Synthesis, Characterization of a Schiff Base Ligand and Its metal complexes, Their Catalytic, Thermal and DNA Binding Features

Selma Bal

doi:10.17776/csj.1671518

Synthesis, Characterization of a Schiff Base Ligand and Its metal complexes, Their Catalytic, Thermal and DNA Binding Features

Abstract

This work, first of all, reports the synthesis and structural elucidation of a schiff base ligand and its Co(II), Ni(II)and Mn(II) coordination compounds using various spectroscopic methods. Then, it moves on to the search of catalytic activity features of all the metal complexes, which were tested on the oxidation reactions of styrene and cyclohexene that are known to have a crucial importance in organic synthesis. The results of these reactions showed that the metal complexes especially the Cobalt complex was the most effective as catalyst, showing %70.3 yield for styrene oxidation and %50.1 yield for cyclohexene. Synthesized compounds were also searched for their thermal behaviour and similar fragmentations were observed only for the Cobalt and Manganese complexes of the ligand. Finally DNA binding studies were carried out on all the synthesized compounds and among them the Manganese complex showed the highest binding constant (Kb ) with 7.04.

Keywords

References

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Details

Primary Language

English

Subjects

Transition Metal Chemistry , Organometallic Chemistry , Organic Chemical Synthesis

Journal Section

Research Article

Authors

Selma Bal ^*
0000-0001-9547-8717
Türkiye

Publication Date

December 30, 2025

Submission Date

July 7, 2025

Acceptance Date

November 29, 2025

Published in Issue

Year 1970 Volume: 46 Number: 4

DOI

https://doi.org/10.17776/csj.1671518

IZ

https://izlik.org/JA48MW54DT

Cite

RIS / Bibtex

APA

Bal, S. (2025). Synthesis, Characterization of a Schiff Base Ligand and Its metal complexes, Their Catalytic, Thermal and DNA Binding Features. Cumhuriyet Science Journal, 46(4), 841-853. https://doi.org/10.17776/csj.1671518