A New Spherical Catalyst For Hydrogen Evolution Reaction

Murat Farsak

doi:10.17776/csj.406167

EN TR

A New Spherical Catalyst For Hydrogen Evolution Reaction

Abstract

CuFeZn composite catalysts have been prepared on the graphite electrode by electrochemical deposition as electrocatalytic materials for hydrogen evolution reaction (HER). The etching process was applied on catalysts in caustic solution to leach out zinc and to produce a porous electrocatalytic surface for hydrogen evolution. The surface morphologies were investigated by scanning electron microscopy. HER activity is assessed by recording cathodic current–potential curves, cyclic voltammetry, electrochemical impedance spectroscopy and electrolysis techniques. The results show that etched catalysts have a compact and porous structure as well as a good electrocatalytic activity for the HER in alkaline media.

Keywords

Hydrogen evolution,metal deposition,cathode catalyst

References

[1]. Bicer Y., Chehade G., Dincer I., Experimental investigation of various copper oxide electrodeposition conditions on photoelectrochemical hydrogen production, Int. J. Hydrogen Energy, 42 (2017) 6490-6501.
[2]. Ngamlerdpokin K., Tantavichet N., Electrodeposition of nickel–copper alloys to use as a cathode for hydrogen evolution in an alkaline media, Int. J. Hydrogen Energy, 39 (2014) 2505-2515.
[3]. Telli E., Döner A., Kardaş G., Electrocatalytic oxidation of methanol on Ru deposited NiZn catalyst at graphite in alkaline medium, Electrochim. Acta, 107 (2013) 216-224.
[4]. Parsons R., The rate of electrolytic hydrogen evolution and the heat of adsorption of hydrogen, Transactions of the Faraday Society, 54 (1958) 1053-1063.
[5]. Crnkovic F., Machado S., Avaca L., Electrochemical and morphological studies of electrodeposited Ni–Fe–Mo–Zn alloys tailored for water electrolysis, Int. J. Hydrogen Energy, 29 (2004) 249-254.
[6]. Mouanga M., Puiggali M., Devos O., EIS and LEIS investigation of aging low carbon steel with Zn–Ni coating, Electrochim. Acta, 106 (2013) 82-90.
[7]. Ortiz-Aparicio J., Meas Y., Trejo G., Ortega R., Chapman T., Chaînet E., Ozil P., Electrodeposition of zinc–cobalt alloy from a complexing alkaline glycinate bath, Electrochim. Acta, 52 (2007) 4742-4751.
[8]. Szczygieł B., Laszczyńska A., Tylus W., Influence of molybdenum on properties of Zn–Ni and Zn–Co alloy coatings, Surf. Coat. Technol., 204 (2010) 1438-1444.

[9]. Winiarski J., Tylus W., Krawczyk M., Szczygieł B., The influence of molybdenum on the electrodeposition and properties of ternary Zn–Fe–Mo alloy coatings, Electrochim. Acta, 196 (2016) 708-726.
[10]. Golvano-Escobal I., Suriñach S., Baró M.D., Pané S., Sort J., Pellicer E., Electrodeposition of sizeable and compositionally tunable rhodium-iron nanoparticles and their activity toward hydrogen evolution reaction, Electrochim. Acta, 194 (2016) 263-275.
[11]. Safizadeh F., Ghali E., Houlachi G., Electrocatalysis developments for hydrogen evolution reaction in alkaline solutions–a review, Int. J. Hydrogen Energy, 40 (2015) 256-274.
[12]. Sequeira C., Santos D., Brito P., Electrocatalytic activity of simple and modified Fe–P electrodeposits for hydrogen evolution from alkaline media, Energy, 36 (2011) 847-853.
[13]. Döner A., Solmaz R., Kardaş G., Enhancement of hydrogen evolution at cobalt–zinc deposited graphite electrode in alkaline solution, Int. J. Hydrogen Energy, 36 (2011) 7391-7397.
[14]. Döner A., Solmaz R., Kardaş G., Fabrication and characterization of alkaline leached CuZn/Cu electrode as anode material for direct methanol fuel cell, Energy, 90 (2015) 1144-1151.
[15]. Farsak M., Telli E., Yüce A.O., Kardaş G., The noble metal loading binary iron–zinc electrode for hydrogen production, Int. J. Hydrogen Energy, (2016)
[16]. Solmaz R., Döner A., Doğrubaş M., Erdoğan İ.Y., Kardaş G., Enhancement of electrochemical activity of Raney-type NiZn coatings by modifying with PtRu binary deposits: Application for alkaline water electrolysis, Int. J. Hydrogen Energy, 41 (2016) 1432-1440.
[17]. Solmaz R., Döner A., Kardaş G., Preparation, characterization and application of alkaline leached CuNiZn ternary coatings for long-term electrolysis in alkaline solution, Int. J. Hydrogen Energy, 35 (2010) 10045-10049.
[18]. Solmaz R., Kardaş G., Hydrogen evolution and corrosion performance of NiZn coatings, Energy Convers. Manage., 48 (2007) 583-591.
[19]. Solmaz R., Kardaş G., Electrochemical deposition and characterization of NiFe coatings as electrocatalytic materials for alkaline water electrolysis, Electrochim. Acta, 54 (2009) 3726-3734.
[20]. Solmaz R., Kardaş G., Fabrication and characterization of NiCoZn–M (M: Ag, Pd and Pt) electrocatalysts as cathode materials for electrochemical hydrogen production, Int. J. Hydrogen Energy, 36 (2011) 12079-12087.
[21]. Solmaz R., Salcı A., Yüksel H., Doğrubaş M., Kardaş G., Preparation and characterization of Pd-modified Raney-type NiZn coatings and their application for alkaline water electrolysis, Int. J. Hydrogen Energy, 42 (2017) 2464-2475.
[22]. Kaninski M.P.M., Nikolić V.M., Potkonjak T.N., Simonović B.R., Potkonjak N.I., Catalytic activity of Pt-based intermetallics for the hydrogen production-Influence of ionic activator, Applied Catalysis A: General, 321 (2007) 93-99.
[23]. Navarro-Flores E., Chong Z., Omanovic S., Characterization of Ni, NiMo, NiW and NiFe electroactive coatings as electrocatalysts for hydrogen evolution in an acidic medium, J. Mol. Catal. A: Chem., 226 (2005) 179-197.
[24]. Yüce A.O., Döner A., Kardaş G., NiMn composite electrodes as cathode material for hydrogen evolution reaction in alkaline solution, Int. J. Hydrogen Energy, 38 (2013) 4466-4473.

Details

Primary Language

English

Subjects

-

Journal Section

Research Article

Authors

Murat Farsak ^*

Publication Date

March 16, 2018

Submission Date

August 7, 2017

Acceptance Date

March 2, 2018

Published in Issue

Year 1970 Volume: 39 Number: 1

DOI

https://doi.org/10.17776/csj.406167

IZ

https://izlik.org/JA22GL59LG

Cite

RIS / Bibtex

APA

Farsak, M. (2018). A New Spherical Catalyst For Hydrogen Evolution Reaction. Cumhuriyet Science Journal, 39(1), 250-257. https://doi.org/10.17776/csj.406167

A New Spherical Catalyst For Hydrogen Evolution Reaction

A New Spherical Catalyst For Hydrogen Evolution Reaction

Abstract

Keywords

Hidrojen İndirgenme Reaksiyonu İçin Yeni Bir Küresel Katalizör

Öz

Anahtar Kelimeler

References

Details

Primary Language

Subjects

Journal Section

Authors

Publication Date

Submission Date

Acceptance Date

Published in Issue

DOI

IZ

Cite