Removal of Cationic Dye in Aquatic Medium by Using a New Composite Material

Zeynep Mine Hasdemir; Selçuk Şimşek

doi:10.17776/csj.356915

TR EN

Yeni Bir Kompozit Malzeme Kullanılarak Sulu Ortamdaki Katyonik Boya Giderimi

Öz

Bu çalışmada, Poliakrilamid (PAA) ve diatomit (D) içeren yeni bir kompozit materyal sentezlendi ve bir katyonik boya olan metilen mavisinin (MB) sulu ortamdaki gideriminde kullanıldı. Elde edilen yeni kompozit, pliakrilamid-diatomit (PAA-D) sıfır yük noktası (SYN), FTIR analizleriyle karakterize edildi. Yeni kompozit materyalin adsorpsiyon özellikleri kapsamlı olarak ve deneysel değişkenler derişim, pH, sıcaklık, zaman ve iyonik şiddet gibi optimize edilerek araştırılmıştır. Deneysel veriler teorik adsorpsiyon modelleri kullanılarak hesaplandı. Kompozit materyalin adsorpsiyon kapasitesi Langmiur eşitliğinden 0.019 mol kg⁻¹olarak hesaplandı. Freundlich ve DR modellerinden hesaplanan sabitler 0.075 ve 0.034 olarak bulundu. Adsorpsiyon kinetiği yalanci ikinci derece kinetik ve parçacık içi difüzyon modelleriyle de açıklandı. Deneysel çalışmalar adsorpsiyonun endotermik olduğunu ve kendiliğinden meydana geldiğini gösterdi. Yeni geliştirilen materyal çeşitli ortamlardan atık sular gibi, metilen mavisi katyonik boyasını gidermek için potansiyel bir adsorban olarak kullanılabilir.

Anahtar Kelimeler

Metilen mavisi,adsorpsiyon,poliakrilamid,diyatomit,kompozit

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Details

Primary Language

English

Subjects

-

Journal Section

Research Article

Authors

Zeynep Mine Hasdemir ^*
CUMHURİYET ÜNİVERSİTESİ
Türkiye

Selçuk Şimşek
CUMHURİYET ÜNİVERSİTESİ
Türkiye

Publication Date

March 16, 2018

Submission Date

November 22, 2017

Acceptance Date

January 15, 2018

Published in Issue

Year 1970 Volume: 39 Number: 1

DOI

https://doi.org/10.17776/csj.356915

IZ

https://izlik.org/JA26TS88EZ

Cite

RIS / Bibtex

APA

Hasdemir, Z. M., & Şimşek, S. (2018). Removal of Cationic Dye in Aquatic Medium by Using a New Composite Material. Cumhuriyet Science Journal, 39(1), 181-191. https://doi.org/10.17776/csj.356915