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Characterization of ZnSe Thin Film Electrodeposited at Room Temperature in Aqueous Medium without Complexing Agents

Year 2024, , 524 - 529, 30.09.2024

Sevda İldan Özmen

https://doi.org/10.17776/csj.1455751

Abstract

This study includes a simple electrodeposition technique for the fabrication of ZnSe thin film at room temperature and in an aqueous medium without additional complexing agents. Comprehensive analysis of the optical, structural, and morphological characteristics of the ZnSe thin film electrodeposited onto an ITO substrate was conducted using UV-Vis spectrometry, X-ray diffraction (XRD), Raman spectroscopy, Fourier transform infrared spectroscopy (FT-IR), and field emission–scanning electron microscopy (FE–SEM). Furthermore, the photoelectrochemical properties were evaluated through current-time (I-t) measurements and electrochemical impedance spectroscopy (EIS) under light on/off conditions. Mott-Schottky analysis was also performed to determine the conductivity type, carrier concentration, and flat band potential of the ZnSe thin film. Structural investigations revealed that the ZnSe thin film has a hexagonal structure, the longitudinal optical (LO) phonon mode, stretching and bending vibration modes of Zn-Se. The carrier type of the ZnSe thin film was identified as n- type semiconductor and photoelectrochemical measurements exhibited a photoresponse under the light illumination

Keywords

Electrodeposition ZnSe Characterization Mott–Schottky Photoelectrochemical measurements

References

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  • [5] Dhanasekaran V., Mahalingam T., Rhee J.K., Chu J.P., Structural and optical properties of electrosynthesized ZnSe thin films, Optik, 124 (2013) 255–260.
  • [6] Yildirim E., Metin Gubur H., Alpdogan S., Ari M., Harputlu E., Ocakoglu K., The effect of annealing of ZnSe nanocrystal thin films in air atmosphere, Indian Journal of Physics, 90 (2016) 793–803.
  • [7] Khalfi R., Talantikite-Touati D., Tounsi A., Merzouk H., Effect of deposition time on structural and optical properties of ZnSe thin films grown by CBD method, Opt. Mater., 106 (2020) 109989.
  • [8] Arslan M., Maqsood A., Mahmood A., Iqbal A., Structural and optical properties of copper enriched ZnSe thin films prepared by closed space sublimation technique, Mater. Sci. Semicond. Process, 16 (2013) 1797–1803.
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  • [14] Kowalik R., Szaciłowski K., Zabiński P., Photoelectrochemical study of ZnSe electrodeposition on Cu electrode, Journal of Electroanalytical Chemistry, 674 (2012) 108–112.
  • [15] Asil Uǧurlu H., Hamurcu Y., Electrochemical growth of ZnSe thin films, characterization and heterojunction applications, Mater. Res. Express, 6 (2019) 116422.
  • [16] Lohar G.M., Thombare J. V., Shinde S.K., Han S.H., Fulari V.J., Structural, photoluminescence and photoelectrochemical properties of electrosynthesized ZnSe spheres, Journal of Materials Science: Materials in Electronics, 25 (2014) 1597–1604.
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  • [19] Ildan Ozmen S., Metin Gubur H., Synthesis and characterization of CdTe/CdSe thin film on glass/ITO by electrodeposition at room temperature, Bulletin of Materials Science, 45(2) (2022) 77.
  • [20] Ildan Ozmen S., Temiz S.H., Metin Gubur H., Effects of annealing on SnS fi lms produced by chemical bath deposition (CBD), Phys. Scr., 97 (2022) 75704.
  • [21] Yildirim E., Ildan Ozmen S., Havare A.K., Gubur H.M., Annealing effect on CdS nanowalls grown by chemical bath deposition on glass substrate, Phys. Scr., 98 (2023) 075933.
  • [22] Ivashchenko M.M., Opanasyuk A.S., Buryk I.P., Lutsenko V.A., Shevchenko A.V., Optical properties of pure and Eu Doped ZnSe films deposited by CSVS technique, Journal of Nano- and Electronic Physics, 9 (2017).
  • [23] Bhagavathula S.D., Kokkarachedu V., Acuna D.Q., Koduri R., Veluri S., Reddy V., Insight of electrical behavior in ferroelectric-semiconductor polymer nanocomposite films of PVDF/ZnSe and PVDF/Cu:ZnSe, J. Appl. Polym. Sci., 134(25) (2017) 44983.
  • [24] Baran E., Yazıcı B., Preparation and characterization of poly (3-hexylthiophene) sensitized Ag doped TiO2 nanotubes and its carrier density under solar light illumination, Thin Solid Films, 627 (2017) 82–93.
  • [25] Majumder S., Sankapal B.R., Facile fabrication of CdS/CdSe core-shell nanowire heterostructure for solar cell applications, New Journal of Chemistry, 41 (2017) 5808–5817.
  • [26] Schneider M., Langklotz U., Körsten O., Gierth U., Passive layer investigation on tin and tin solder alloys, Materials and Corrosion, (2023) 1-9.
  • [27] Baran E., Yazici B., Fabrication of TiO2 -NTs and TiO2 -NTs covered honeycomb lattice and investigation of carrier densities in I-/I3- electrolyte by electrochemical impedance spectroscopy, Appl. Surf. Sci., 357 (2015) 2206–2216.
  • [28] Bayramoglu H., Peksoz A., Electronic energy levels and electrochemical properties of co-electrodeposited CdSe thin films, Mater. Sci. Semicond. Process, 90 (2019) 13–19.

Year 2024, , 524 - 529, 30.09.2024

Sevda İldan Özmen

https://doi.org/10.17776/csj.1455751

Abstract

References

  • [1] Yudin N., Antipov O., Balabanov S., Eranov I., Getmanovskiy Y., Slyunko E., Effects of the Processing Technology of CVD-ZnSe, Cr2+:ZnSe, and Fe2+:ZnSe Polycrystalline Optical Elements on the Damage Threshold Induced by a Repetitively Pulsed Laser at 2.1 µm, Ceramics, 5 (2022) 459–471.
  • [2] Lal N., Chawla K., Sharma S., Chouhan R.L., Lal C., Study of electrodeposited zinc selenide (ZnSe) nanostructure thin films for solar cell applications, Journal of the Indian Chemical Society, 100 (2023) 101006.
  • [3] Prabukanthan P., Kumar T.R., Harichandran G., Influence of various complexing agents on structural, morphological, optical and electrical properties of electrochemically deposited ZnSe thin films, Journal of Materials Science: Materials in Electronics, 28 (2017) 14728–14737.
  • [4] Gromboni M.F., Mascaro L.H., Optical and structural study of electrodeposited zinc selenide thin films, Journal of Electroanalytical Chemistry, 780 (2016) 360–366.
  • [5] Dhanasekaran V., Mahalingam T., Rhee J.K., Chu J.P., Structural and optical properties of electrosynthesized ZnSe thin films, Optik, 124 (2013) 255–260.
  • [6] Yildirim E., Metin Gubur H., Alpdogan S., Ari M., Harputlu E., Ocakoglu K., The effect of annealing of ZnSe nanocrystal thin films in air atmosphere, Indian Journal of Physics, 90 (2016) 793–803.
  • [7] Khalfi R., Talantikite-Touati D., Tounsi A., Merzouk H., Effect of deposition time on structural and optical properties of ZnSe thin films grown by CBD method, Opt. Mater., 106 (2020) 109989.
  • [8] Arslan M., Maqsood A., Mahmood A., Iqbal A., Structural and optical properties of copper enriched ZnSe thin films prepared by closed space sublimation technique, Mater. Sci. Semicond. Process, 16 (2013) 1797–1803.
  • [9] Ivashchenko M.M., Buryk I.P., Opanasyuk A.S., Nam D., Cheong H., Vaziev J.G., Bibyk V. V., Influence of deposition conditions on morphological, structural, optical and electro-physical properties of ZnSe films obtained by close-spaced vacuum sublimation, Mater. Sci. Semicond. Process, 36 (2015) 13–19.
  • [10] Boo B.H., Xu N., Lee J.K., Growth of crystalline ZnSe : N thin films by pulsed laser ablation deposition, Vacuum, 64 (2002) 145–151.
  • [11] Prabukanthan P., Harichandran G., Electrochemical Deposition of n-Type ZnSe Thin Film Buffer Layer for Solar Cells, J. Electrochem. Soc., 161 (2014) 736–741.
  • [12] Xu J.L., Gong W.Y., Wang W., Meng H., Zhang X., Shi Z.N., Haarberg G.M., Electrodeposition mechanism of ZnSe thin film in aqueous solution, Rare Metals, 36 (2017) 816–820.
  • [13] Mahalingam T., Dhanasekaran V., Chandramohan R., Rhee J.K., Microstructural properties of electrochemically synthesized ZnSe thin films, J. Mater. Sci., 47 (2012) 1950–1957.
  • [14] Kowalik R., Szaciłowski K., Zabiński P., Photoelectrochemical study of ZnSe electrodeposition on Cu electrode, Journal of Electroanalytical Chemistry, 674 (2012) 108–112.
  • [15] Asil Uǧurlu H., Hamurcu Y., Electrochemical growth of ZnSe thin films, characterization and heterojunction applications, Mater. Res. Express, 6 (2019) 116422.
  • [16] Lohar G.M., Thombare J. V., Shinde S.K., Han S.H., Fulari V.J., Structural, photoluminescence and photoelectrochemical properties of electrosynthesized ZnSe spheres, Journal of Materials Science: Materials in Electronics, 25 (2014) 1597–1604.
  • [17] Lohar G.M., Shinde S.K., Rath M.C., Fulari V.J., Structural, optical, photoluminescence, electrochemical, and photoelectrochemical properties of Fe doped ZnSe hexagonal nanorods, Mater. Sci. Semicond. Process, 26 (2014) 548–554.
  • [18] Gubur Metin H., Septekin F., Alpdogan S., CdSe nanowires grown by using chemical bath deposition, Journal of the Korean Physical Society, 67 (2015) 1222–1227.
  • [19] Ildan Ozmen S., Metin Gubur H., Synthesis and characterization of CdTe/CdSe thin film on glass/ITO by electrodeposition at room temperature, Bulletin of Materials Science, 45(2) (2022) 77.
  • [20] Ildan Ozmen S., Temiz S.H., Metin Gubur H., Effects of annealing on SnS fi lms produced by chemical bath deposition (CBD), Phys. Scr., 97 (2022) 75704.
  • [21] Yildirim E., Ildan Ozmen S., Havare A.K., Gubur H.M., Annealing effect on CdS nanowalls grown by chemical bath deposition on glass substrate, Phys. Scr., 98 (2023) 075933.
  • [22] Ivashchenko M.M., Opanasyuk A.S., Buryk I.P., Lutsenko V.A., Shevchenko A.V., Optical properties of pure and Eu Doped ZnSe films deposited by CSVS technique, Journal of Nano- and Electronic Physics, 9 (2017).
  • [23] Bhagavathula S.D., Kokkarachedu V., Acuna D.Q., Koduri R., Veluri S., Reddy V., Insight of electrical behavior in ferroelectric-semiconductor polymer nanocomposite films of PVDF/ZnSe and PVDF/Cu:ZnSe, J. Appl. Polym. Sci., 134(25) (2017) 44983.
  • [24] Baran E., Yazıcı B., Preparation and characterization of poly (3-hexylthiophene) sensitized Ag doped TiO2 nanotubes and its carrier density under solar light illumination, Thin Solid Films, 627 (2017) 82–93.
  • [25] Majumder S., Sankapal B.R., Facile fabrication of CdS/CdSe core-shell nanowire heterostructure for solar cell applications, New Journal of Chemistry, 41 (2017) 5808–5817.
  • [26] Schneider M., Langklotz U., Körsten O., Gierth U., Passive layer investigation on tin and tin solder alloys, Materials and Corrosion, (2023) 1-9.
  • [27] Baran E., Yazici B., Fabrication of TiO2 -NTs and TiO2 -NTs covered honeycomb lattice and investigation of carrier densities in I-/I3- electrolyte by electrochemical impedance spectroscopy, Appl. Surf. Sci., 357 (2015) 2206–2216.
  • [28] Bayramoglu H., Peksoz A., Electronic energy levels and electrochemical properties of co-electrodeposited CdSe thin films, Mater. Sci. Semicond. Process, 90 (2019) 13–19.
There are 28 citations in total.

Details

Primary Language English
Subjects Material Physics, Solid State Chemistry
Journal Section Natural Sciences
Authors

Sevda İldan Özmen 0000-0002-4222-0330

Publication Date September 30, 2024
Submission Date March 20, 2024
Acceptance Date September 23, 2024
Published in Issue Year 2024

Cite

APA İldan Özmen, S. (2024). Characterization of ZnSe Thin Film Electrodeposited at Room Temperature in Aqueous Medium without Complexing Agents. Cumhuriyet Science Journal, 45(3), 524-529. https://doi.org/10.17776/csj.1455751