Barreto J.A., dos Santos de Assis R., Cassella, R.J., and Lemos, V.A., A novel strategy based on in-syringe dispersive liquid-liquid microextraction for the determination of nickel in chocolate samples, Talanta, 193 (2019) 23–28.
  • [2] Zdrojewicz Z., Popowicz E., and Winiarski J., Nickel - role in human organism and toxic effects, Polski Merkuriusz Lekarski : Organ Polskiego Towarzystwa Lekarskiego, (2016) 115–118.
  • [3] Baytak S., and Türker A., Determination of lead and nickel in environmental samples by flame atomic absorption spectrometry after column solid-phase extraction on Ambersorb-572 with EDTA. Journal of Hazardous Materials, 129-1,3 (2006) 130–136.
  • [4] Arkhipova A.A., Statkus M.A., Tsizin G.I., and Zolotov Y.A., Preconcentration of elements as hydrophobic complexes with low-polar adsorbents, Journal of Analytical Chemistry, 70-12 (2015) 1413–1431.
  • [5] Hashemi B., Zohrabi P., Kim K.H., Shamsipur M., Deep, A., and Hong J., Recent advances in liquid-phase microextraction techniques for the analysis of environmental pollutants, TrAC Trends in Analytical Chemistry, 97 (2017) 83–95.
  • [6] Lemos V., Baliza P., Santos J., Nunes L., Jesus A., and Rocha M., A new functionalized resin and its application in preconcentration system with multivariate optimization for nickel determination in food samples, Talanta, 66-1 (2005) 174–180.
  • [7] Yalçın M.S., Özdemir S., and Kılınç E., Preconcentrations of Ni(II) and Co(II) by using immobilized thermophilic Geobacillus stearothermophilus SO-20 before ICP-OES determinations, Food Chemistry, 266 (2018) 126–132.
  • [8] Naghizadeh M., Taher M.A., Abadi L.Z., and Moghaddam F.H., Synthesis, characterization and theoretical investigation of magnetite nanoclay modified as a new nanocomposite for simultaneous preconcentration of lead and nickel prior to ETAAS determination, Environmental Nanotechnology, Monitoring & Management, 7 (2017) 46–56. [9] ALOthman Z.A., Habila M.A., Yilmaz E., Soylak M., and Alfadul S.M., Ultrasonic supramolecular microextration of nickel (II) as N,N′-Dihydroxy-1,2-cyclohexanediimine chelates from water, tobacco and fertilizer samples before FAAS determination, Journal of Molecular Liquids, 221 (2016) 773–777.
  • [10] He Y. and Lee H.K., Liquid-Phase Microextraction in a Single Drop of Organic Solvent by Using a Conventional Microsyringe. Analytical Chemistry, 69-22 (1997) 4634–4640.
  • [11] Rykowska I., Ziemblińska J., and Nowak I., Modern approaches in dispersive liquid-liquid microextraction (DLLME) based on ionic liquids: A review, Journal of Molecular Liquids, 259 (2018) 319–339.
  • [12] De Almeida O.N., Luzardo F.H.M., Amorim F.A.C., Velasco F.G., and González L.N., Use of fiberglass support in the application of dried-spot technique with dispersion liquid-liquid microextraction for the determination of Co, Cr, Cu, Ni and Pb by Energy Dispersive X-Ray Fluorescence Spectrometry, Spectrochimica Acta Part B: Atomic Spectroscopy, 150 (2018) 92–98.
  • [13] Kocot K., Pytlakowska K., Zawisza B., and Sitko R., How to detect metal species preconcentrated by microextraction techniques, TrAC Trends in Analytical Chemistry, 82 (2016) 412–424.
  • [14] Giakisikli G. and Anthemidis A.N., An automatic stirring-assisted liquid–liquid microextraction system based on lab-in-syringe platform for on-line atomic spectrometric determination of trace metals, Talanta, 166 (2017) 364–368.
  • [15] Habila M.A., Yilmaz E., ALOthman Z.A., and Soylak M., Combination of dispersive liquid–liquid microextraction and multivariate optimization for separation-enrichment of traces lead by flame atomic absorption spectrometry, Journal of Industrial and Engineering Chemistry, 37 (2016) 306–311.
  • [16] Zhang S., Chen B., He M., and Hu B., Switchable solvent based liquid phase microextraction of trace lead and cadmium from environmental and biological samples prior to graphite furnace atomic absorption spectrometry detection, Microchemical Journal, 139 (2018) 380–385.
  • [17] Biata N.R., Nyaba L., Ramontja J., Mketo N., and Nomngongo P.N., Determination of antimony and tin in beverages using inductively coupled plasma-optical emission spectrometry after ultrasound-assisted ionic liquid dispersive liquid-liquid phase microextraction, Food Chemistry, 237 (2017) 904–911.
  • [18] Khazaeli E., Haddadi H., Zargar B., Hatamie A., and Semnani A., Ni(II) analysis in food and environmental samples by liquid-liquid microextraction combined with electro-thermal atomic absorption spectrometry, Microchemical Journal, 133 (2017) 311–319.
  • [19] Altunay N., Yıldırım E., and Gürkan R., Extraction and preconcentration of trace Al and Cr from vegetable samples by vortex-assisted ionic liquid-based dispersive liquid–liquid microextraction prior to atomic absorption spectrometric determination, Food Chemistry, 245 (2018) 586–594.
  • [20] Manzoori J.L., Amjadi M., and Abulhassani, J., Ultra-trace determination of lead in water and food samples by using ionic liquid-based single drop microextraction-electrothermal atomic absorption spectrometry, Analytica Chimica Acta, 644-1,2 (2009) 48–52.
  • [21] Xia L., Li, X., Wu Y., Hu B., and Chen R., Ionic liquids based single drop microextraction combined with electrothermal vaporization inductively coupled plasma mass spectrometry for determination of Co, Hg and Pb in biological and environmental samples. Spectrochimica Acta Part B: Atomic Spectroscopy, 63-11 (2008) 1290–1296.
  • [22] Dadfarnia S., and Haji Shabani A.M., Recent development in liquid phase microextraction for determination of trace level concentration of metals—A review, Analytica Chimica Acta, 658-2 (2010) 107–119.
  • [23] Jiang H., Hu B., Chen B., and Xia L., Hollow fiber liquid phase microextraction combined with electrothermal atomic absorption spectrometry for the speciation of arsenic (III) and arsenic (V) in fresh waters and human hair extracts, Analytica Chimica Acta, 634-1 (2009) 15–21.
  • [24] Ghambarian M., Yamini Y., and Esrafili A., Developments in hollow fiber based liquid-phase microextraction: principles and applications, Microchimica Acta, 177-3 (2012) 271–294.
  • [25] Shamsipur M., Ramezani M., and Miran Beigi A.A., Floating Organic Drop Microextraction Combined with Electrothermal Atomic Absorption Spectrometry for Trace Determination of Cobalt in Oil Refining Wastewaters, Energy Sources, Part A: Recovery, Utilization, and Environmental Effects, 37-11 (2015) 1164–1171.
  • [26] Mohammadi S.Z., Sheibani A., Abdollahi F., and Shahsavani E., Speciation of Tl(III) and Tl(I) in hair samples by dispersive liquid–liquid microextraction based on solidification of floating organic droplet prior to flame atomic absorption spectrometry determination, Arabian Journal of Chemistry, 9 (2016) 1510–S1515.
  • [27] Haji Shabani A.M., Dadfarnia S., and Nozohor M., Indirect spectrophotometric determination of ultra trace amounts of selenium based on dispersive liquid–liquid microextraction–solidified floating organic drop, Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 116 (2013) 1–5.
  • [28] Karadaş, C., and Kara, D., Dispersive liquid–liquid microextraction based on solidification of floating organic drop for preconcentration and determination of trace amounts of copper by flame atomic absorption spectrometry, Food Chemistry, 220 (2017) 242–248.
  • [29] Mohamadi M., and Mostafavi A., A novel solidified floating organic drop microextraction based on ultrasound-dispersion for separation and preconcentration of palladium in aqueous samples. Talanta, 81-2 (2010) 309–313.
  • [30] Pérez-Outeiral J., Millán E., and Garcia-Arrona, R., Determination of phthalates in food simulants and liquid samples using ultrasound-assisted dispersive liquid–liquid microextraction followed by solidification of floating organic drop, Food Control, 62 (2016) 171–177.
  • [31] Pelit F.O. and Yengin Ç., Application of solidified floating organic drop microextraction method for biomonitoring of chlorpyrifos and its oxon metabolite in urine samples, Journal of Chromatography B, 949–950 (2014) 109–114.
  • [32] Mansour F.R. and Danielson N.D., Solidification of floating organic droplet in dispersive liquid-liquid microextraction as a green analytical tool, Talanta, 170 (2017) 22–35.
  • [33] Mirzaei M., Behzadi M., Abadi N.M., and Beizaei A., Simultaneous separation/preconcentration of ultra trace heavy metals in industrial wastewaters by dispersive liquid–liquid microextraction based on solidification of floating organic drop prior to determination by graphite furnace atomic absorption spectrometer Journal of Hazardous Materials, 186-3 (2011) 1739–1743.
  • [34] Wang Y., Zhang J., Zhao B., Du X., Ma J., and Li J., Development of Dispersive Liquid–Liquid Microextraction Based on Solidification of Floating Organic Drop for the Determination of Trace Nickel, Biological Trace Element Research, 144-3 (2011) 1381–1393.
  • [35] Bidabadi M.S., Dadfarnia S., and Shabani A.M.H., Solidified floating organic drop microextraction (SFODME) for simultaneous separation/preconcentration and determination of cobalt and nickel by graphite furnace atomic absorption spectrometry (GFAAS), Journal of Hazardous Materials, 166-1 (2009) 291–296.
  • [36] Arpa Ç. and Arıdaşır I., Ultrasound assisted ion pair based surfactant-enhanced liquid–liquid microextraction with solidification of floating organic drop combined with flame atomic absorption spectrometry for preconcentration and determination of nickel and cobalt ions in vegeta, Food Chemistry, 284 (2019) 16–22.
  • [37] Amirkavei M., Dadfarnia S., and Shabani A.M.H., Dispersive liquid-liquid microextraction based on solidification of floating organic drop for simultaneous separation/preconcentration of nickel, cobalt and copper prior to determination by electrothermal atomic absorption spectrometry. Química Nova, 36-1 (2013) 63–68.
  • [38] Ezoddin M., Taghizadeh T., and Majidi B., Ultrasound-assisted surfactant-enhanced emulsification microextraction for the determination of Cd and Ni in tea and water samples. Environmental Technology, 35-19 (2014) 2401–2409.
There are 37 citations in total.

Details

Primary Language English
Journal Section Natural Sciences
Authors

Demirhan Çıtak 0000-0003-1831-3788

Rabia Demirok 0000-0002-7910-9222

Project Number 2018/41
Publication Date December 31, 2019
Submission Date November 4, 2019
Acceptance Date December 19, 2019
Published in Issue Year 2019

Cite

APA Çıtak, D., & Demirok, R. (2019). The Development of pH Modulated Solidified Homogeneous Liquid Phase Microextraction Methodology for Preconcentration and Determination of Nickel in Water Samples. Cumhuriyet Science Journal, 40(4), 917-925. https://doi.org/10.17776/csj.642319

Cited By

Response surface methodology and hydrophobic deep eutectic solvent based liquid phase microextraction combination for determination of cadmium in food and water samples
Journal of Food Measurement and Characterization
Demirhan Çıtak
https://doi.org/10.1007/s11694-020-00761-1