Novel Fluorene and Pyrrole Comprising Copolymers: Effect of Copolymer Feed Ratio on Electrochromic and Electrochemical Properties

Şerife Özdemir Hacıoğlu

doi:10.17776/csj.541338

EN

Novel Fluorene and Pyrrole Comprising Copolymers: Effect of Copolymer Feed Ratio on Electrochromic and Electrochemical Properties

Abstract

Herein, synthesis of two homopolymers namely, poly-2,2′-(9,9-dioctyl-9h-fluorene-2,7-diyl)bisthiophene (PBT), poly-pyrrole-3-carboxylic acid (PP3CA) and fluorene and pyrrole comprising five novel copolymers (CoP1, CoP2, CoP3, CoP4, CoP5) were electrochemically synthesized. Each electrolytic solution was prepared with different monomer feed ratios to investigate the effect of comonomer ratio on electrochromic and electrochemical properties. After synthesis, homopolymers and copolymers were compared in terms of their electrochemical, spectroelectrochemical and colorimetry properties. The number of studies on electrochromic characterization of pristine P3CA group was limited in literature, hence in this study P3CA was electrochemically inserted into the polymer chain via copolymerization.CoP1 with 1:1 (BT: P3CA) monomer feed ratio exhibited the lower optical band gap and red shifted neutral state absorption compared to PP3CA, additionally light yellow color of PP3CA turned out to be multichromic for CoP1with the insertion of BT unit via electrocopolymerization.

Keywords

Fluorene,pyrrole,copolymerization

References

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Details

Primary Language

English

Subjects

-

Journal Section

Research Article

Authors

Şerife Özdemir Hacıoğlu ^*
0000-0002-7362-0740
Türkiye

Publication Date

September 30, 2019

Submission Date

March 18, 2019

Acceptance Date

August 5, 2019

Published in Issue

Year 2019 Volume: 40 Number: 3

DOI

https://doi.org/10.17776/csj.541338

IZ

https://izlik.org/JA79FX55XJ

Cite

RIS / Bibtex

APA

Özdemir Hacıoğlu, Ş. (2019). Novel Fluorene and Pyrrole Comprising Copolymers: Effect of Copolymer Feed Ratio on Electrochromic and Electrochemical Properties. Cumhuriyet Science Journal, 40(3), 723-731. https://doi.org/10.17776/csj.541338

AMA

1.Özdemir Hacıoğlu Ş. Novel Fluorene and Pyrrole Comprising Copolymers: Effect of Copolymer Feed Ratio on Electrochromic and Electrochemical Properties. CSJ. 2019;40(3):723-731. doi:10.17776/csj.541338

Chicago

Özdemir Hacıoğlu, Şerife. 2019. “Novel Fluorene and Pyrrole Comprising Copolymers: Effect of Copolymer Feed Ratio on Electrochromic and Electrochemical Properties”. Cumhuriyet Science Journal 40 (3): 723-31. https://doi.org/10.17776/csj.541338.

EndNote

Özdemir Hacıoğlu Ş (September 1, 2019) Novel Fluorene and Pyrrole Comprising Copolymers: Effect of Copolymer Feed Ratio on Electrochromic and Electrochemical Properties. Cumhuriyet Science Journal 40 3 723–731.

IEEE

[1]Ş. Özdemir Hacıoğlu, “Novel Fluorene and Pyrrole Comprising Copolymers: Effect of Copolymer Feed Ratio on Electrochromic and Electrochemical Properties”, CSJ, vol. 40, no. 3, pp. 723–731, Sept. 2019, doi: 10.17776/csj.541338.

ISNAD

Özdemir Hacıoğlu, Şerife. “Novel Fluorene and Pyrrole Comprising Copolymers: Effect of Copolymer Feed Ratio on Electrochromic and Electrochemical Properties”. Cumhuriyet Science Journal 40/3 (September 1, 2019): 723-731. https://doi.org/10.17776/csj.541338.

JAMA

1.Özdemir Hacıoğlu Ş. Novel Fluorene and Pyrrole Comprising Copolymers: Effect of Copolymer Feed Ratio on Electrochromic and Electrochemical Properties. CSJ. 2019;40:723–731.

MLA

Özdemir Hacıoğlu, Şerife. “Novel Fluorene and Pyrrole Comprising Copolymers: Effect of Copolymer Feed Ratio on Electrochromic and Electrochemical Properties”. Cumhuriyet Science Journal, vol. 40, no. 3, Sept. 2019, pp. 723-31, doi:10.17776/csj.541338.

Vancouver

1.Şerife Özdemir Hacıoğlu. Novel Fluorene and Pyrrole Comprising Copolymers: Effect of Copolymer Feed Ratio on Electrochromic and Electrochemical Properties. CSJ. 2019 Sep. 1;40(3):723-31. doi:10.17776/csj.541338