Synthesis and Characterization of Cationic P(AAm-AETAC) Hydrogels, and Their Uses in Adsorption of Titan Yellow
Abstract
In this study, a new cationic P(AAm-AETAC) hydrogels were prepared by a radical addition reaction in aqueous solution with acrylamide and [2-(acryloyloxy)ethyl] trimethylammonium chloride) comonomers in the presence of ethylene glycolmethacrylate. Hydrogels were characterized by spectroscopic, surface, and thermal analysis. The hydrogel does not undergo any structural degradation with the effect of heat up to 250 oC.
The adsorption of titan yellow from aqueous solution to the newly prepared cationic hydrogels was evaluated by Freundlich, Langmuir, and Temkin isotherms. The dye adsorption to hydrogels prepared from adsorption isotherms was L type according to the Giles adsorption isotherms. It was determined that the adsorption of titan yellow to the hydrogels prepared from the RL values calculated for a concentration of 500 mg L-1 titan yellow was favorable. The dye removal efficiency of the hydrogel from the aqueous solution was found to be about 98%. As a result, it can be said that the cationic P(AAm-AETAC) hydrogel, which is prepared at a low cost, can provide a high amount of removal in the adsorption of anionic dyes from aqueous solutions.
Keywords
[2-(acryloyloxy)ethyl] trimethylammonium chloride Acrylamide Hydrogel Titan yellow Adsorption
Project Number
Yok
References
- [1] El-Azazy M., Dimassi S., El-Shafie A., Issa A., Bio-Waste Aloe vera Leaves as an Efficient Adsorbent for Titan Yellow from Wastewater: Structuring of a Novel Adsorbent Using Plackett-Burman Factorial Design, Appl. Sci., 9 (2019) 4856.
- [2] Işıkver Y., Synthesis of Anionic Hydrogels for Uranyl Ion Adsorption, Cumhuriyet Sci. J., 38(4) (2017) 770–780.
- [3] Işikver Y.,Removal of some cationic dyes from aqueous solution by acrylamide- or 2-hydroxyethyl methacrylate-based copolymeric hydrogels, Fiber. Polym.,18(11) (2017) 2070–2078.
- [4] Cheng X., Li N., Zhu M., Zhang L., Deng Y., Deng C., Positively charged microporous ceramic membrane for the removal of Titan Yellow through electrostatic adsorption, J. Environ. Sci., 44 (2016) 204–212.
- [5] Ghaemi M., Absalan G., Sheikhian L., Adsorption characteristics of Titan yellow and Congo red on CoFe2O4 magnetic nanoparticles, J. Iran. Chem. Soc., 11(6) (2014) 1759–1766.
- [6] Web of Science, WOS. Available at: https://www.webofscience.com/wos/woscc/summary/36b6867e-d99d-4371-8868-4ac9292c9274-0d0c3701/relevance/1. Retrieved October 14, 2021.
- [7] Rastgordani M., Zolgharnein J., Mahdavi V., Derivative spectrophotometry and multivariate optimization for simultaneous removal of Titan yellow and Bromophenol blue dyes using polyaniline@SiO2 nanocomposite, Microchem. J., 155 (2020) 104717.
- [8] Sun J., Ma X., Li X., Fan J., Chen Q., Liu X., Pan J., Synthesis of a Cationic Polyacrylamide under UV Initiation and Its Flocculation in Estrone Removal, Int. J. Polym. Sci., 2018 (2018) 1–11.
- [9] Feng L., Zheng H., Tang X., Zheng X., Liu S., Sun Q., Wang M., The investigation of the specific behavior of a cationic block structure and its excellent flocculation performance in high-turbidity water treatment, RSC Adv., 8(27) (2018) 15119–15133.
- [10] Giles C. H., MacEwan T. H., Nakhwa S. N., Smith D., Studies in adsorption. Part XI. A system of classification of solution adsorption isotherms, and its use in diagnosis of adsorption mechanisms and in measurement of specific surface areas of solids, J. Chem. Soc., 786 (1960) 3973-3993.
- [11] Ivanovska A., Dojčinović B., Maletic S., Pavun L., Asanović K., Kostić M., Waste Jute Fabric as a Biosorbent for Heavy Metal Ions from Aqueous Solution, Fiber. Polym., 21 (2020) 1992-2002.
- [12] Saraydın D., Işıkver Y., Karadağ E,. A Study on the Correlation Between Adsorption and Swelling for Poly(Hydroxamic Acid) Hydrogels-Triarylmethane Dyes Systems, J. Polym. Environ., 26(9) (2018) 3924–3936.
- [13] Yabo W., Yi X., Yongkui Z., Siyang T., Chencen G., Jiansheng W., Raymond L., Chem. Eng. Res. Des., 114 (2016) 258-267.
- [14] Nechifor G., Pascu D. E., Pascu M., Traistaru G. A., Albu P. C., U.P.B. Sci. Bull. Series B, 77 (2015) 63-72.
Abstract
Supporting Institution
Yok
Project Number
Yok
Thanks
Yok
References
- [1] El-Azazy M., Dimassi S., El-Shafie A., Issa A., Bio-Waste Aloe vera Leaves as an Efficient Adsorbent for Titan Yellow from Wastewater: Structuring of a Novel Adsorbent Using Plackett-Burman Factorial Design, Appl. Sci., 9 (2019) 4856.
- [2] Işıkver Y., Synthesis of Anionic Hydrogels for Uranyl Ion Adsorption, Cumhuriyet Sci. J., 38(4) (2017) 770–780.
- [3] Işikver Y.,Removal of some cationic dyes from aqueous solution by acrylamide- or 2-hydroxyethyl methacrylate-based copolymeric hydrogels, Fiber. Polym.,18(11) (2017) 2070–2078.
- [4] Cheng X., Li N., Zhu M., Zhang L., Deng Y., Deng C., Positively charged microporous ceramic membrane for the removal of Titan Yellow through electrostatic adsorption, J. Environ. Sci., 44 (2016) 204–212.
- [5] Ghaemi M., Absalan G., Sheikhian L., Adsorption characteristics of Titan yellow and Congo red on CoFe2O4 magnetic nanoparticles, J. Iran. Chem. Soc., 11(6) (2014) 1759–1766.
- [6] Web of Science, WOS. Available at: https://www.webofscience.com/wos/woscc/summary/36b6867e-d99d-4371-8868-4ac9292c9274-0d0c3701/relevance/1. Retrieved October 14, 2021.
- [7] Rastgordani M., Zolgharnein J., Mahdavi V., Derivative spectrophotometry and multivariate optimization for simultaneous removal of Titan yellow and Bromophenol blue dyes using polyaniline@SiO2 nanocomposite, Microchem. J., 155 (2020) 104717.
- [8] Sun J., Ma X., Li X., Fan J., Chen Q., Liu X., Pan J., Synthesis of a Cationic Polyacrylamide under UV Initiation and Its Flocculation in Estrone Removal, Int. J. Polym. Sci., 2018 (2018) 1–11.
- [9] Feng L., Zheng H., Tang X., Zheng X., Liu S., Sun Q., Wang M., The investigation of the specific behavior of a cationic block structure and its excellent flocculation performance in high-turbidity water treatment, RSC Adv., 8(27) (2018) 15119–15133.
- [10] Giles C. H., MacEwan T. H., Nakhwa S. N., Smith D., Studies in adsorption. Part XI. A system of classification of solution adsorption isotherms, and its use in diagnosis of adsorption mechanisms and in measurement of specific surface areas of solids, J. Chem. Soc., 786 (1960) 3973-3993.
- [11] Ivanovska A., Dojčinović B., Maletic S., Pavun L., Asanović K., Kostić M., Waste Jute Fabric as a Biosorbent for Heavy Metal Ions from Aqueous Solution, Fiber. Polym., 21 (2020) 1992-2002.
- [12] Saraydın D., Işıkver Y., Karadağ E,. A Study on the Correlation Between Adsorption and Swelling for Poly(Hydroxamic Acid) Hydrogels-Triarylmethane Dyes Systems, J. Polym. Environ., 26(9) (2018) 3924–3936.
- [13] Yabo W., Yi X., Yongkui Z., Siyang T., Chencen G., Jiansheng W., Raymond L., Chem. Eng. Res. Des., 114 (2016) 258-267.
- [14] Nechifor G., Pascu D. E., Pascu M., Traistaru G. A., Albu P. C., U.P.B. Sci. Bull. Series B, 77 (2015) 63-72.
Details
| Primary Language | English |
|---|---|
| Journal Section | Natural Sciences |
| Authors | |
| Project Number | Yok |
| Publication Date | March 30, 2022 |
| Submission Date | September 24, 2021 |
| Acceptance Date | January 27, 2022 |
| Published in Issue | Year 2022 |