Synthesis of new generation calix[4]arene derivatives as fluorescence chemosensor and its theoretical calculation

Hacer Azak

doi:10.17776/csj.573312

EN

Synthesis of new generation calix[4]arene derivatives as fluorescence chemosensor and its theoretical calculation

Abstract

Calixarenes are among the commonly preferred molecules of the supramolecular chemistry since they are easily synthesizable and functionalizable.In this study, new types of calix[4]aren derivatives containing benzylisoquinoline groups were synthesized and the structures of the obtaining compounds were characterized by spectroscopic techniques such as 1H-NMR, 13C-NMR. Synthesized calix[4]aren derivatives towards some metal cations (Ag+, Al+3, Ba+, Ca+2, Co+2, Cs+2, Fe+3, Hg+2, Li+, Pb+2, Mg+2, Mn+2, Na+, Cu+2, Ba+2, Ni+2, Zn+2, Sr+2 showed fluorescence behaviors ve these behaviors were investigated utilizing UV-vis spectrophotometer and fluorescence spectroscopic techniques.It was found out according to the obtained results that it got complexed in 1:1 ratio as stoichiometric as a result of its activation with aqueous solutions of Cu+2 and Fe+2 ions and responded as an off-on sensor. In this regard, a highly selective and sensitive sensor was developed. Theoretical studies were also conducted in addition to the achieved experimental results. The bonding of metal ions was also calculated theoretically by using Gaussian 09 and GaussView 5.0.8.

Keywords

calıx4arene,Fluorescence Sensor,DFT,SENSOR

Thanks

We express our sincere thanks to Assoc. Dr. Murat YILDIZ for helping to use Gaussian 09 and GaussView 5.0.8, to Karamanoglu Mehmetbey University, Faculty of Science, Department of Physics.

References

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Details

Primary Language

English

Subjects

-

Journal Section

Research Article

Authors

Hacer Azak ^*
0000-0001-6492-6572
Türkiye

Publication Date

March 22, 2020

Submission Date

June 1, 2019

Acceptance Date

October 25, 2019

Published in Issue

Year 2020 Volume: 41 Number: 1

DOI

https://doi.org/10.17776/csj.573312

IZ

https://izlik.org/JA45SA86YL

Cite

RIS / Bibtex

APA

Azak, H. (2020). Synthesis of new generation calix[4]arene derivatives as fluorescence chemosensor and its theoretical calculation. Cumhuriyet Science Journal, 41(1), 122-130. https://doi.org/10.17776/csj.573312

Cited By

A novel and cost effective isatin based Schiff base fluorophore: a highly efficient “turn-off” fluorescence sensor for the selective detection of cysteine in an aqueous medium

New Journal of Chemistry

https://doi.org/10.1039/D1NJ03087F

Öz

Synthesis of new generation calix[4]arene derivatives as fluorescence chemosensor and its theoretical calculation

Abstract

Keywords

Thanks

References

Details

Primary Language

Subjects

Journal Section

Authors

Publication Date

Submission Date

Acceptance Date

Published in Issue

DOI

IZ

Cite

Cited By

A novel and cost effective isatin based Schiff base fluorophore: a highly efficient “turn-off” fluorescence sensor for the selective detection of cysteine in an aqueous medium