Reclaim of Wrecked Bi-Te Based Materials In Peltier Modules In Thermopower Properties By Mechanical Milling

Mehmet Çetin; Gizem Durak Yüzüak; Ercüment Yüzüak

doi:10.17776/csj.1184107

EN

Reclaim of Wrecked Bi-Te Based Materials In Peltier Modules In Thermopower Properties By Mechanical Milling

Abstract

We thoroughly evaluated the effects of various treatments on the structural and electrical properties of the two as-cast materials, “Sb-doping Bi-Te (p-type)” and “Se-doping Bi-Te (n-type)” which are frequently present in abandoned Peltier modules. To investigate the thermoelectric properties of Bi2Te3-based materials, waste alloys characterized by electrical conductivity using the hot-end method. Alloys were purified by performing arc melting on a water-cooled copper crucible in a vacuum of at least 10-3 mbar, with five times melting sessions to assure homogeneity. A single and long milling period of 144 hours is applied. After the compressing operation, the resulting discs with nanostructures were annealed for an hour at 600 K under vacuum conditions. The discs' structural properties were characterized using X-ray diffraction (XRD) and their surfaces and stoichiometries were determined using scanning electron microscopy with an energy dispersive feature. The Seebeck coefficient of the nanoparticle formed n-type Bi-Te based sample is -35.3 µV.K-1 and p-type Bi-Te based sample is 100 µV.K-1 (15% of mean error margin). It was found that a notable improvement was attained in comparison to the initial state with the addition of nanoparticles.We thoroughly evaluated the effects of various treatments on the structural and electrical properties of the two as-cast materials, “Sb-doping Bi-Te (p-type)” and “Se-doping Bi-Te (n-type)”, which are frequently present in abandoned Peltier modules. To investigate the thermoelectric properties of Bi2Te3-based materials, waste alloys were produced and separated by electrical conductivity using the hot-end method. The alloys were purified by performing arc melting on a water-cooled copper crucible in a vacuum of at least 10-3 mbar, with 5 times melting sessions to assure homogeneity. A ball-milled procedure was used to reduce the obtained mass-scale materials to nano sizes. Single and long milling period of 144 hours is applied. After the compressing operation, the resulting discs with nano-structures were annealed for an hour at 600 K in a vacuum. X-ray diffraction was used to characterize the discs' structures, while scanning electron microscopy and energy dispersive X-ray spectroscopy were used to examine the discs' surfaces and determine their morphologies. Based on thermal imaging camera scans and Si-diode, we know that the Seebeck coefficient of the nanoparticle formed n-type Bi-Te based sample is -35.37 V.K-1, while that of the nanoparticle formed p-type Bi-Te based sample is 100.05 V.K-1 (15% of mean error margin). It was found that a notable improvement was attained in comparison to the initial state with the addition of nanoparticles.

Keywords

Project Number

Scientific and Technological Research Council of Turkey-TÜBİTAK, 2209-A Research Project Support Program for Undergraduate Students

Thanks

The authors would like to thank Sedanur Baltacı and Gaye Dülger for their helpful contribution.

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Details

Primary Language

English

Subjects

Classical Physics (Other)

Journal Section

Research Article

Authors

Mehmet Çetin
0000-0001-6422-4634
Türkiye

Gizem Durak Yüzüak
0000-0002-2358-8789
Türkiye

Ercüment Yüzüak ^*
0000-0002-2521-9362
Türkiye

Publication Date

March 26, 2023

Submission Date

October 4, 2022

Acceptance Date

February 26, 2023

Published in Issue

Year 2023 Volume: 44 Number: 1

DOI

https://doi.org/10.17776/csj.1184107

IZ

https://izlik.org/JA43DN58LU

Cite

RIS / Bibtex

APA

Çetin, M., Durak Yüzüak, G., & Yüzüak, E. (2023). Reclaim of Wrecked Bi-Te Based Materials In Peltier Modules In Thermopower Properties By Mechanical Milling. Cumhuriyet Science Journal, 44(1), 209-217. https://doi.org/10.17776/csj.1184107

AMA

1.Çetin M, Durak Yüzüak G, Yüzüak E. Reclaim of Wrecked Bi-Te Based Materials In Peltier Modules In Thermopower Properties By Mechanical Milling. CSJ. 2023;44(1):209-217. doi:10.17776/csj.1184107

Chicago

Çetin, Mehmet, Gizem Durak Yüzüak, and Ercüment Yüzüak. 2023. “Reclaim of Wrecked Bi-Te Based Materials In Peltier Modules In Thermopower Properties By Mechanical Milling”. Cumhuriyet Science Journal 44 (1): 209-17. https://doi.org/10.17776/csj.1184107.

EndNote

Çetin M, Durak Yüzüak G, Yüzüak E (March 1, 2023) Reclaim of Wrecked Bi-Te Based Materials In Peltier Modules In Thermopower Properties By Mechanical Milling. Cumhuriyet Science Journal 44 1 209–217.

IEEE

[1]M. Çetin, G. Durak Yüzüak, and E. Yüzüak, “Reclaim of Wrecked Bi-Te Based Materials In Peltier Modules In Thermopower Properties By Mechanical Milling”, CSJ, vol. 44, no. 1, pp. 209–217, Mar. 2023, doi: 10.17776/csj.1184107.

ISNAD

Çetin, Mehmet - Durak Yüzüak, Gizem - Yüzüak, Ercüment. “Reclaim of Wrecked Bi-Te Based Materials In Peltier Modules In Thermopower Properties By Mechanical Milling”. Cumhuriyet Science Journal 44/1 (March 1, 2023): 209-217. https://doi.org/10.17776/csj.1184107.

JAMA

1.Çetin M, Durak Yüzüak G, Yüzüak E. Reclaim of Wrecked Bi-Te Based Materials In Peltier Modules In Thermopower Properties By Mechanical Milling. CSJ. 2023;44:209–217.

MLA

Çetin, Mehmet, et al. “Reclaim of Wrecked Bi-Te Based Materials In Peltier Modules In Thermopower Properties By Mechanical Milling”. Cumhuriyet Science Journal, vol. 44, no. 1, Mar. 2023, pp. 209-17, doi:10.17776/csj.1184107.

Vancouver

1.Mehmet Çetin, Gizem Durak Yüzüak, Ercüment Yüzüak. Reclaim of Wrecked Bi-Te Based Materials In Peltier Modules In Thermopower Properties By Mechanical Milling. CSJ. 2023 Mar. 1;44(1):209-17. doi:10.17776/csj.1184107