Floresan Özellikli Boya İçeren ZnO Nanokompozit Kopolimerlerin Elektrokimyasal Sentezi ve Karakterizasyonu
Abstract
Floresans boya sınıfından olan BODIPY’nin (Boron dipirolmetilen) bilim
insanları tarafından sentezi uğraştırıcı olmasına karşın floresan, iyon /
molekül ve pH probları, sensörler, redoks aktif moleküller, metal şelatörler,
hücresel görüntüleme, fotodinamik tedavi, ilaç teslim malzemeleri ve
fotovoltaik uygulamalar ve enerji depolama gibi çok çeşitli uygulamalarda
kullanılması ilgi çekici olmuştur. Öncelikle çalışmada sentezi zor ama çekici
floresans aktif monomer başarı ile sentezlenmiştir. Sonra elektrokimyasal
yöntem kullanılarak yenilikçi malzeme olan bir iletken kopolimer
sentezlenmiştir. Elde edilen yarı iletken malzemenin dayanım, iletkenlik özelliklerini
arttırmak için Zno nanopartikülleri kullanılarak yine bir potansiyostat yardımı
ile nanokompozit sentezlenmiş ve varlığı SEM-EDX, AFM-Raman gibi ileri teknolojik
cihazlarla tayin edilmiştir. ZnO gibi inorganik ve nano ölçekli bileşiklerin
karakteristik pikleri geleneksel FT-IR cihazında parmak izi bölgesinde ve
zayıf/orta gözlenmektedir. Buda bahsedilen bileşiklerin kızılötesi spektrometre
ile nitel teşhisini zorlaştırmaktadır. Buna karşın Raman spektroskopisi hem
ICP-MS gibi nispeten uğraştırıcı hem de FT-IR gibi karmaşık bir spektrum
bölgesi olmadığından nano parçacıkların tayininde tercih edilmiştir.
Keywords
References
- Değirmenci, A. and Algı, F., Synthesis, chemiluminescence and energy transfer efficiency of 2,3-dihydrophthalazine-1,4-dione and BODIPY dyad, Dyes Pigments, 140 (2017) 92-99.
- Turaç E., Şahmetlioğlu E. and Göktürk E., Synthesis of Conducting Polymer/Zinc Sulfide Nanocomposite Films and Investigation of Their Electrochemical and Morphological Properties, Adv. Poly Tech., 34 (2015) 21478-21486.
- Moraes B.R., Campos N.S. and Izumi Celly M.S., Surface-enhanced Raman scattering of EDOT and PEDOT on silver and gold nanoparticles, Vib. Spectrosc., 96 (2018) 137-142.
- Madhurima P., Prabhat G., Yogajivan R. and Rajneesh M., Donor–acceptor phenothiazine functionalized BODIPYs, Dyes Pigments, 146 (2017) 368-373.
- Kılıç B., Yeşilyurt N., Polat V., Gerçek Z. and Akkaya E.U., Bodipy-based photosensitizers with long alkyl tails at the meso position: efficient singlet oxygen generation in Cremophor-EL micelles, Tetrahedron Lett., 57 (2016) 1317–1320.
- Algı F. and Cihaner A., A novel terthienyl based polymer electrochrome with peripheral BODIPY, Polymer, 53 (2012) 3469-3475.
- Shijing L., Chunjiang T., Jialin L., Xin Z. and Wenzhong W., Visible light-induced charge transfer to improve sensitive surface-enhanced Raman scattering of ZnO/Ag nanorod arrays, Appl. Surf. Sci., 452 (2018) 148–154.
- Bukowska P., Piechowska J. and Loska R., Azine-imidazole aza-BODIPY analogues with large Stokes shift, Dyes Pigments, 137 (2017) 312-321.
- Lu J., Song H., Li S., Wang L., Han L., Ling H. and Lu X., A poly(3,4-ethylenedioxythiophene):poly(styrene sulfonic acid)/titanium oxide nanocomposite film synthesized by sol–gel assisted electropolymerization for electrochromic application, Thin Solid Films, 584 (2015) 353-358.
- Sahmetlioglu E., Yilmaz E., Aktas E. and Soylak M., Polypyrrole/multi-walled carbon nanotube composite for the solid phase extraction of lead(II) in water samples, Talanta, 119 (2014) 447–451.
- Ak M., Sahmetlioglu E. and Toppare L., Synthesis, characterization and optoelectrochemical properties of poly(1,6-bis(2,5-di(thiophen-2-yl)-1H-pyrrol-1-yl)hexane) and its copolymer with EDOT, J. Electroanal. Chem., 621 (2008) 55–61.
- Sapp S.A., Sotzing G.A. and Reynolds J.R., High Contrast Ratio and Fast-Switching Dual Polymer Electrochromic Devices, Chem. Mater., 10 (1998) 2101-2108.
- Rault-Berthelot J., Raoult E. and Le Floch F., Synthesis and anodic oxidation of a dimer EDOT–dicyanomethylenefluorene and a trimer EDOT–dicyanomethylenefluorene–EDOT: towards mixed polymers with very low bandgap, J. Electroanal. Chem., 546 (2003) 29-34.
- Maier E., Rath T., Haas W.,Werzer O., Saf R., Hofer F., Meissner D., Volobujeva O., Bereznev S., Mellikov E., Amenitsch H., Resel R. and Trimmel G., CuInS2–Poly(3-(ethyl-4-butanoate)thiophene) nanocomposite solar cells: Preparation by an in situ formation route, performance and stability issues, Sol. Energ. Mat. Sol. C., 95 (2011) 1354-1361.
- Madani A., Nessark B., Boukherroub R. and Chehimi M.M., Preparation and electrochemical behaviour of PPy–CdS composite films, J. Electroanal. Chem., 650 (2011) 176-181.
- Guptaa N., Grovera R., Singh Mehtab D. and Saxena K., A simple technique for the fabrication of zinc oxide-PEDOT:PSS nanocomposite thin film for OLED application, Synthetic Met., 221 (2016) 261–267.
- Xu G.L., Li Y., Maa T., Ren Y., Wang H.H., Wang L., Wen J., Miller D., Amine K. and Chena Z., PEDOT-PSS coated ZnO/C hierarchical porous nanorods as ultralong-life anode material for lithium ion batteries, Nano Energy, 18 (2015) 253–264.
- Decremps F., Pellicer-Porres J., Saitta A. M., Chervin J.C. and Polian A., High-pressure Raman spectroscopy study of wurtzite ZnO, Phys. Rev. B, 65 (2002) 092101.
Electrochemical Synthesis and Characterization of ZnO Nanocomposite Copolymer Containing Fluorescent Feature Dye
Abstract
BODIPY
(boron dipyrrolmethene) has attracted the attention of scientists although the synthesis
of BODIPY from the fluorescent dye class is challenging, there are many
applications such as fluorescence, ion / molecule and pH probes, sensors, redox
active molecules, metal chelators, cellular imaging, photodynamic therapy, drug
delivery materials and photovoltaic applications and energy storage. Firstly,
it is synthesized with difficulty in synthesis but attractive fluorescence
active monomer. Then, by electrochemical method, a conductive copolymer, which
is an innovative material, was synthesized. The nanocomposite was synthesized
with the help of a potentiostat using Zno nanoparticles to increase the
strength and conductivity properties of the obtained semiconducting material
and its existence was determined by advanced technological devices such as
SEM-EDX, AFM-Raman. Characteristic peaks of inorganic and nano-scale compounds
such as ZnO are observed in the fingerprint region and weak / medium in the
conventional FT-IR device. This makes it difficult to qualitatively diagnose
the compounds by infrared spectrometry. Raman spectroscopy, however, has been
preferred for the determination of nanoparticles because it is relatively
laborious, such as ICP-MS, and is not a complex spectral region such as FT-IR.
Keywords
References
- Değirmenci, A. and Algı, F., Synthesis, chemiluminescence and energy transfer efficiency of 2,3-dihydrophthalazine-1,4-dione and BODIPY dyad, Dyes Pigments, 140 (2017) 92-99.
- Turaç E., Şahmetlioğlu E. and Göktürk E., Synthesis of Conducting Polymer/Zinc Sulfide Nanocomposite Films and Investigation of Their Electrochemical and Morphological Properties, Adv. Poly Tech., 34 (2015) 21478-21486.
- Moraes B.R., Campos N.S. and Izumi Celly M.S., Surface-enhanced Raman scattering of EDOT and PEDOT on silver and gold nanoparticles, Vib. Spectrosc., 96 (2018) 137-142.
- Madhurima P., Prabhat G., Yogajivan R. and Rajneesh M., Donor–acceptor phenothiazine functionalized BODIPYs, Dyes Pigments, 146 (2017) 368-373.
- Kılıç B., Yeşilyurt N., Polat V., Gerçek Z. and Akkaya E.U., Bodipy-based photosensitizers with long alkyl tails at the meso position: efficient singlet oxygen generation in Cremophor-EL micelles, Tetrahedron Lett., 57 (2016) 1317–1320.
- Algı F. and Cihaner A., A novel terthienyl based polymer electrochrome with peripheral BODIPY, Polymer, 53 (2012) 3469-3475.
- Shijing L., Chunjiang T., Jialin L., Xin Z. and Wenzhong W., Visible light-induced charge transfer to improve sensitive surface-enhanced Raman scattering of ZnO/Ag nanorod arrays, Appl. Surf. Sci., 452 (2018) 148–154.
- Bukowska P., Piechowska J. and Loska R., Azine-imidazole aza-BODIPY analogues with large Stokes shift, Dyes Pigments, 137 (2017) 312-321.
- Lu J., Song H., Li S., Wang L., Han L., Ling H. and Lu X., A poly(3,4-ethylenedioxythiophene):poly(styrene sulfonic acid)/titanium oxide nanocomposite film synthesized by sol–gel assisted electropolymerization for electrochromic application, Thin Solid Films, 584 (2015) 353-358.
- Sahmetlioglu E., Yilmaz E., Aktas E. and Soylak M., Polypyrrole/multi-walled carbon nanotube composite for the solid phase extraction of lead(II) in water samples, Talanta, 119 (2014) 447–451.
- Ak M., Sahmetlioglu E. and Toppare L., Synthesis, characterization and optoelectrochemical properties of poly(1,6-bis(2,5-di(thiophen-2-yl)-1H-pyrrol-1-yl)hexane) and its copolymer with EDOT, J. Electroanal. Chem., 621 (2008) 55–61.
- Sapp S.A., Sotzing G.A. and Reynolds J.R., High Contrast Ratio and Fast-Switching Dual Polymer Electrochromic Devices, Chem. Mater., 10 (1998) 2101-2108.
- Rault-Berthelot J., Raoult E. and Le Floch F., Synthesis and anodic oxidation of a dimer EDOT–dicyanomethylenefluorene and a trimer EDOT–dicyanomethylenefluorene–EDOT: towards mixed polymers with very low bandgap, J. Electroanal. Chem., 546 (2003) 29-34.
- Maier E., Rath T., Haas W.,Werzer O., Saf R., Hofer F., Meissner D., Volobujeva O., Bereznev S., Mellikov E., Amenitsch H., Resel R. and Trimmel G., CuInS2–Poly(3-(ethyl-4-butanoate)thiophene) nanocomposite solar cells: Preparation by an in situ formation route, performance and stability issues, Sol. Energ. Mat. Sol. C., 95 (2011) 1354-1361.
- Madani A., Nessark B., Boukherroub R. and Chehimi M.M., Preparation and electrochemical behaviour of PPy–CdS composite films, J. Electroanal. Chem., 650 (2011) 176-181.
- Guptaa N., Grovera R., Singh Mehtab D. and Saxena K., A simple technique for the fabrication of zinc oxide-PEDOT:PSS nanocomposite thin film for OLED application, Synthetic Met., 221 (2016) 261–267.
- Xu G.L., Li Y., Maa T., Ren Y., Wang H.H., Wang L., Wen J., Miller D., Amine K. and Chena Z., PEDOT-PSS coated ZnO/C hierarchical porous nanorods as ultralong-life anode material for lithium ion batteries, Nano Energy, 18 (2015) 253–264.
- Decremps F., Pellicer-Porres J., Saitta A. M., Chervin J.C. and Polian A., High-pressure Raman spectroscopy study of wurtzite ZnO, Phys. Rev. B, 65 (2002) 092101.
Details
| Primary Language | English |
|---|---|
| Journal Section | Natural Sciences |
| Authors | |
| Publication Date | June 30, 2019 |
| Submission Date | July 11, 2018 |
| Acceptance Date | December 11, 2018 |
| Published in Issue | Year 2019 |