Production and Characterization of Ni0.50 Al0.50 and Ni0.55 Al0.45 Powders by Volume Combustion Synthesis
Abstract
Nickel aluminide (NiAl) is an essential intermetallic material with a high melting point and excellent high temperature corrosion resistance. It is a solid solution of Ni and Al in 40-61 mol.% Ni range. In this study, Ni0.50Al0.50 and Ni0.55Al0.45 powders were formed by using nickel and aluminum elemental powders through volume combustion synthesis (VCS). MgO powder was utilized as the thermal diluent. According to adiabatic temperature calculations, MgO was added to the reactant mixture in 10-40 vol.% range for preventing the melting and sintering of the formed Ni0.50Al0.50 and Ni0.55Al0.45 particles. After VCS, the products were ground into powder form and leached in 3M HCl solution in order to remove the MgO particles. After VCS, the samples which were obtained with 10 - 30 vol.% MgO addition were quite hard and difficult to grind. This indicated the partial sintering of the formed particles. It was relatively easier to grind into powder form the samples which contained 40 vol.% MgO. Therefore, it was determined that the most suitable MgO ratio for the formation of Ni0.50Al0.50 and Ni0.55Al0.45 powders was 40 vol.%. Formed powders were mostly in 5-100 µm particle size range. The formation of single phase pure powders was confirmed by the XRD analyses. A shift of about 0.1 degrees to higher 2-theta values was determined in the XRD peaks of the Ni0.55Al0.45 powder as compared to the Ni0.50Al0.50 phase, after annealing the powders. The results were in agreement with the crystallographic data.
Supporting Institution
Akdeniz Üniversitesi
Project Number
FDK-2021-5653
Thanks
Authors thank to Akdeniz University Scientific Research Projects Coordination Unit for supporting this study with Project No: FDK-2021-5653.
References
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- [4] Scheppe F., Sahm P.R., Hermann W., Paul U., Preuhs J., Nickel aluminides: a step toward industrial application, Mater. Sci. Eng. A ., 329 (2002) 596-601.
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- [6] Kaplanskii Y.Y., Zaitsev A.A., Sentyurina Z.A., Levashov E.A., Pogozhev Y.S., Loginov P.A., Logachev I.A., The structure and properties of pre-alloyed NiAl-Cr (Co, Hf) spherical powders produced by plasma rotating electrode processing for additive manufacturing, J. Mater. Res. Technol., 7(4) (2018) 461-468.
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- [8] Liu Y., Cai X., Sun Z., Zhang H., Akhtar F., Czujko T., Feng P., Fabrication and Characterization of Highly Porous FeAl‐Based Intermetallics by Thermal Explosion Reaction, Adv. Eng. Mater., 21(4) (2019) 1801110.
- [9] Yeh C.L., Su S.H., Chang H.Y., Effects of TiC addition on combustion synthesis of NiAl in SHS mode, J. Alloys Compd., 398(1-2) (2005) 85-93.
- [10] Sarıyer G., Çamurlu, H.E., Effect of Diluent Amount on Properties of Porous NiAl, Gazi Univ. J. Sci. Part A : Eng. Innov., 9(4) (2022) 429-438.
- [11] Terada Y., Ohkubo K., Mohri T., Suzuki T., Thermal conductivity of intermetallic compounds with metallic bonding, Mater. Trans., 43 (12) (2002) 3167-3176.
- [12] López G.A., Sommadossi S., Gust W., Zieba P., Phase Characterization of Diffusion Soldered Ni/Al/Ni Interconnections, Interface Science 10(1) (2002) 13-19.
- [13] Cullity B.D., Elements of X-ray Diffraction, Addison-Wesley Publishing, (1956).
Abstract
Project Number
FDK-2021-5653
References
- [1] Portnoy V. K., Blinov A.M., Tomilin I. A., Kuznetsov V. N., Kulik T, Formation of nickel aluminides by mechanical alloying and thermodynamics of interaction, J. Alloys Compd., 336(1-2) (2002) 196-201.
- [2] Pasturel A., Colinet C., Paxton A.T., Van Schilfgaarde M., First-principles determination of the Ni-Al phase diagram, J. Phys. Condens., 4(4) (1992) 945.
- [3] Bochenek K., Basista M., Advances in processing of NiAl intermetallic alloys and composites for high temperature aerospace applications, Prog. Aerosp. Sci., 79 (2015) 136-146.
- [4] Scheppe F., Sahm P.R., Hermann W., Paul U., Preuhs J., Nickel aluminides: a step toward industrial application, Mater. Sci. Eng. A ., 329 (2002) 596-601.
- [5] Povarova K.B., Skachkov O.A., Kazanskaya N.K., Drozdov A.A., Morozov A. E., Makarevich O. N., NiAl powder alloys: I. Production of NiAl powders, Russ. Metall., 2011 (2011) 844-852.
- [6] Kaplanskii Y.Y., Zaitsev A.A., Sentyurina Z.A., Levashov E.A., Pogozhev Y.S., Loginov P.A., Logachev I.A., The structure and properties of pre-alloyed NiAl-Cr (Co, Hf) spherical powders produced by plasma rotating electrode processing for additive manufacturing, J. Mater. Res. Technol., 7(4) (2018) 461-468.
- [7] Varma A., Rogachev A.S., Mukasyan A.S., Hwang S., Combustion synthesis of advanced materials: principles and applications, Adv. Chem. Eng., 24 (1998) 79-226.
- [8] Liu Y., Cai X., Sun Z., Zhang H., Akhtar F., Czujko T., Feng P., Fabrication and Characterization of Highly Porous FeAl‐Based Intermetallics by Thermal Explosion Reaction, Adv. Eng. Mater., 21(4) (2019) 1801110.
- [9] Yeh C.L., Su S.H., Chang H.Y., Effects of TiC addition on combustion synthesis of NiAl in SHS mode, J. Alloys Compd., 398(1-2) (2005) 85-93.
- [10] Sarıyer G., Çamurlu, H.E., Effect of Diluent Amount on Properties of Porous NiAl, Gazi Univ. J. Sci. Part A : Eng. Innov., 9(4) (2022) 429-438.
- [11] Terada Y., Ohkubo K., Mohri T., Suzuki T., Thermal conductivity of intermetallic compounds with metallic bonding, Mater. Trans., 43 (12) (2002) 3167-3176.
- [12] López G.A., Sommadossi S., Gust W., Zieba P., Phase Characterization of Diffusion Soldered Ni/Al/Ni Interconnections, Interface Science 10(1) (2002) 13-19.
- [13] Cullity B.D., Elements of X-ray Diffraction, Addison-Wesley Publishing, (1956).
Details
| Primary Language | English |
|---|---|
| Subjects | Material Production Technologies |
| Journal Section | Natural Sciences |
| Authors | |
| Project Number | FDK-2021-5653 |
| Publication Date | March 28, 2024 |
| Submission Date | April 10, 2023 |
| Acceptance Date | February 1, 2024 |
| Published in Issue | Year 2024 |