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Exploration of Seasonal Metal Pollution in Karacaören II Dam Lake Sediment Samples using X-ray Fluorescence Method

Year 2023, , 567 - 582, 29.09.2023

Gökhan Apaydın , Oğuz Kağan Köksal , Erhan Cengiz , Murat Şirin , Hasan Baltas , Engin Tıraşoğlu

https://doi.org/10.17776/csj.1269391
Cited By: 1

Abstract

In this study, the seasonal metal pollution of sediment samples taken from twelve distinct notes of the Karacaören II Dam Lake was examined. The quantity of metal in soil samples was determined using energy dispersive X-ray fluorescence spectroscopy. The geoaccumulation index and enrichment factor expressions were created using the metal concentrations found in the sediments. Seasonal values at the local, state, and international levels were compared to the findings. The ratios of the elements copper, zinc, lead, arsenic, nickel, chromium, and mercury, measured in parts per million (ppm), were found to be 42-96, 53-78, 11-14, 4-7, 233-244, and 611-711, respectively. There is also discussion of the sediments' elemental composition and degree of pollution. In contrast, it was found that the Urbach energy increased from 0.246 eV to 0.630 eV with increasing levels of V2O5. These synthetic glasses' densities and molar volumes were also investigated and discussed.

Keywords

Karacaören II dam lake Sediment Heavy metal Pollution ED-XRF.

Supporting Institution

TÜBİTAK

Project Number

115Y768

Thanks

This work has been made possible thanks to TUBITAK Project No. 115Y768 from the Turkish Council for Scientific and Technological Research.

References

  • [1] Casas J., Rosas H., Solé M., Lao C., Heavy metals and metalloids in sediments from the Llobregat basin, Spain, Environmental Geology, 44 (2003) 325-332.
  • [2] Singh K.P., Mohan D., Singh V.K., Malik A., Studies on distribution and fractionation of heavy metals in Gomti river sediments—a tributary of the Ganges, India, Journal of Hydrology, 312 (2005) 14-27.
  • [3] Mwamburi J., Variations in trace elements in bottom sediments of major rivers in Lake Victoria's basin, Kenya, Lakes & Reservoirs: Research & Management, 8 (2003) 5-13.
  • [4] Ghrefat H., Yusuf N., Assessing Mn, Fe, Cu, Zn, and Cd pollution in bottom sediments of Wadi Al-Arab Dam, Jordan, Chemosphere, 65 (2006) 2114-2121.
  • [5] Khaled A., El Nemr A., El Sikaily A., An assessment of heavy-metal contamination in surface sediments of the Suez Gulf using geoaccumulation indexes and statistical analysis, Chemistry and Ecology, 22 (2006) 239-252.
  • [6] Linnik P.M., Zubenko I.B., Role of bottom sediments in the secondary pollution of aquatic environments by heavy‐metal compounds, Lakes & Reservoirs: Research & Management, 5 (2000) 11-21.
  • [7] Makundi I.N., A study of heavy metal pollution in Lake Victoria sediments by energy dispersive X-ray fluorescence, Journal of Environmental Science and Health, Part A, 36 (2001) 909-921.
  • [8] Çevik F., Göksu M.Z.L., Derici O.B., Fındık Ö., An assessment of metal pollution in surface sediments of Seyhan dam by using enrichment factor, geoaccumulation index and statistical analyses, Environmental monitoring and assessment, 152 (2009) 309-317.
  • [9] Şener Ş., Elitok Ö., Şener E., Davraz A., An investigation of Mn contents in water and bottom sediments from Eğirdir Lake, Turkey, Mühendislik Bilimleri ve Tasarım Dergisi, 1 (2011) 145-149.
  • [10] Bat L., Yesim Ozkan E., Oztekin H. Can, The contamination status of trace metals in Sinop coast of the Black Sea, Turkey, (2015).
  • [11] Bryan G., Some aspects of heavy metal tolerance in aquatic organisms, Effects of pollutants on aquatic organisms, 2 (1976) 7- 34.
  • [12] Fernandez-Leborans G., Herrero Y.O., Toxicity and bioaccumulation of lead and cadmium in marine protozoan communities, Ecotoxicology and environmental safety, 47 (2000) 266-276.
  • [13] Järup L., Hazards of heavy metal contamination, British medical bulletin, 68 (2003) 167-182.
  • [14] Turekian K.K., Marine geochemistry, Eos, Transactions American Geophysical Union, 52 (1971) IUGG237-IUGG244.
  • [15] Alkan A., Alkan N., Yanar B., Investigation of pollution levels originated from anthropogenic gadolinium in Ankara Stream, Environmental Science and Pollution Research, 27 (2020) 23677-23685.
  • [16] Chatterjee M., Silva Filho E., Sarkar S., Sella S., Bhattacharya A., Satpathy K., Prasad M., Chakraborty S., Bhattacharya B., Distribution and possible source of trace elements in the sediment cores of a tropical macrotidal estuary and their ecotoxicological significance, Environment International, 33 (2007) 346-356.
  • [17] Idris A.M., Combining multivariate analysis and geochemical approaches for assessing heavy metal level in sediments from Sudanese harbors along the Red Sea coast, Microchemical Journal, 90 (2008) 159-163.
  • [18] Ozkan E.Y., Buyukisik B., Geochemical and statistical approach for assessing heavy metal accumulation in the southern Black Sea sediments, Ekoloji, 21 (2012) 11-24.
  • [19] Wardas M., Budek L., Rybicka E.H., Variability of heavy metals content in bottom sediments of the Wilga River, a tributary of the Vistula River (Krakow area, Poland), Applied Geochemistry, 11 (1996) 197-202.
  • [20] Diken G., Köknaroğlu H., Can İ., Cultural energy use and energy use efficiency of a small-scale rainbow trout (Oncorhynchus mykiss Walbaum, 1792) cage farm in the inland waters of Turkey: A case study from Karacaören-I Dam Lake, Aquaculture Studies, 21 (2020) 31-39.
  • [21] Kir I., Erdogan M., Engin M.S., Cay S., Trace metals in sediment, water and their bioaccumalation in Carp (Cyprinus Carpio L., 1758) samples, captured from the Karacaoren (I) Dam Lake, Turkey, Fresenius Environmental Bulletin, 25 (2016) 3557-3562.
  • [22] Citil O.B., Kalyoncu L., Kahraman O., Fatty acid composition of the muscle lipids of five fish species in Işıklı and Karacaören Dam Lake, Turkey, Veterinary Medicine International, (2014) 2014.
  • [23] Kalyoncu L., Kalyoncu H., Arslan G., Determination of heavy metals and metals levels in five fish species from Işıklı Dam Lake and Karacaören Dam Lake (Turkey), Environmental monitoring and assessment, 184 (2012) 2231-2235.
  • [24] Ozvarol Z., Karabacak G., Changes in the population structure of pikeperch (Sander lucioperca Linnaeus, 1758) Karacaoren-I Dam Lake, Turkey, Journal of Animal and Veterinary Advances, 10 (2011) 224-228.
  • [25] Ozvarol Z.A.B., Ramazan I., Mortality ratio and stock analysis of Vimba (Vimba vimba tenella (Nordmann, 1840)) population ın Karacaoren I Dam Lake (Burdur-Turkey), Journal of Applied Biological Sciences, 3 (2009) 143-147.
  • [26] Becer Z., İkiz R., Investigation of some biological characters of the Vimba (Vimba vimba tenella (Nordmann, 1840)) population in Karacaören I Dam Lake, Turkish Journal of Veterinary & Animal Sciences, 25 (2001) 111-117.
  • [27] Diler, A., Becer Z., Chemical composition and meat yield of vimba (Vimba vimba tenella (Nordmann, 1840)) in Karacaören I Dam Lake, Turkish Journal of Veterinary & Animal Sciences, 25 (2001) 87-92.
  • [28] Mahommed N., Makundi I., Optimization of EDXRF for the study of heavy metal pollution of Lake Victoria, Tanzania Journal of Science, 28 (2002) 7-24.
  • [29] Al-Haidarey M., Hassan F., Al-Kubaisey A., Douabul A., The geoaccumulation index of some heavy metals in Al-Hawizeh Marsh, Iraq, E-Journal of Chemistry, 7 (2010) S157-S162.
  • [30] Loska K., Cebula J., Pelczar J., Wiechuła D., KwapulińskiJ., Use of enrichment, and contamination factors together with geoaccumulation indexes to evaluate the content of Cd, Cu, and Ni in the Rybnik water reservoir in Poland, Water, Air, and Soil Pollution, 93 (1997) 347-365.
  • [31] Hasan A.B., Kabir S., Reza A.S., Zaman M.N., Ahsan A., Rashid M., Enrichment factor and geo-accumulation index of trace metals in sediments of the ship breaking area of Sitakund Upazilla (Bhatiary–Kumira), Chittagong, Bangladesh, Journal of Geochemical Exploration, 125 (2013) 130-137.
  • [32] Krauskoph K., Bird D., Introduction to geochemistry McGraw-Hill Inc, New York, (1995) 647.
  • [33] Krauskopf K.B., Bird D.K., Introduction to geochemistry, McGraw-Hill New York, 1967.
  • [34] Karadede H., Ünlü E., Concentrations of some heavy metals in water, sediment and fish species from the Atatürk Dam Lake (Euphrates), Turkey, Chemosphere, 41 (2000) 1371-1376.
  • [35] Çevik F., Göksu M.Z.L., Derici O.B., Fındık Ö., An assessment of metal pollution in surface sediments of Seyhan dam by using enrichment factor, geoaccumulation index and statistical analyses, Environmental monitoring and assessment, 152 (2009) 309-317.
  • [36] Kır I., Tumantozlu H., Investigation of some heavy metal accumulation in water, sediment and carp (Cyprinus carpio) samples of Karacaoren-II Dam Lake, Ekoloji, 21 (2012) 65-70.
  • [37] Öztürk M., Özözen G., Minareci O., Minareci E., Determination of heavy metals in fish, water and sediments of Avsar Dam Lake in Turkey, Journal of Environmental Health Science & Engineering, 6 (2009) 73-80.
  • [38] Uysal K., Özden Y., Çiçek A., Esengül K., Bioaccumulation ratios of sediment-bound heavy metals of Porsuk and Enne Dam Lakes (Kütahya/Turkey) to different tissues of common carp (Cyprinus carpio), Aquatic Sciences and Engineering, 25 (2010) 1-10.
  • [39] Akin B.S., Kırmızıgül O., Heavy metal contamination in surface sediments of Gökçekaya Dam Lake, Eskişehir, Turkey, Environmental Earth Sciences, 76 (2017) 1-11.

Year 2023, , 567 - 582, 29.09.2023

Gökhan Apaydın , Oğuz Kağan Köksal , Erhan Cengiz , Murat Şirin , Hasan Baltas , Engin Tıraşoğlu

https://doi.org/10.17776/csj.1269391
Cited By: 1

Abstract

Project Number

115Y768

References

  • [1] Casas J., Rosas H., Solé M., Lao C., Heavy metals and metalloids in sediments from the Llobregat basin, Spain, Environmental Geology, 44 (2003) 325-332.
  • [2] Singh K.P., Mohan D., Singh V.K., Malik A., Studies on distribution and fractionation of heavy metals in Gomti river sediments—a tributary of the Ganges, India, Journal of Hydrology, 312 (2005) 14-27.
  • [3] Mwamburi J., Variations in trace elements in bottom sediments of major rivers in Lake Victoria's basin, Kenya, Lakes & Reservoirs: Research & Management, 8 (2003) 5-13.
  • [4] Ghrefat H., Yusuf N., Assessing Mn, Fe, Cu, Zn, and Cd pollution in bottom sediments of Wadi Al-Arab Dam, Jordan, Chemosphere, 65 (2006) 2114-2121.
  • [5] Khaled A., El Nemr A., El Sikaily A., An assessment of heavy-metal contamination in surface sediments of the Suez Gulf using geoaccumulation indexes and statistical analysis, Chemistry and Ecology, 22 (2006) 239-252.
  • [6] Linnik P.M., Zubenko I.B., Role of bottom sediments in the secondary pollution of aquatic environments by heavy‐metal compounds, Lakes & Reservoirs: Research & Management, 5 (2000) 11-21.
  • [7] Makundi I.N., A study of heavy metal pollution in Lake Victoria sediments by energy dispersive X-ray fluorescence, Journal of Environmental Science and Health, Part A, 36 (2001) 909-921.
  • [8] Çevik F., Göksu M.Z.L., Derici O.B., Fındık Ö., An assessment of metal pollution in surface sediments of Seyhan dam by using enrichment factor, geoaccumulation index and statistical analyses, Environmental monitoring and assessment, 152 (2009) 309-317.
  • [9] Şener Ş., Elitok Ö., Şener E., Davraz A., An investigation of Mn contents in water and bottom sediments from Eğirdir Lake, Turkey, Mühendislik Bilimleri ve Tasarım Dergisi, 1 (2011) 145-149.
  • [10] Bat L., Yesim Ozkan E., Oztekin H. Can, The contamination status of trace metals in Sinop coast of the Black Sea, Turkey, (2015).
  • [11] Bryan G., Some aspects of heavy metal tolerance in aquatic organisms, Effects of pollutants on aquatic organisms, 2 (1976) 7- 34.
  • [12] Fernandez-Leborans G., Herrero Y.O., Toxicity and bioaccumulation of lead and cadmium in marine protozoan communities, Ecotoxicology and environmental safety, 47 (2000) 266-276.
  • [13] Järup L., Hazards of heavy metal contamination, British medical bulletin, 68 (2003) 167-182.
  • [14] Turekian K.K., Marine geochemistry, Eos, Transactions American Geophysical Union, 52 (1971) IUGG237-IUGG244.
  • [15] Alkan A., Alkan N., Yanar B., Investigation of pollution levels originated from anthropogenic gadolinium in Ankara Stream, Environmental Science and Pollution Research, 27 (2020) 23677-23685.
  • [16] Chatterjee M., Silva Filho E., Sarkar S., Sella S., Bhattacharya A., Satpathy K., Prasad M., Chakraborty S., Bhattacharya B., Distribution and possible source of trace elements in the sediment cores of a tropical macrotidal estuary and their ecotoxicological significance, Environment International, 33 (2007) 346-356.
  • [17] Idris A.M., Combining multivariate analysis and geochemical approaches for assessing heavy metal level in sediments from Sudanese harbors along the Red Sea coast, Microchemical Journal, 90 (2008) 159-163.
  • [18] Ozkan E.Y., Buyukisik B., Geochemical and statistical approach for assessing heavy metal accumulation in the southern Black Sea sediments, Ekoloji, 21 (2012) 11-24.
  • [19] Wardas M., Budek L., Rybicka E.H., Variability of heavy metals content in bottom sediments of the Wilga River, a tributary of the Vistula River (Krakow area, Poland), Applied Geochemistry, 11 (1996) 197-202.
  • [20] Diken G., Köknaroğlu H., Can İ., Cultural energy use and energy use efficiency of a small-scale rainbow trout (Oncorhynchus mykiss Walbaum, 1792) cage farm in the inland waters of Turkey: A case study from Karacaören-I Dam Lake, Aquaculture Studies, 21 (2020) 31-39.
  • [21] Kir I., Erdogan M., Engin M.S., Cay S., Trace metals in sediment, water and their bioaccumalation in Carp (Cyprinus Carpio L., 1758) samples, captured from the Karacaoren (I) Dam Lake, Turkey, Fresenius Environmental Bulletin, 25 (2016) 3557-3562.
  • [22] Citil O.B., Kalyoncu L., Kahraman O., Fatty acid composition of the muscle lipids of five fish species in Işıklı and Karacaören Dam Lake, Turkey, Veterinary Medicine International, (2014) 2014.
  • [23] Kalyoncu L., Kalyoncu H., Arslan G., Determination of heavy metals and metals levels in five fish species from Işıklı Dam Lake and Karacaören Dam Lake (Turkey), Environmental monitoring and assessment, 184 (2012) 2231-2235.
  • [24] Ozvarol Z., Karabacak G., Changes in the population structure of pikeperch (Sander lucioperca Linnaeus, 1758) Karacaoren-I Dam Lake, Turkey, Journal of Animal and Veterinary Advances, 10 (2011) 224-228.
  • [25] Ozvarol Z.A.B., Ramazan I., Mortality ratio and stock analysis of Vimba (Vimba vimba tenella (Nordmann, 1840)) population ın Karacaoren I Dam Lake (Burdur-Turkey), Journal of Applied Biological Sciences, 3 (2009) 143-147.
  • [26] Becer Z., İkiz R., Investigation of some biological characters of the Vimba (Vimba vimba tenella (Nordmann, 1840)) population in Karacaören I Dam Lake, Turkish Journal of Veterinary & Animal Sciences, 25 (2001) 111-117.
  • [27] Diler, A., Becer Z., Chemical composition and meat yield of vimba (Vimba vimba tenella (Nordmann, 1840)) in Karacaören I Dam Lake, Turkish Journal of Veterinary & Animal Sciences, 25 (2001) 87-92.
  • [28] Mahommed N., Makundi I., Optimization of EDXRF for the study of heavy metal pollution of Lake Victoria, Tanzania Journal of Science, 28 (2002) 7-24.
  • [29] Al-Haidarey M., Hassan F., Al-Kubaisey A., Douabul A., The geoaccumulation index of some heavy metals in Al-Hawizeh Marsh, Iraq, E-Journal of Chemistry, 7 (2010) S157-S162.
  • [30] Loska K., Cebula J., Pelczar J., Wiechuła D., KwapulińskiJ., Use of enrichment, and contamination factors together with geoaccumulation indexes to evaluate the content of Cd, Cu, and Ni in the Rybnik water reservoir in Poland, Water, Air, and Soil Pollution, 93 (1997) 347-365.
  • [31] Hasan A.B., Kabir S., Reza A.S., Zaman M.N., Ahsan A., Rashid M., Enrichment factor and geo-accumulation index of trace metals in sediments of the ship breaking area of Sitakund Upazilla (Bhatiary–Kumira), Chittagong, Bangladesh, Journal of Geochemical Exploration, 125 (2013) 130-137.
  • [32] Krauskoph K., Bird D., Introduction to geochemistry McGraw-Hill Inc, New York, (1995) 647.
  • [33] Krauskopf K.B., Bird D.K., Introduction to geochemistry, McGraw-Hill New York, 1967.
  • [34] Karadede H., Ünlü E., Concentrations of some heavy metals in water, sediment and fish species from the Atatürk Dam Lake (Euphrates), Turkey, Chemosphere, 41 (2000) 1371-1376.
  • [35] Çevik F., Göksu M.Z.L., Derici O.B., Fındık Ö., An assessment of metal pollution in surface sediments of Seyhan dam by using enrichment factor, geoaccumulation index and statistical analyses, Environmental monitoring and assessment, 152 (2009) 309-317.
  • [36] Kır I., Tumantozlu H., Investigation of some heavy metal accumulation in water, sediment and carp (Cyprinus carpio) samples of Karacaoren-II Dam Lake, Ekoloji, 21 (2012) 65-70.
  • [37] Öztürk M., Özözen G., Minareci O., Minareci E., Determination of heavy metals in fish, water and sediments of Avsar Dam Lake in Turkey, Journal of Environmental Health Science & Engineering, 6 (2009) 73-80.
  • [38] Uysal K., Özden Y., Çiçek A., Esengül K., Bioaccumulation ratios of sediment-bound heavy metals of Porsuk and Enne Dam Lakes (Kütahya/Turkey) to different tissues of common carp (Cyprinus carpio), Aquatic Sciences and Engineering, 25 (2010) 1-10.
  • [39] Akin B.S., Kırmızıgül O., Heavy metal contamination in surface sediments of Gökçekaya Dam Lake, Eskişehir, Turkey, Environmental Earth Sciences, 76 (2017) 1-11.
There are 39 citations in total.

Details

Primary Language English
Subjects Classical Physics (Other)
Journal Section Natural Sciences
Authors

Gökhan Apaydın 0000-0002-4647-344X

Oğuz Kağan Köksal 0000-0003-2671-6683

Erhan Cengiz 0000-0002-4094-5784

Murat Şirin 0000-0001-6864-752X

Hasan Baltas 0000-0002-1939-8253

Engin Tıraşoğlu 0000-0001-7953-5638

Project Number 115Y768
Publication Date September 29, 2023
Submission Date March 22, 2023
Acceptance Date July 7, 2023
Published in Issue Year 2023

Cite

APA Apaydın, G., Köksal, O. K., Cengiz, E., Şirin, M., et al. (2023). Exploration of Seasonal Metal Pollution in Karacaören II Dam Lake Sediment Samples using X-ray Fluorescence Method. Cumhuriyet Science Journal, 44(3), 567-582. https://doi.org/10.17776/csj.1269391

Cited By

Analysis the Metal Composition of Fish Samples Collected From Karacaören II Dam Lake
Journal of Anatolian Environmental and Animal Sciences
https://doi.org/10.35229/jaes.1419710