Hydrothermal synthesis and crystal structures of a novel Keggin-type polyoxometalate based on 1,10-phenanthroline

Asuman Uçar; Mükerrem Fındık; Nuriye Koçak; Alper Çolak; Onur Şahin

doi:10.17776/csj.812164

EN

Hydrothermal synthesis and crystal structures of a novel Keggin-type polyoxometalate based on 1,10-phenanthroline

Abstract

Herein a novel inorganic-organic hybrid Keggin-type heteropolymolybdate [Ni2Na(C12H8N2)4(BMo12O40)(H2O)2] (1) has been synthesized under hydrothermal conditions in aqueous solution. The cyrstal structure was fully characterized by powder X-ray diffraction (XRD), elemental analysis, Fourier-tranform infrared spectrum (FT-IR), Thermogravimetric analysis (TGA) and Scanning Electron Microscopy (SEM) analysis. Single crystal X-ray structural analysis demonstrates that the complex consists of a Keggin anion [BMo12O40]5− polyanion, four 1,10-phenanthroline (C12H8N2) ligands, two Ni(II) ions, two Na(I) ions and two aqua ligands. The experimental powder X-ray diffraction (XRD) result of the crystal is consistent with the calculated data. The SEM image shows that the compound crystals have a cubic structure.

Keywords

Supporting Institution

Necmettin Erbakan University Research Foundation

Project Number

151210002

References

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Details

Primary Language

English

Subjects

-

Journal Section

Research Article

Authors

Asuman Uçar ^*
0000-0003-2674-3120
Türkiye

Mükerrem Fındık
0000-0002-9441-0814
Türkiye

Nuriye Koçak
0000-0002-0531-3538
Türkiye

Alper Çolak
0000-0003-4478-7792
Türkiye

Onur Şahin
0000-0003-3765-3235
Türkiye

Publication Date

March 29, 2021

Submission Date

October 18, 2020

Acceptance Date

January 21, 2021

Published in Issue

Year 2021 Volume: 42 Number: 1

DOI

https://doi.org/10.17776/csj.812164

IZ

https://izlik.org/JA82AC99GM

Cite

RIS / Bibtex

APA

Uçar, A., Fındık, M., Koçak, N., Çolak, A., & Şahin, O. (2021). Hydrothermal synthesis and crystal structures of a novel Keggin-type polyoxometalate based on 1,10-phenanthroline. Cumhuriyet Science Journal, 42(1), 22-29. https://doi.org/10.17776/csj.812164

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Applied Organometallic Chemistry

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Öz

Hydrothermal synthesis and crystal structures of a novel Keggin-type polyoxometalate based on 1,10-phenanthroline

Abstract

Keywords

Supporting Institution

Project Number

References

Details

Primary Language

Subjects

Journal Section

Authors

Publication Date

Submission Date

Acceptance Date

Published in Issue

DOI

IZ

Cite

Cited By

Synthesis, spectroscopic, DFT calculations, antimicrobial, cytotoxicity, and DNA binding studies of novel Cu (II), Ni (II), Zn (II), and VO (II) Schiff base complexes based on ibuprofen

Efficiency and development of guanidine chelate catalysts for rapid and green synthesis of 7‐amino‐4,5‐dihydro‐tetrazolo[1,5‐a]pyrimidine‐6‐carbonitrile derivatives supported by density functional theory (DFT) studies