Investigation of Adsorption Isotherm Models for Interaction of P(AAm-ClAETA) and Carminic Acid, and Theoretical Approaches

Yasemin Işıkver; Ali Işıkver

doi:10.17776/csj.1268752

EN

Investigation of Adsorption Isotherm Models for Interaction of P(AAm-ClAETA) and Carminic Acid, and Theoretical Approaches

Abstract

In this study, the adsorption isotherm models for the sorption of carminic acid on P(AAm-ClAETA) hydrogels are explained by experimental and theoretical studies. The crosslinked hydrogels with ethylene glycol dimethacrylate were prepared by radical addition reaction of acrylamide (AAm) and 2-(acryloyloxy)ethyl trimethylammonium chloride (ClAETA) monomers in an aqueous solution. The spectral and morphological analyses of P(AAm-ClAETA) hydrogels were performed by FTIR/ATR and SEM, respectively. The adsorbed amounts of carminic acid on P(AAm-ClAETA) hydrogels were evaluated by Giles, Langmuir, and Freundlich adsorption isotherm models. Langmuir parameters were calculated for the adsorption of the dye on the hydrogels according to the L-type Giles isotherm. In addition, it was determined that its adsorption was appropriate from the RL values calculated for 500 mg L-1 carminic acid concentration. In addition, molecular electrostatic potential (MEP) mapping was performed to predict the reactive sites of P(AAm-ClAETA) hydrogels and carminic acid. The results showed that the theoretical and experimental data of the hydrogels were in agreement with each other. As a result, it can be said that P(AAm-ClAETA) hydrogels are suitable for the removal of anionic dyes such as carminic acid from aqueous solutions.

Keywords

Supporting Institution

Yok

Project Number

Yok

Thanks

We thank Assoc. Prof. Nihat Karakuş for his help in the calculation of MEP maps.

References

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Details

Primary Language

English

Subjects

Polymer Science and Technologies

Journal Section

Research Article

Authors

Yasemin Işıkver ^*
0000-0001-6481-188X
Türkiye

Ali Işıkver
0000-0003-3871-9435
Türkiye

Publication Date

September 29, 2023

Submission Date

March 21, 2023

Acceptance Date

August 22, 2023

Published in Issue

Year 2023 Volume: 44 Number: 3

DOI

https://doi.org/10.17776/csj.1268752

IZ

https://izlik.org/JA53GM94HH

Cite

RIS / Bibtex

APA

Işıkver, Y., & Işıkver, A. (2023). Investigation of Adsorption Isotherm Models for Interaction of P(AAm-ClAETA) and Carminic Acid, and Theoretical Approaches. Cumhuriyet Science Journal, 44(3), 510-515. https://doi.org/10.17776/csj.1268752

Öz

Investigation of Adsorption Isotherm Models for Interaction of P(AAm-ClAETA) and Carminic Acid, and Theoretical Approaches

Abstract

Keywords

Supporting Institution

Project Number

Thanks

References

Details

Primary Language

Subjects

Journal Section

Authors

Publication Date

Submission Date

Acceptance Date

Published in Issue

DOI

IZ

Cite