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Kurşunlu ve Kurşunsuz Bi2Sr2Ca2Cu3Oδ Sistemine Seryum Katkısının Yapısal ve Süperiletkenlik Özelliklere Etkileri

Year 2017, , 492 - 501, 30.09.2017

Hasan Ağıl

https://doi.org/10.17776/csj.340877

Abstract

Bu
çalışmada kurşunsuz ve kurşunlu seryum ilave edilmiş Bi2Sr2Ca2Cu3Oδ
süperiletken sisteminin termal, yapısal ve süperiletkenlik özellikleri
araştırılmıştır. Bi2-xPbxSr2Ca2Cu3CeyOδ
(x = 0 ve 0.4 ve y = 0, 0.1, 0.2 ve 0.4) genel stokiyometrisine sahip seryum
katkılı süperiletkenler geleneksel katı hal sentezleme tekniği ile
hazırlanmıştır. Malzemeler DTK/TGA, XRD, SEM, EDX ve R-T ölçümleri ile
karakterize edilmiştir. Üretilen malzemelerde elde edilmek istenen faz Bi-2223
fazı olmasına rağmen bazı malzemelerde Bi-2212 fazının baskın olduğu
görülmüştür. Özellikle kurşunsuz malzemelerde ana faz Bi-2212 fazı iken
kurşunlu malzemelerde ise nispeten ana faz Bi-2223 fazıdır. Buna bağlı olarak
kritik sıcaklık değerleri düşmüş ve iki adımda geçiş davranışı
gözlemlenmiştir.  

Keywords

Yüksek Tc Süperiletkenler BSCCO Katkılama ve İlaveler

References

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Influences of Cerium Addition on the Structural and Superconducting Properties with Pb and Pb-free Bi2Sr2Ca2Cu3Oδ System

Year 2017, , 492 - 501, 30.09.2017

Hasan Ağıl

https://doi.org/10.17776/csj.340877

Abstract

In
this study, the thermal, structural and superconducting properties with lead
and lead-free cerium added Bi2Sr2Ca2Cu3Oδ
superconducting system have been investigated. Cerium-added superconductors
with the general stoichiometry of Bi2-xPbxSr2Ca2Cu3CeyOδ
(x = 0 and 0.4 and y = 0, 0.1, 0.2 and 0.4) were prepared by the conventional
solid state synthesis technique. The materials are characterized by DTA/TGA,
XRD, SEM, EDX and R-T measurements. Although the desired phase is the Bi-2223
phase in the manufactured materials, it is observed that Bi-2212 phase
predominates in some materials. Especially while being the Bi-2212 phase in
Pb-free samples, the main phase is relatively Bi-2223 phase in Pb containing
samples. Consequently, critical temperature values have also decreased and
transition behavior has been observed in two steps.  

Keywords

High Tc Superconductors BSCCO Doping and Additions

References

  • [1]. Runde, M.: IEEE Trans. Appl. Supercond. 5, 813 (1995).
  • [2]. Godeke, A., Cheng, D., Dietderich, D.R., English, C.D., Felice, H., Hannaford, C.R., Prestemon, S.O., Sabbi, G., Scanlan, R.M., Hikichi, Y., Nishioka, J., Hasegawa, T.: IEEE Trans. Appl. Supercond. 18, 516 (2008).
  • [3]. Miao, H., Meinesz, M., Czabai, B., Parrell, J., Hong, S.: AIP Conf. Proc. 986, 423 (2008).
  • [4]. Maeda, H., Tanaka, Y., Fukutomi, M., Asano, T.: Jpn. J. Appl. Phys. 27, L209 (1988).
  • [5]. Mousavi Ghahfarokhi, S.E., Zargar Shoushtari, M.: Physica B 405, 4643 (2010).
  • [6]. P. Majewski, J. Mater. Res. 15 (2000) 854.
  • [7]. Biju, P.M. Sarun, R.P. Aloysius, U. Syamaprasad, J. Alloy Compd. 433 (2007) 68–72.
  • [8]. X.Y. Lu, K. Watanabe, D. Yi, H. Chen, A. Nagata, C. Physica, Supercond. Appl. 471 (2011) 1090.
  • [9]. C. Terzioglu, H. Aydin, O. Ozturk, E. Bekiroglu, I. Belenli, Phys. B: Cond. Mater. 403 (2008) 3354–3359.
  • [10]. T.S. Chin, T.W. Huang, W.T. Lin, N.C. Wa, Y.H. Chou, T.C. Wu, P.T. Wu, H.H. Yen, Symp. Proc. Mater. Res. Soc., 1988, p. 261.
  • [11]. L. Ciontea, V. Boffa, T. Petrisor, R. Bruzzese, E. Perte, C. Alvani, Phys. C: Supercond. Appl. 257 (1996) 304.
  • [12]. Y.W. Hsueh, S.C. Chang, R.S. Liu, L. Woodall, M. Gerards, Mater. Res. Bull. 36 (2001) 1653.
  • [13]. P.E. Kazin, Yu D. Tretvakov, Russian Chem. Rev. 72 (2003) 849.
  • [14]. Sedky, J. Phys. Chem. Sol. 70 (2009) 9.
  • [15]. W. Zhu, C.K. Kuo, P.S. Nicholson, J. Am. Ceram. Soc. 80 (8) (1997) 1975.
  • [16]. J.C. Grivel, F. Kubel, R. Flukiger, J. Therm. Anal. 48 (1997) 665–674.
  • [17]. B.A. Marinkovic, P.M. Jardim, F. Rizzo, L. Mancic, O. Milosevic, Materials Chemistry and Physics 94 (2005) 233–240.
  • [18]. H.K. Liu, S.X. Dou, M. Ionescu, Z.B. Shao, K.R. Liu, L.Q. Liu, J. Mater. Res. 10 (11) (1995) 2933–2937.
  • [19]. Chong, M. Hiroi, J. Izumi, Y. Shimoyama, Y. Nakayama, K. Kishio, T. Terashima, Y. Bando, M. Takano, Science 276 (1997) 770–773.
  • [20]. T. Motohashi, Y. Nakayama, T. Fujita, K. Kitazawa, J. Shimoyama, K. Kishio, Phys. Rev. B 59 (1999) 14080–14086.
  • [21]. W.D.Wu, A. Keren, L.P. Le, B.J. Sternlieb, G.M. Luke, Y.J. Uemura, Phys. Rev. B 47 (1993) 8172–8186.
  • [22]. Crossley, A.D. Caplin, A.V. Berenov, J.L. MacManus, Supercond. Sci. Technol. 13 (2000) 551–557.
  • [23]. C.W. Chiu, R.L. Meng, L. Gao, Z.J. Huang, F. Chen, Y.Y. Xue, Nature 365, 323 (1993).
  • [24]. S.A. Halim, S.A. Khawaldeh, S.B. Mohammed, H. Azhan, Mater. Chem. Phys. 61, 251 (1999).
There are 24 citations in total.

Details

Journal Section Articles
Authors

Hasan Ağıl

Publication Date September 30, 2017
Submission Date May 16, 2017
Acceptance Date August 7, 2017
Published in Issue Year 2017

Cite

APA Ağıl, H. (2017). Influences of Cerium Addition on the Structural and Superconducting Properties with Pb and Pb-free Bi2Sr2Ca2Cu3Oδ System. Cumhuriyet Science Journal, 38(3), 492-501. https://doi.org/10.17776/csj.340877