Hydrogen evolution by ternary metal selenide at biomembrane-like soft interfaces

Emre Aslan

doi:10.17776/csj.772412

EN

Hydrogen evolution by ternary metal selenide at biomembrane-like soft interfaces

Abstract

Two phase reactions are the analogy of biomembranes, which are polarized by Galvani potential difference at interface between two immiscible electrolyte solutions. Energy conversion reactions such as oxygen reduction reaction or hydrogen evolution reaction have been great drawn attention at soft interfaces due to the similarity of natural biochemical reactions. In this study, copper-based ternary metal selenide (copper tungsten selenide, Cu2WSe4) was first reported in the literature for hydrogen evolution reaction catalysis at the water/1,2-dichloroethane interface. The synthesized Cu2WSe4 catalyst is characterized by morphological and structural techniques. Catalytic activity of Cu2WSe4 at liquid–liquid interfaces by lipophilic decamethylferrocene as the sacrificial electron donor agent. This catalytic activity was tracked by four-electrode voltammetry at the water/1,2-dichloroethane interface and biphasic reactions monitored by gas chromatography. The rates of the hydrogen evolution reaction catalyzed by the Cu2WSe4 were found to be approximately 160-fold than the rate for the reaction performed in the absence of a catalyst.

Keywords

Supporting Institution

Selçuk Üniversitesi

Project Number

19401163

Thanks

The author would like to thank you to Selcuk University Scientific Research Projects (Grant number: 19401163) for financial supports, as well as Assoc. Prof. Dr. Faruk Ozel and Prof. Dr. Imren Hatay Patir for the valuable guidance and contributions on the use of laboratory equipment.

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Details

Primary Language

English

Subjects

-

Journal Section

Research Article

Authors

Emre Aslan ^*
0000-0002-7672-2873
Türkiye

Publication Date

March 29, 2021

Submission Date

July 21, 2020

Acceptance Date

January 16, 2021

Published in Issue

Year 2021 Volume: 42 Number: 1

DOI

https://doi.org/10.17776/csj.772412

IZ

https://izlik.org/JA67AA75PM

Cite

RIS / Bibtex

APA

Aslan, E. (2021). Hydrogen evolution by ternary metal selenide at biomembrane-like soft interfaces. Cumhuriyet Science Journal, 42(1), 13-21. https://doi.org/10.17776/csj.772412

Öz

Hydrogen evolution by ternary metal selenide at biomembrane-like soft interfaces

Abstract

Keywords

Supporting Institution

Project Number

Thanks

References

Details

Primary Language

Subjects

Journal Section

Authors

Publication Date

Submission Date

Acceptance Date

Published in Issue

DOI

IZ

Cite