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Ni-Esaslı Alaşımların (Ni% ≥70) Analizi için Spektroskopik Yöntemlerin Uygulanması

Year 2018, , 144 - 151, 16.03.2018

Zeynep Aygün

https://doi.org/10.17776/csj.405681
Cited By: 2

Abstract

Bu çalışmada NixFeyMoz
(x = 0.80; y = 0.15; z = 0.05), NixCryFez (x =
0.70; y = 0.20; z = 0.10), and NixCryAlzCut
(x = 0.75; y = 0.20; z = 0.025; t = 0.025) şeklinde olan ve yüksek
sıcaklıklarda pellet formunda ısıtılarak hazırlanan Ni esaslı alaşımların
yapısal ve manyetik özellikleri incelenmiştir. Bu amaçla, dış manyetik alanda
alaşımların davranışlarını görmek için bu kompozisyonların paramanyetik
özelliklerinin analizinde elektron paramanyetik rezonans deneyi kullanılmıştır.
Oda sıcaklığında kaydedilen elektron paramanyetik rezonans spektrumlarından g
değerleri hesaplanmıştır. NixFeyMoz,
NixCryFez and NixCryAlzCut
alaşımlarının yapısal özellikleri x-ışını kırınımı tekniği ile
gözlemlenmiştir. Çizgi yerleri ve şiddetleri oda sıcaklığında kaydedilen
x-ışını kırınımı spektrumları ile tartışılmıştır. Numunelerin yüzey
morfolojisini anlamak için taramalı elektron mikroskobu; alaşımların elementel
kompozisyonu için enerji dağılımlı spektroskopi deneyleri oda sıcaklığında
yürütülmüştür.

Keywords

Ni-esaslı alaşımlar manyetik özellikler yapısal özellikler

References

  • [1]. Yang Y., Wu P., Wang Q., Wu H., Liu Y., Deng Y., Zhou Y., Shuai C. The Enhancement of Mg Corrosion Resistance by Alloying Mn and Laser-Melting. Mater, 9 (2016) 1-10.
  • [2]. Rodrigues, W.C., Espinoza, F.R.M., Schaeffer, L., Knörnschild, G., A study of Al-Mo powder processing as a possible way to corrosion resistent aluminum-alloys. Mater. Res., 12 (2009) 211-218.
  • [3]. Han İ., Demir L., Mass attenuation coefficients, effective atomic and electron numbers of Ti and Ni alloys. Radiat. Measure., 44 (2009) 289-294.
  • [4]. Pervaiz S., Rashid A., Deiab I., Mihai N., Influence of Tool Materials on Machinability of Titanium- and Nickel-Based Alloys: A Review. Mater. Manufacturing Process., 29 (2014) 219-252.
  • [5]. Davis JR. Nickel, Cobalt, and Their Alloys ASM Specialty Handbook, (2000) 92-101.
  • [6]. Aygun Z., Aygun M., Karabulut B., Karabulut A., Investigation of non-irradiated and gamma-irradiated Trommel Sieve Waste (TSW) with EPR technique. Ann. Nucl. Energy, 40 (2012) 84-86. [7]. Wang H.L., Yan J.M., Li S.J., Zhang X.W., Jiang Q.,. Noble-metal-free NiFeMo nanocatalyst for hydrogen generation from the decomposition of hydrous hydrazine. J. Mater. Chem. A, 3 (2015) 121-124.
  • [8]. Oleksakova, D., Kollar, P., Fuzer, J., Kusy, M., Roth, S., Polansk, K.,. The influence of mechanical milling on structure and soft magnetic properties of NiFe and NiFeMo alloys. J. Magn. Magn. Mater., 316 (2007) e838-e841.
  • [9]. Banerjee M., Banerjee, R., Majumdar, A.K., Mookerjee, A., Sanyal, B., Nigam, A.K., Magnetism in NiFeMo disordered alloys: Experiment and theory, Physica B, 405 (2010) 4287-4293.
  • [10]. Srinivasan R., Sougandi I., Venkatesan R., Rao P.S., Synthesis and room temperature single crystal EPR studies of a dinickel complex having an {Ni2(m-phenoxide)2}2+ unit supported by a macrocyclic ligand environment [Ni2(L)2(OClO3)2] [L = 2-[(4-methyl-pyridin-2-ylimino)- methyl]-phenol]. Proc. Indian Academia Science (Chem. Sci.), 115 (2003) 91-102.
  • [11]. Manjunatha C., Sunitha D.V., Nagabhushana H., Sharma S.C., Ashoka S., Rao J.L., Nagabhushana B.M., Chakradhar R.P.S., Structural characterization, EPR and thermoluminescence properties of Cd1-xNixSiO3 nanocrystalline phosphors. Mater. Res. Bulletin, 47 (2012) 2306-2314.
  • [12]. Aygun Z., Aygun M., Spectroscopic analysis of Ahlat stone (ignimbrite) and pumice formed by volcanic activity. Spectrochim. Acta A, 166 (2016) 73–78.
  • [13]. Reddy A.J., Kokila M.K., Nagabhushana H., Chakradhar R.P.S., Shivakumara C., Rao J.L., Nagabhushana B.M.,Structural, optical and EPR studies on ZnO:Cu nanopowders prepared via low temperature solution combustion synthesis. J. Alloy Comp., 509 (2011) 5349-5355.
  • [14]. Li, Y., Fu, Q., Flytzani-Stephanopoulos, M. Low-temperature water-gas shift reaction over Cu- and Ni-loaded cerium oxide catalysts. Appl. Catalysis B: Environ, 27 (2001) 179-191.
  • [15]. Kabir L., Mandal A.R., Mandal S.K., Polymer stabilized Ni–Ag and Ni–Fe alloy nanoclusters: Structural and magnetic properties. J. Magn. Magn. Mater, 322 (2010) 934-939.
  • [16]. Yarbasi Z., Karabulut A., Karabulut B. EPR Studies of Copper-Doped Potassium Dihydrogen Citrate (C6H7KO7) Single Crystal. Appl. Magn. Resonance, 41 (2011) 51-57.
  • [17]. Stucki J.W., Banwart W.L. Advanced chemical Methods for Soil and Clay Minerals Research; ed. Reidel Pub; 1980.
  • [18]. Mcbride M.B., Electron Spin Resonance spectroscopy In Instrumental Surface Analysis of Geologic Materials; ed. Perry DL VCH, Newyork; 1990.
  • [19]. Slater, A.F.G., Swıggard, W.J., Orton, B.R., Flıtter, W.D., Goldberg, D.E., Ceramı, A., Henderson, G.B.,. An iron-carboxylate bond links the heme units of malaria pigment. Proc. National Academic Sci., 88 (1991) 325-329.
  • [20]. Walker, F.A., Huynh, B.H., Scheidt, W.R., Osvath, S.R., Models of the Cytochromes b. Effect of Axial Ligand Plane Orientation on the EPR and Mb’ssbauer Spectra of Low-Spin Ferrihemes. J. American Chem. Soc., 108 (1986) 5288-5297.
  • [21]. Fujii, H., Yoshimura, T., Kamada, H., ESR Studies of A1u and A2u Oxoiron(IV) Porphyrin ð-Cation Radical Complexes. Spin Coupling between Ferryl Iron and A1u/A2u Orbitals. Inorganic Chem., 35 (1996) 2373-2377.
  • [22]. Davis, L.C., Henzl, M.T., Burris, R.H., Orme-Johnson, W.H., Iron-Sulfur Clusters in the Molybdenum-Iron Protein Component of Nitrogenase. Electron Paramagnetic Resonance of the Carbon Monoxide Inhibited State. Biochem. 1 (1979) 4860-4869.
  • [23]. Fedorov V.V., Konak T., Dashdorj J., Zvanut, M.E., Mirov S.B. Optical and EPR spectroscopy of Zn:Cr:ZnSe and Zn:Fe:ZnSe crystals. Opt. Mater.,37 (2014) 262-266.
  • [24]. Vercamer V., Lelong G., Hijiya H., Kondo Y., Galoisy L., Calas G., Diluted Fe3+ in silicate glasses: Structural effects of Fe-redox state and matrix composition. An optical absorption and X-band/Q-band EPR study. J. Non-Cryst. Solids, 428 (2015) 138-145.
  • [25]. PushpaManjari V., Aswani T., Babu B., Thirumala Rao G., Joyce Stella R., Jayaraja B., Ravikumar R.V.S.S.N. EPR and Optical Studies of Cr (III) Ions Doped NaCaAlPO4F3 Nano Phosphor. Inter. J. Current Eng. Technol., 2 (2004) 259-264.
  • [26]. Padlyak B.V., Romanowski W.R., Lisiecki R., Adamiv V.T., Burak Y.V., Teslyuk I.M., Synthesis, EPR and optical spectroscopy of the Cr-doped tetraborate glasses. Opt. Mater., 34 (2002) 2112-2119.
  • [27]. Alıahmad, M., Moghaddam, N.N. Synthesis of maghemite (g-Fe2O3) nanoparticles by thermal-decomposition of magnetite (Fe3O4) nanoparticles. Mater. Sci. Poland 31 (2013) 264-268.
  • [28]. Drbohlavova J., Hrdy R., Adam V., Kizek R., Schneeweiss O., Hubalek J. Preparation and Properties of Various Magnetic Nanoparticles. Sensors, 9 (2009) 2352-2362.
  • [29]. Iwasaki, T., Mechanochemical Synthesis of Magnetite/Hydroxyapatite Nanocomposites for Hyperthermia. Mater. Sci.-Advanced Topics, 8 (2013) 175-194.
  • [30]. Ul-Hamid, A., Quddus, A., Saricimen, H., Dafall, H., Corrosion Behavior of Coarse- and Fine-Grain Ni Coatings Incorporating NaH2PO4.H2O Inhibitor Treated Substrates. Mater. Res., 18 (2015) 20-26.
  • [31]. Anđić, Z., Vujović, A., Tasić, M., Korać, M., Kamberovic, Z., Synthesis and characterization of Dispersion Reinforced Sintered System Based on Ultra Fine and Nanocomposite Cu-Al2O3 Powders. Dr. Yoshitake Masuda (Ed.), (2011) 217-236.
  • [32]. Saravanan, G., Mohan, S., Electrodeposition of Fe-Ni-Cr alloy from Deep Eutectic System containing Choline chloride and Ethylene Glycol. Int. J. Electrochem. Sci., 6 (2011) 1468-1478.
  • [33]. Park, J.H., Kim, H.G., Park, J.Y., Jung, Y.I., Park, D.J., Koo, Y.H., 2015. High temperature steam-oxidation behavior of arc ion plated Cr coatings for accident tolerant fuel claddings. Surface & Coatings Technol., 280 (2015) 256-259.
  • [34]. Aygun, Z., 2013. AFM and SEM Studies of VO2+ Doped Potassium Dihydrogen Citrate Single Crystal Obtained by Slow Evaporation Method. J. Chem. Crystallog., 43 (2013) 103-107.

Application of Spectroscopic Methods for Analysis of Ni-Based Alloys (Ni% ≥70)

Year 2018, , 144 - 151, 16.03.2018

Zeynep Aygün

https://doi.org/10.17776/csj.405681
Cited By: 2

Abstract

In this paper, we investigate the structural and magnetic properties of
Ni based alloys which are in the form of NixFeyMoz
(x = 0.80; y = 0.15; z = 0.05), NixCryFez (x =
0.70; y = 0.20; z = 0.10), and NixCryAlzCut (x = 0.75; y = 0.20; z =
0.025; t = 0.025) and are prepared by heating the pellet formed samples at high
temperature. For this purpose, electron paramagnetic resonance experiment is
performed for analysis of paramagnetic centers of these compositions to see the
behaviours of alloys in an external magnetic field. g values are calculated
from electron paramagnetic resonance spectra recorded at room temperature.
Structural features of NixFeyMoz,
NixCryFez and NixCryAlzCut
alloys are observed by x-ray diffraction technique. Line positions and line
intensities are discussed by the help of x-ray diffraction spectra recorded at
room temperature. In order to understand the surface morphology of samples,
scanning electron microscopy; for the elemental compositions of the alloys
energy dispersive spectrosopy experiments are carried out at room temperature.

Keywords

Ni-based alloys magnetic properties structural features

References

  • [1]. Yang Y., Wu P., Wang Q., Wu H., Liu Y., Deng Y., Zhou Y., Shuai C. The Enhancement of Mg Corrosion Resistance by Alloying Mn and Laser-Melting. Mater, 9 (2016) 1-10.
  • [2]. Rodrigues, W.C., Espinoza, F.R.M., Schaeffer, L., Knörnschild, G., A study of Al-Mo powder processing as a possible way to corrosion resistent aluminum-alloys. Mater. Res., 12 (2009) 211-218.
  • [3]. Han İ., Demir L., Mass attenuation coefficients, effective atomic and electron numbers of Ti and Ni alloys. Radiat. Measure., 44 (2009) 289-294.
  • [4]. Pervaiz S., Rashid A., Deiab I., Mihai N., Influence of Tool Materials on Machinability of Titanium- and Nickel-Based Alloys: A Review. Mater. Manufacturing Process., 29 (2014) 219-252.
  • [5]. Davis JR. Nickel, Cobalt, and Their Alloys ASM Specialty Handbook, (2000) 92-101.
  • [6]. Aygun Z., Aygun M., Karabulut B., Karabulut A., Investigation of non-irradiated and gamma-irradiated Trommel Sieve Waste (TSW) with EPR technique. Ann. Nucl. Energy, 40 (2012) 84-86. [7]. Wang H.L., Yan J.M., Li S.J., Zhang X.W., Jiang Q.,. Noble-metal-free NiFeMo nanocatalyst for hydrogen generation from the decomposition of hydrous hydrazine. J. Mater. Chem. A, 3 (2015) 121-124.
  • [8]. Oleksakova, D., Kollar, P., Fuzer, J., Kusy, M., Roth, S., Polansk, K.,. The influence of mechanical milling on structure and soft magnetic properties of NiFe and NiFeMo alloys. J. Magn. Magn. Mater., 316 (2007) e838-e841.
  • [9]. Banerjee M., Banerjee, R., Majumdar, A.K., Mookerjee, A., Sanyal, B., Nigam, A.K., Magnetism in NiFeMo disordered alloys: Experiment and theory, Physica B, 405 (2010) 4287-4293.
  • [10]. Srinivasan R., Sougandi I., Venkatesan R., Rao P.S., Synthesis and room temperature single crystal EPR studies of a dinickel complex having an {Ni2(m-phenoxide)2}2+ unit supported by a macrocyclic ligand environment [Ni2(L)2(OClO3)2] [L = 2-[(4-methyl-pyridin-2-ylimino)- methyl]-phenol]. Proc. Indian Academia Science (Chem. Sci.), 115 (2003) 91-102.
  • [11]. Manjunatha C., Sunitha D.V., Nagabhushana H., Sharma S.C., Ashoka S., Rao J.L., Nagabhushana B.M., Chakradhar R.P.S., Structural characterization, EPR and thermoluminescence properties of Cd1-xNixSiO3 nanocrystalline phosphors. Mater. Res. Bulletin, 47 (2012) 2306-2314.
  • [12]. Aygun Z., Aygun M., Spectroscopic analysis of Ahlat stone (ignimbrite) and pumice formed by volcanic activity. Spectrochim. Acta A, 166 (2016) 73–78.
  • [13]. Reddy A.J., Kokila M.K., Nagabhushana H., Chakradhar R.P.S., Shivakumara C., Rao J.L., Nagabhushana B.M.,Structural, optical and EPR studies on ZnO:Cu nanopowders prepared via low temperature solution combustion synthesis. J. Alloy Comp., 509 (2011) 5349-5355.
  • [14]. Li, Y., Fu, Q., Flytzani-Stephanopoulos, M. Low-temperature water-gas shift reaction over Cu- and Ni-loaded cerium oxide catalysts. Appl. Catalysis B: Environ, 27 (2001) 179-191.
  • [15]. Kabir L., Mandal A.R., Mandal S.K., Polymer stabilized Ni–Ag and Ni–Fe alloy nanoclusters: Structural and magnetic properties. J. Magn. Magn. Mater, 322 (2010) 934-939.
  • [16]. Yarbasi Z., Karabulut A., Karabulut B. EPR Studies of Copper-Doped Potassium Dihydrogen Citrate (C6H7KO7) Single Crystal. Appl. Magn. Resonance, 41 (2011) 51-57.
  • [17]. Stucki J.W., Banwart W.L. Advanced chemical Methods for Soil and Clay Minerals Research; ed. Reidel Pub; 1980.
  • [18]. Mcbride M.B., Electron Spin Resonance spectroscopy In Instrumental Surface Analysis of Geologic Materials; ed. Perry DL VCH, Newyork; 1990.
  • [19]. Slater, A.F.G., Swıggard, W.J., Orton, B.R., Flıtter, W.D., Goldberg, D.E., Ceramı, A., Henderson, G.B.,. An iron-carboxylate bond links the heme units of malaria pigment. Proc. National Academic Sci., 88 (1991) 325-329.
  • [20]. Walker, F.A., Huynh, B.H., Scheidt, W.R., Osvath, S.R., Models of the Cytochromes b. Effect of Axial Ligand Plane Orientation on the EPR and Mb’ssbauer Spectra of Low-Spin Ferrihemes. J. American Chem. Soc., 108 (1986) 5288-5297.
  • [21]. Fujii, H., Yoshimura, T., Kamada, H., ESR Studies of A1u and A2u Oxoiron(IV) Porphyrin ð-Cation Radical Complexes. Spin Coupling between Ferryl Iron and A1u/A2u Orbitals. Inorganic Chem., 35 (1996) 2373-2377.
  • [22]. Davis, L.C., Henzl, M.T., Burris, R.H., Orme-Johnson, W.H., Iron-Sulfur Clusters in the Molybdenum-Iron Protein Component of Nitrogenase. Electron Paramagnetic Resonance of the Carbon Monoxide Inhibited State. Biochem. 1 (1979) 4860-4869.
  • [23]. Fedorov V.V., Konak T., Dashdorj J., Zvanut, M.E., Mirov S.B. Optical and EPR spectroscopy of Zn:Cr:ZnSe and Zn:Fe:ZnSe crystals. Opt. Mater.,37 (2014) 262-266.
  • [24]. Vercamer V., Lelong G., Hijiya H., Kondo Y., Galoisy L., Calas G., Diluted Fe3+ in silicate glasses: Structural effects of Fe-redox state and matrix composition. An optical absorption and X-band/Q-band EPR study. J. Non-Cryst. Solids, 428 (2015) 138-145.
  • [25]. PushpaManjari V., Aswani T., Babu B., Thirumala Rao G., Joyce Stella R., Jayaraja B., Ravikumar R.V.S.S.N. EPR and Optical Studies of Cr (III) Ions Doped NaCaAlPO4F3 Nano Phosphor. Inter. J. Current Eng. Technol., 2 (2004) 259-264.
  • [26]. Padlyak B.V., Romanowski W.R., Lisiecki R., Adamiv V.T., Burak Y.V., Teslyuk I.M., Synthesis, EPR and optical spectroscopy of the Cr-doped tetraborate glasses. Opt. Mater., 34 (2002) 2112-2119.
  • [27]. Alıahmad, M., Moghaddam, N.N. Synthesis of maghemite (g-Fe2O3) nanoparticles by thermal-decomposition of magnetite (Fe3O4) nanoparticles. Mater. Sci. Poland 31 (2013) 264-268.
  • [28]. Drbohlavova J., Hrdy R., Adam V., Kizek R., Schneeweiss O., Hubalek J. Preparation and Properties of Various Magnetic Nanoparticles. Sensors, 9 (2009) 2352-2362.
  • [29]. Iwasaki, T., Mechanochemical Synthesis of Magnetite/Hydroxyapatite Nanocomposites for Hyperthermia. Mater. Sci.-Advanced Topics, 8 (2013) 175-194.
  • [30]. Ul-Hamid, A., Quddus, A., Saricimen, H., Dafall, H., Corrosion Behavior of Coarse- and Fine-Grain Ni Coatings Incorporating NaH2PO4.H2O Inhibitor Treated Substrates. Mater. Res., 18 (2015) 20-26.
  • [31]. Anđić, Z., Vujović, A., Tasić, M., Korać, M., Kamberovic, Z., Synthesis and characterization of Dispersion Reinforced Sintered System Based on Ultra Fine and Nanocomposite Cu-Al2O3 Powders. Dr. Yoshitake Masuda (Ed.), (2011) 217-236.
  • [32]. Saravanan, G., Mohan, S., Electrodeposition of Fe-Ni-Cr alloy from Deep Eutectic System containing Choline chloride and Ethylene Glycol. Int. J. Electrochem. Sci., 6 (2011) 1468-1478.
  • [33]. Park, J.H., Kim, H.G., Park, J.Y., Jung, Y.I., Park, D.J., Koo, Y.H., 2015. High temperature steam-oxidation behavior of arc ion plated Cr coatings for accident tolerant fuel claddings. Surface & Coatings Technol., 280 (2015) 256-259.
  • [34]. Aygun, Z., 2013. AFM and SEM Studies of VO2+ Doped Potassium Dihydrogen Citrate Single Crystal Obtained by Slow Evaporation Method. J. Chem. Crystallog., 43 (2013) 103-107.
There are 33 citations in total.

Details

Primary Language English
Journal Section Natural Sciences
Authors

Zeynep Aygün

Publication Date March 16, 2018
Submission Date July 5, 2017
Acceptance Date March 12, 2018
Published in Issue Year 2018

Cite

APA Aygün, Z. (2018). Application of Spectroscopic Methods for Analysis of Ni-Based Alloys (Ni% ≥70). Cumhuriyet Science Journal, 39(1), 144-151. https://doi.org/10.17776/csj.405681

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