The Development of pH Modulated Solidified Homogeneous Liquid Phase Microextraction Methodology for Preconcentration and Determination of Nickel in Water Samples

Demirhan Çıtak; Rabia Demirok

doi:10.17776/csj.642319

EN

The Development of pH Modulated Solidified Homogeneous Liquid Phase Microextraction Methodology for Preconcentration and Determination of Nickel in Water Samples

Abstract

Abstract: In this work, a new, fast and green pH assisted solidified homogeneous liquid phase microextraction method (pH-MS-HLPME) was developed. Initially, the complex formation of Ni-1-Phenylthiosemicarbazide (Ni-PTC) and the dissolution of the extraction solvent (caprylic acid) in water were achieved by addition of NaOH. After base addition caprylic acid (CA) become completely soluble as sodium caprylate in model solution. The phase separation of extraction solvent was accessed by addition of HCl. The analyse of nickel concentrations was carried out by micro-sampler adapted flame atomic absorption spectrometer. Under optimized parameters, linear range (10.0-450 μg L-1), detection limit (3.2 μg L-1), limit of quantification (10.0 μg L-1), relative standard deviation (2.0 %), relative error (-3.9 %), and preconcentration factor (45) were calculated, respectively. Finally, the developed pH-MS -HLPME methodology was successfully applied to LGC 6010 hard drinking water (CRM) and some water samples.

Keywords

nickel, pH, liquid phase microextraction, drinking water samples, microsampler system

Supporting Institution

Tokat Gaziosmanpaşa Üniversitesi Bilimsel Araştırma Projeleri Birimi

Project Number

2018/41

Thanks

The authors are grateful for the financial support of the Unit of the Scientific Research Projects of Tokat Gaziosmanpaşa University (project number: 2018/41).

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Details

Primary Language

English

Subjects

-

Journal Section

Research Article

Authors

Demirhan Çıtak ^*
0000-0003-1831-3788
Türkiye

Rabia Demirok
0000-0002-7910-9222

Publication Date

December 31, 2019

Submission Date

November 4, 2019

Acceptance Date

December 19, 2019

Published in Issue

Year 2019 Volume: 40 Number: 4

DOI

https://doi.org/10.17776/csj.642319

IZ

https://izlik.org/JA68AM58KX

Cite

RIS / Bibtex

APA

Çıtak, D., & Demirok, R. (2019). The Development of pH Modulated Solidified Homogeneous Liquid Phase Microextraction Methodology for Preconcentration and Determination of Nickel in Water Samples. Cumhuriyet Science Journal, 40(4), 917-925. https://doi.org/10.17776/csj.642319

Cited By

Response surface methodology and hydrophobic deep eutectic solvent based liquid phase microextraction combination for determination of cadmium in food and water samples

Journal of Food Measurement and Characterization

https://doi.org/10.1007/s11694-020-00761-1

Öz

The Development of pH Modulated Solidified Homogeneous Liquid Phase Microextraction Methodology for Preconcentration and Determination of Nickel in Water Samples

Abstract

Keywords

Supporting Institution

Project Number

Thanks

References

Details

Primary Language

Subjects

Journal Section

Authors

Publication Date

Submission Date

Acceptance Date

Published in Issue

DOI

IZ

Cite

Cited By

Response surface methodology and hydrophobic deep eutectic solvent based liquid phase microextraction combination for determination of cadmium in food and water samples