A Simple and Cheap Ultrasound-Assisted Microextraction Procedure For Extraction of Tartrazine in Soft Drinks and Foodstuff
Abstract
In this study, a simple and cheap ultrasound-assisted ionic liquid-based
floating organic droplets microextraction (UA-IL-FODME) has been proposed for
spectrophotometric determination of synthetic food dye (tartrazine) in soft
drinks and food samples. 1-Octyl-3-methylimidazolium tetrafluoroborate
[C8MIM][BF4] and 1-octanol were used as the extraction solvent and dispersant
solvent, respectively. The method is based on extracting the tarrazine to the
ionic phase with the help of ultrasonic effect at pH 5.5. Some experimental
variables (pH, ionic liquid amount, type and volume of dispersive solvent, and
ultrasonic conditions) were studied and optimized in detail. In optimum
conditions, some analytical parameters of the method were as follows. Operating
range, limit of detection, preconcentration factor, recovery % and RSD % values
were 10-700 µg L-1, 3.2 µg L-1, 75, 94.7-104.7% and 2.7%, respectively.
Following comprehensive validation studies, the recommended method was
successfully applied to the extravasation and determination of tartrazine in
soft drinks and foodstuff.
Keywords
References
- [1] Amin, K. A., Hameid, H.A. and Elsttar, A.A. Effect of food azo dyes tartrazine and carmoisine on biochemical parameters related to renal, hepatic function and oxidative stress biomarkers in young male rats. Food Chem. Toxicol., 48(10) (2010)2994-2999.
- [2] Ghoreishi, S.M., Behpour, M. and Golestaneh M. Simultaneous determination of sunset yellow and tartrazine in soft drinks using gold nanoparticles carbon paste electrode. Food chem., 132(1) (2012) 637-641.
- [3] Kucharska, M. and Grabka, J. A review of chromatographic methods for determination of synthetic food dyes. Talanta, 80(3) (2010) 1045-1051.
- [4] Soponar, F., Moţ, A.C. and Sârbu, C. Quantitative determination of some food dyes using digital processing of images obtained by thin-layer chromatography. J. Chromatogr. A, 1188(2) (2008) 295-300.
- [5] Hajimahmoodi, M., Afsharimanesh, M., Moghaddam, G., Sadeghi, N., Oveisi, M.R., Jannat, B. and Kanan, H. Determination of eight synthetic dyes in foodstuffs by green liquid chromatography. Food Additives & Contaminants: Part A, 30(5) (2013) 780-785.
- [6] El-Sheikh, A.H. and Al-Degs, Y.S. Spectrophotometric determination of food dyes in soft drinks by second order multivariate calibration of the absorbance spectra-pH data matrices. Dyes Pigm., 97(2) (2013) 330-339.
- [7] Alves, S.P., Brum, D.M., Andrade, E.C.B. and Netto, A.D.P. Determination of synthetic dyes in selected foodstuffs by high performance liquid chromatography with UV-DAD detection. Food Chem., 107(1) (2008) 489-496.
- [8] Andrade, F.I., Guedes, M.I.F., Vieira, Í.G.P., Mendes, F.N.P., Rodrigues, P.A.S., Maia, C.S.C. and Matos L. Determination of synthetic food dyes in commercial soft drinks by TLC and ion-pair HPLC. Food Chem., 157 (2014)193-198.
Details
Primary Language
English
Subjects
-
Journal Section
Research Article
Authors
Nail Altunay
*
0000-0001-9053-7570
Türkiye
Publication Date
June 30, 2019
Submission Date
December 20, 2018
Acceptance Date
February 22, 2019
Published in Issue
Year 2019 Volume: 40 Number: 2
Cited By
A novel ultrasonication-assisted deep eutectic solvent microextraction procedure for tartrazine at trace levels from environmental samples
Journal of the Iranian Chemical Society
https://doi.org/10.1007/s13738-019-01781-5Ultrasonic-assisted cloud point microextraction and spectrophotometric determination of Ponceau 4R in various beverage samples using Non-ionic surfactant PONPE 7.5
Food Additives & Contaminants: Part A
https://doi.org/10.1080/19440049.2021.1873427Synthetic Food Dyes – Some Aspects Of Use And Methods Of Determination
Methods and Objects of Chemical Analysis
https://doi.org/10.17721/moca.2020.5-20Preparation and investigation of green and cheap deep eutectic solvents for determination of essential and toxic metal ions at trace levels in different coffee products
Sustainable Chemistry and Pharmacy
https://doi.org/10.1016/j.scp.2024.101602