A New Nickel(II) Complex Derived From Bisthiocarbohydrazone: Synthesis, Characterization, Crystal Structure and Antioxidant Activity

Yeliz Kaya

doi:10.17776/csj.1248428

EN

A New Nickel(II) Complex Derived From Bisthiocarbohydrazone: Synthesis, Characterization, Crystal Structure and Antioxidant Activity

Abstract

A new complex with composition [Ni(L)(PPh3)] (PPh3 = triphenylphosphine) was obtained from the reaction of 1,5-bis(salicylidene)thiocarbohydrazone (L) with an equimolar amount of [NiCl2(PPh3)2]. The complex was identified by FT-IR, 1H NMR and UV-Vis spectroscopic methods and elemental analysis. The solid state structure of [Ni(L)(PPh3)] was established by X-ray diffraction analysis. It was determined that the complex, whose nickel center has a distorted square planar configuration, crystallizes in the monoclinic space group I2/c. Bisthiocarbohydrazone (L) binds to the nickel center through its phenolate O, azomethine N and thioenolate S atoms in a dianionic tridentate mode. The antioxidant capacity of L and Ni(II) complex was examined using the CUPRAC (cupric reducing antioxidant capacity) method. Also, the DPPH (1,1-Diphenyl-2-picrylhydrazyl) method was used to test free radical scavenging activity of the compounds. Antioxidant activity results showed that L exhibited better activity than Ni(II) complex.

Keywords

References

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Details

Primary Language

English

Subjects

Metabolomic Chemistry

Journal Section

Research Article

Authors

Yeliz Kaya ^*
0000-0001-5606-8088
Türkiye

Publication Date

September 29, 2023

Submission Date

February 6, 2023

Acceptance Date

August 22, 2023

Published in Issue

Year 2023 Volume: 44 Number: 3

DOI

https://doi.org/10.17776/csj.1248428

IZ

https://izlik.org/JA54FG85ML

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RIS / Bibtex

APA

Kaya, Y. (2023). A New Nickel(II) Complex Derived From Bisthiocarbohydrazone: Synthesis, Characterization, Crystal Structure and Antioxidant Activity. Cumhuriyet Science Journal, 44(3), 450-455. https://doi.org/10.17776/csj.1248428

A New Nickel(II) Complex Derived From Bisthiocarbohydrazone: Synthesis, Characterization, Crystal Structure and Antioxidant Activity

Abstract

Keywords

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Anahtar Kelimeler

References

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