Electrochemical Synthesis and Characterization of ZnO Nanocomposite Copolymer Containing Fluorescent Feature Dye

Esra Kılavuz; Ersen Turaç; Ertuğrul Şahmetlioğlu

doi:10.17776/csj.442729

TR EN

Floresan Özellikli Boya İçeren ZnO Nanokompozit Kopolimerlerin Elektrokimyasal Sentezi ve Karakterizasyonu

Öz

Floresans boya sınıfından olan BODIPY’nin (Boron dipirolmetilen) bilim insanları tarafından sentezi uğraştırıcı olmasına karşın floresan, iyon / molekül ve pH probları, sensörler, redoks aktif moleküller, metal şelatörler, hücresel görüntüleme, fotodinamik tedavi, ilaç teslim malzemeleri ve fotovoltaik uygulamalar ve enerji depolama gibi çok çeşitli uygulamalarda kullanılması ilgi çekici olmuştur. Öncelikle çalışmada sentezi zor ama çekici floresans aktif monomer başarı ile sentezlenmiştir. Sonra elektrokimyasal yöntem kullanılarak yenilikçi malzeme olan bir iletken kopolimer sentezlenmiştir. Elde edilen yarı iletken malzemenin dayanım, iletkenlik özelliklerini arttırmak için Zno nanopartikülleri kullanılarak yine bir potansiyostat yardımı ile nanokompozit sentezlenmiş ve varlığı SEM-EDX, AFM-Raman gibi ileri teknolojik cihazlarla tayin edilmiştir. ZnO gibi inorganik ve nano ölçekli bileşiklerin karakteristik pikleri geleneksel FT-IR cihazında parmak izi bölgesinde ve zayıf/orta gözlenmektedir. Buda bahsedilen bileşiklerin kızılötesi spektrometre ile nitel teşhisini zorlaştırmaktadır. Buna karşın Raman spektroskopisi hem ICP-MS gibi nispeten uğraştırıcı hem de FT-IR gibi karmaşık bir spektrum bölgesi olmadığından nano parçacıkların tayininde tercih edilmiştir.

Anahtar Kelimeler

İletken polimerler,Nanokompozit,AFM-Raman

Electrochemical Synthesis and Characterization of ZnO Nanocomposite Copolymer Containing Fluorescent Feature Dye

Abstract

BODIPY (boron dipyrrolmethene) has attracted the attention of scientists although the synthesis of BODIPY from the fluorescent dye class is challenging, there are many applications such as fluorescence, ion / molecule and pH probes, sensors, redox active molecules, metal chelators, cellular imaging, photodynamic therapy, drug delivery materials and photovoltaic applications and energy storage. Firstly, it is synthesized with difficulty in synthesis but attractive fluorescence active monomer. Then, by electrochemical method, a conductive copolymer, which is an innovative material, was synthesized. The nanocomposite was synthesized with the help of a potentiostat using Zno nanoparticles to increase the strength and conductivity properties of the obtained semiconducting material and its existence was determined by advanced technological devices such as SEM-EDX, AFM-Raman. Characteristic peaks of inorganic and nano-scale compounds such as ZnO are observed in the fingerprint region and weak / medium in the conventional FT-IR device. This makes it difficult to qualitatively diagnose the compounds by infrared spectrometry. Raman spectroscopy, however, has been preferred for the determination of nanoparticles because it is relatively laborious, such as ICP-MS, and is not a complex spectral region such as FT-IR.

Keywords

Conducting Polymer,Nanocomposite,AFM-Raman

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Details

Primary Language

English

Subjects

-

Journal Section

Conference Paper

Authors

Esra Kılavuz
0000-0001-9324-5346
Türkiye

Ersen Turaç ^*
0000-0002-3543-4728
Türkiye

Ertuğrul Şahmetlioğlu
0000-0002-7324-0385
Türkiye

Publication Date

June 30, 2019

Submission Date

July 11, 2018

Acceptance Date

December 11, 2018

Published in Issue

Year 2019 Volume: 40 Number: 2

DOI

https://doi.org/10.17776/csj.442729

IZ

https://izlik.org/JA63XA87UC

Cite

RIS / Bibtex

APA

Kılavuz, E., Turaç, E., & Şahmetlioğlu, E. (2019). Electrochemical Synthesis and Characterization of ZnO Nanocomposite Copolymer Containing Fluorescent Feature Dye. Cumhuriyet Science Journal, 40(2), 433-439. https://doi.org/10.17776/csj.442729