Green synthesis of carbon quantum dots from sumac: characterization and investigation with cyclic voltammetry technique

Mustafa Çeşme; Hasan Eskalen

doi:10.17776/csj.714200

EN

Green synthesis of carbon quantum dots from sumac: characterization and investigation with cyclic voltammetry technique

Abstract

Carbon dots, due to their minimal size, non-toxicity, simple, cheap and easy synthesis; Among the studies on nanostructured materials that have attracted attention in recent years; has become a popular study topic for researchers. In this study, for the first time, Sumac was used as a source of carbon, and carbon dots were obtained by using the hydrothermal synthesis method in a one-pot reaction at 175 ° C for 8 hours without using any chemical reagents. The characterizations of the obtained carbon dots were illuminated by various analytical instruments (High-Resolution Transmission Electron Microscope (HR-TEM), X-ray Diffractometer (XRD), Raman, Photoluminescence, Infrared, and Uv-vis spectrometer). According to the TEM results, the average diameter of carbon dots was found as 10.48 nm. The maximum emission peak of the carbon dots was monitored at 428 nm when excited at 350 nm. In the next step, the electrochemical properties of the carbon dots were examined by cyclic voltammetry technique. According to cyclic voltammetry results, the substance transport on the electrode surface by diffusion controlled.

Keywords

Supporting Institution

Kahramanmaraş Sütçü İmam University Scientific Research Projects Coordination Unit

Project Number

Project Number: 2019/5-21 M

References

[1] Caliskan G., Dirim SN., The effect of different drying processes and the amounts of maltodextrin addition on the powder properties of sumac extract powders, Powder Technol., 287 (2016) 308–314.
[2] Tohma H., Altay A., Köksal E. et al., Measurement of anticancer, antidiabetic and anticholinergic properties of sumac (Rhus coriaria): analysis of its phenolic compounds by LC–MS/MS, J Food Meas. Charact., 13 (2019) 1607–1619.
[3] Yılmaz G., Eksi G., Demirci B. et al., Chemical Characterization of the Fatty Acid Compositions and Antmicrobial Activity of Sumac (Rhus Coriaria L.) Fruits, Growing Naturally in Turkey and Sold in Herbalist Markets, Ankara Univ. Eczac. Fak. Derg., 44 (2020) 61–69.
[4] Wang S., Zhu F., Chemical composition and biological activity of staghorn sumac (Rhus typhina), Food Chem., 237 (2017) 431–443.
[5] Ghorbani P., Namvar F., Homayouni-Tabrizi M. et al., Apoptotic efficacy and antiproliferative potential of silver nanoparticles synthesised from aqueous extract of sumac (Rhus coriaria L.), IET nanobiotechnology, 12 (2018) 600–603.
[6] Sütyemez M., Güvenç G., Bükücü ŞB. et al., The Determination of Genetic Diversity among some Sumac (Rhus coriaria L.) Genotypes, Erwerbs-Obstbau., 61 (2019) 355–361.
[7] Shabestarian H, Homayouni-Tabrizi M., Soltani M. et al., Green synthesis of gold nanoparticles using sumac aqueous extract and their antioxidant activity, Mater Res., 20 (2017) 264–270.
[8] Wu Z., Zhang Y., Gong X. et al., The preventive effect of phenolic-rich extracts from Chinese sumac fruits against nonalcoholic fatty liver disease in rats induced by a high-fat diet, Food Funct., 11 (2020) 799–812.

[9] Zhang H., You J., Wang J. et al., Highly luminescent carbon dots as temperature sensors and “off-on” sensing of Hg2+ and biothiols, Dye Pigment, 173 (2020) 107950.
[10] Yuan F., Li S., Fan Z. et al., Shining carbon dots: Synthesis and biomedical and optoelectronic applications, Nano Today, 11 (2016) 565–586.
[11] Xu Q., Li W., Ding L. et al., Function-driven engineering of 1D carbon nanotubes and 0D carbon dots: Mechanism, properties and applications, Nanoscale, 11 (2019) 475–1504.
[12] Liu ML., Chen B Bin., Li CM. et al., Carbon dots: Synthesis, formation mechanism, fluorescence origin and sensing applications, Green Chem., 21 (2019) 449–471.
[13] Eskalen H., Uruş S., Cömertpay S. et al., Microwave-assisted ultra-fast synthesis of carbon quantum dots from linter: Fluorescence cancer imaging and human cell growth inhibition properties, Ind Crops Prod 147 (2020) 112209.
[14] Ghosal K., Ghosh A., Carbon dots: The next generation platform for biomedical applications, Mater Sci Eng C., 96 (2019) 887–903.
[15] Ding H., Du F., Liu P. et al., DNA-carbon dots function as fluorescent vehicles for drug delivery, ACS Appl Mater Interfaces, 7 (2015) 6889–6897.
[16] Bandi R., Dadigala R., Gangapuram BR. et al., N-Doped carbon dots with pH-sensitive emission, and their application to simultaneous fluorometric determination of iron(III) and copper(II), Microchim Acta., 187 (2020) 1–10.
[17] De B., Karak N., A green and facile approach for the synthesis of water soluble fluorescent carbon dots from banana juice, RSC Adv., 3 (2013) 8286–8290.
[18] Sahu S., Behera B., Maiti TK. et al., Simple one-step synthesis of highly luminescent carbon dots from orange juice: application as excellent bio-imaging agents, Chem. Commun., 48 (2012) 8835–8837.
[19] Alam A-M., Park B-Y., Ghouri ZK. et al., Synthesis of carbon quantum dots from cabbage with down-and up-conversion photoluminescence properties: excellent imaging agent for biomedical applications. Green Chem., 17 (2015) 3791–3797.
[20] Bandi R., Gangapuram BR., Dadigala R. et al., Facile and green synthesis of fluorescent carbon dots from onion waste and their potential applications as sensor and multicolour imaging agents, RSC Adv. 6 (2016) 28633–28639.
[21] Cheng C., Shi Y., Li M., et al., Carbon quantum dots from carbonized walnut shells: Structural evolution, fluorescence characteristics, and intracellular bioimaging, Mater. Sci. Eng. C. 79 (2017) 473–480.
[22] Rezaei B., Irannejad N., Ensafi AA., et al., The impressive effect of eco-friendly carbon dots on improving the performance of dye-sensitized solar cells, Sol. Energy, 182 (2019) 412–419.
[23] Arul V., Sethuraman MG., Hydrothermally Green Synthesized Nitrogen-Doped Carbon Dots from Phyllanthus emblica and Their Catalytic Ability in the Detoxification of Textile Effluents, ACS Omega, 4 (2019) 3449–3457.
[24] Raji K., Ramanan V., Ramamurthy P., Facile and green synthesis of highly fluorescent nitrogen-doped carbon dots from jackfruit seeds and its applications towards the fluorimetric detection of Au 3+ ions in aqueous medium and in in vitro multicolor cell imaging, New J. Chem., 43 (2019) 11710–11719.
[25] Jayaweera S., Yin K., Hu X. et al., Fluorescent N/Al Co-Doped Carbon Dots from Cellulose Biomass for Sensitive Detection of Manganese (VII), J. Fluoresc., 29(6) (2010) 1291-1300.
[26] Pu ZF., Wen QL., Yang YJ. et al., Fluorescent carbon quantum dots synthesized using phenylalanine and citric acid for selective detection of Fe3+ ions, Spectrochim Acta - Part A Mol Biomol Spectrosc., 229 (2020) 117944.
[27] Sinha R., Bidkar AP., Rajasekhar R. et al., A facile synthesis of nontoxic luminescent carbon dots for detection of chromium and iron in real water sample and bio-imaging, Can. J. Chem. Eng., 98 (2020) 194–204.
[28] Atchudan R., Edison TNJI., Chakradhar D. et al., Facile green synthesis of nitrogen-doped carbon dots using Chionanthus retusus fruit extract and investigation of their suitability for metal ion sensing and biological applications, Sensors Actuators B. Chem., 246 (2017) 497–509.
[29] Wang J., Analytical Electrochemistry, New York: 3rd ed. John Wiley & Sons, Inc., 2006.

Details

Primary Language

English

Subjects

-

Journal Section

Research Article

Authors

Mustafa Çeşme ^*
0000-0002-2020-5965
Türkiye

Hasan Eskalen
0000-0002-4523-6573
Türkiye

Publication Date

December 29, 2020

Submission Date

April 3, 2020

Acceptance Date

December 25, 2020

Published in Issue

Year 2020 Volume: 41 Number: 4

DOI

https://doi.org/10.17776/csj.714200

IZ

https://izlik.org/JA87KT53HW

Cite

RIS / Bibtex

APA

Çeşme, M., & Eskalen, H. (2020). Green synthesis of carbon quantum dots from sumac: characterization and investigation with cyclic voltammetry technique. Cumhuriyet Science Journal, 41(4), 808-814. https://doi.org/10.17776/csj.714200

Investigating the PVA/TiO2/CDs polymer nanocomposites: effect of carbon dots for photocatalytic degradation of Rhodamine B

Journal of Materials Science: Materials in Electronics

https://doi.org/10.1007/s10854-021-07653-0

Morphology, structure and optical properties of PVA nanocomposites reinforced with bismuth oxide nanoparticles and carbon quantum dots

Journal of Materials Science: Materials in Electronics

https://doi.org/10.1007/s10854-023-10617-1

Turn-Off Fluorescence Sensor for the Detection of Ferric Ion in Water Using Green Synthesized Wrightia coccinea Carbon Quantum Dot

Journal of Fluorescence

https://doi.org/10.1007/s10895-024-03760-3

EXAMINING CARBON QUANTUM DOTS RESEARCH IN TURKEY: A SCIENTIFIC MAPPING ANALYSIS

Kahramanmaraş Sütçü İmam Üniversitesi Mühendislik Bilimleri Dergisi

https://doi.org/10.17780/ksujes.1455022

Novel approach to enhance antifungal properties via formation of wavy and Sharp microstructures composed of metal oxide nanoparticles and Cdots

Scientific Reports

https://doi.org/10.1038/s41598-025-10897-z

Green synthesis of carbon quantum dots from sumac: characterization and investigation with cyclic voltammetry technique

Öz

Green synthesis of carbon quantum dots from sumac: characterization and investigation with cyclic voltammetry technique

Abstract

Keywords

Supporting Institution

Project Number

References

Details

Primary Language

Subjects

Journal Section

Authors

Publication Date

Submission Date

Acceptance Date

Published in Issue

DOI

IZ

Cite

Cited By

Effect of ZnO Nanomaterial and Red and Green Cabbage Dyes on the Performance of Dye-Sensitised Solar Cells

Carbon Dots from Turnip Juice: Synthesis, Characterization and Investigation of pH-Dependent Optical Properties

ONE-POT SYNTHESIS OF CARBON QUANTUM DOTS AND THEIR APPLICATION AS A FLUORESCENT INKS

Investigating the PVA/TiO2/CDs polymer nanocomposites: effect of carbon dots for photocatalytic degradation of Rhodamine B

Morphology, structure and optical properties of PVA nanocomposites reinforced with bismuth oxide nanoparticles and carbon quantum dots

Turn-Off Fluorescence Sensor for the Detection of Ferric Ion in Water Using Green Synthesized Wrightia coccinea Carbon Quantum Dot

EXAMINING CARBON QUANTUM DOTS RESEARCH IN TURKEY: A SCIENTIFIC MAPPING ANALYSIS

Novel approach to enhance antifungal properties via formation of wavy and Sharp microstructures composed of metal oxide nanoparticles and Cdots