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Thermal Degradation Kinetics of Modified Fe3O4 With Poly(Vinyl Chloride) via Click Chemistry

Yıl 2023, Cilt: 10 Sayı: 4, 919 - 928, 11.11.2023

Abdulrahman Tukur Mustafa Ersin Pekdemir Abdullahi Musa Abubakar

Öz

The three derivatives poly(POHMAC-co-VTM)-g-Fe3O4, poly(POHMAC-co-VTM)-g-Fe3O4 and PVC-g-poly(POHMAC-co-VTM)-g-Fe3O4 were characterized based on thermal properties. The thermal properties like initial decomposition and final decomposition temperatures and temperature at the maximum rate of decomposition were studied by thermogravimetry (TG) and differential thermal gravimetry (DTG) and the decomposition steps were investigated. Then, the thermal characteristics of the final product formed via click chemistry, PVC-g-poly(POHMAC-co-VTM)-g-Fe3O4 were evaluated through thermogravimetry analysis (TGA) under argon atmosphere at 5, 10, and 15 oC/min. The temperature range studied is 0 to 800oC. Based on the iso-conversional method, the thermal degradation kinetic parameter of the activation energy was calculated by the free model methods of the Flynn-Wall-Ozawa method (FWO) and Kissinger-Akahira-Sinuse method (KAS). The predicted activation energy values ranged from 41.40 to 117.83 KJmol-1 meanwhile the average activation energy values were calculated as 85.75 KJmol-1 and 72.31 KJmol-1 respectively for FWO and KAS methods. In addition, the saturation magnetization value of 33.7 emu/g was recorded using the vibration sample magnetometry (VSM).

Anahtar Kelimeler

PVC Fe3O4 thermal degradation kinetics click chemistry

Kaynakça

  • 1. Charles J, Ramkumaar GR, Azhagiri S, Gunasekaran S. FTIR and Thermal Studies on Nylon-66 and 30% Glass Fibre Reinforced Nylon-66. E-Journal Chem [Internet]. 2009;6(1):23–33. Available from: <URL>.
  • 2. Stepto RFT, Work WJ. International Union of Pure and Applied Chemistry Commission on Macromolecular Nomenclature (IV. 1). Polym news. 1998;23(5).
  • 3. Ehrenstein GW, Riedel G, Trawiel P. Thermal analysis of plastics: theory and practice. Carl Hanser Verlag GmbH Co KG; 2012.
  • 4. Chrissafis K, Bikiaris D. Can nanoparticles really enhance thermal stability of polymers? Part I: An overview on thermal decomposition of addition polymers. Thermochim Acta [Internet]. 2011 Aug 20;523(1–2):1–24. Available from: <URL>.
  • 5. Hurley MJ, Gottuk D, Hall JR, Harada K, Kuligowski E, Puchovsky M, et al., editors. SFPE Handbook of Fire Protection Engineering [Internet]. New York, NY: Springer New York; 2016. Available from: <URL>.
  • 6. Król-Morkisz K, Pielichowska K. Thermal Decomposition of Polymer Nanocomposites With Functionalized Nanoparticles. In: Polymer Composites with Functionalized Nanoparticles [Internet]. Elsevier; 2019. p. 405–35. Available from: <URL>.
  • 7. Mano JF, Koniarova D, Reis RL. Thermal properties of thermoplastic starch/synthetic polymer blends with potential biomedical applicability. J Mater Sci Mater Med [Internet]. 2003 Feb 1;14(2):127–35. Available from: <URL>.
  • 8. Wang H, Tao X, Newton E. Thermal degradation kinetics and lifetime prediction of a luminescent conducting polymer. Polym Int [Internet]. 2004 Jan 1;53(1):20–6. Available from: <URL>.
  • 9. Chang TC, Yang CW, Wu KH, Wu TR, Chiu YS. Organic–inorganic hybrid materials3 Characterization and degradation of poly(imide–silica) hybrids doped with LiCF3SO3. Polym Degrad Stab [Internet]. 2000 Apr;68(1):103–9. Available from: <URL>.
  • 10. Chaudhary RG, Juneja HD, Gandhare N V. Evaluation of kinetic parameters from TG/DTG data of chelate polymer compounds of isophthaoyl bis (paramethoxyphenylcarbamide). J Chinese Adv Mater Soc [Internet]. 2013 Dec;1(4):305–16. Available from: <URL>.
  • 11. Carvalho CT, Caires FJ, Lima LS, Ionashiro M. Thermal investigation of solid 2-methoxycinnamylidenepyruvate of some bivalent transition metal ions. J Therm Anal Calorim [Internet]. 2012 Mar 3;107(3):863–8. Available from: <URL>.
  • 12. Sekerci M, Yakuphanoglu F. Thermal analysis study of some transition metal complexes by TG and DSC methods. J Therm Anal Calorim [Internet]. 2004 Nov 2;75(1):189–95. Available from: <URL>.
  • 13. Chaudhary RG, Juneja HD, Gharpure MP. Thermal degradation behaviour of some metal chelate polymer compounds with bis(bidentate) ligand by TG/DTG/DTA. J Therm Anal Calorim [Internet]. 2013 May 21;112(2):637–47. Available from: <URL>.
  • 14. Padole Gaikwad GS, Juneja HD. Synthesis, thermal degradation, and kinetic parameters studies of some coordination polymers. J Therm Anal Calorim [Internet]. 2010 May 31;100(2):645–50. Available from: <URL>.
  • 15. Xu Z, Kolapkar SS, Zinchik S, Bar-Ziv E, McDonald AG. Comprehensive kinetic study of thermal degradation of polyvinylchloride (PVC). Polym Degrad Stab. 2020 Jun;176:109148. Available from: <URL>.
  • 16. Ephraim A, Pozzobon V, Lebonnois D, Peregrina C, Sharrock P, Nzihou A, et al. Pyrolysis of wood and PVC mixtures: thermal behaviour and kinetic modelling. Biomass Convers Biorefinery [Internet]. 2023 Jul 13;13(10):8669–83. Available from: <URL>.
  • 17. Wang Z, Xie T, Ning X, Liu Y, Wang J. Thermal degradation kinetics study of polyvinyl chloride (PVC) sheath for new and aged cables. Waste Manag [Internet]. 2019 Nov 1;99:146–53. Available from: <URL>.
  • 18. Zhou R, Huang B, Ding Y, Li W, Mu J. Thermal Decomposition Mechanism and Kinetics Study of Plastic Waste Chlorinated Polyvinyl Chloride. Polymers (Basel) [Internet]. 2019 Dec 12;11(12):2080. Available from: <URL>.
  • 19. Altarawneh S, Al-Harahsheh M, Dodds C, Buttress A, Kingman S. Thermal degradation kinetics of polyvinyl chloride in presence of zinc oxide. Thermochim Acta [Internet]. 2022 Jan 1;707:179105. Available from: <URL>.
  • 20. Ghaebi Mehmandoust S, Alizadeh R, Babaluo AA. Kinetic study of the poly(vinyl chloride)/titanium dioxide nanocomposites photodegradation under accelerated ultraviolet and visible light exposure. Polym Adv Technol [Internet]. 2014 Aug 1;25(8):799–808. Available from: <URL>.
  • 21. Shi Z, Wang Y, Xiao T, Dong S, Lan T. Preparation and Thermal Decomposition Kinetics of a New Type of a Magnetic Targeting Drug Carrier. ACS Omega [Internet]. 2021 Feb 2;6(4):3427–33. Available from: <URL>.
  • 22. AlFannakh H. Nonisothermal Kinetic Analysis and AC Conductivity for Polyvinyl Chloride (PVC)/Zinc Oxide (ZnO) Nanocomposite. Adv Polym Technol [Internet]. 2020 Aug 17;2020:1233401. Available from: <URL>.
  • 23. Pekdemir ME, Tukur A, Coskun M. Thermal and dielectric investigation of magnetic nanoparticles functionalized with PVC via click chemistry. Polym Bull [Internet]. 2021 Oct 17;78(10):6047–57. Available from: <URL>.
  • 24. Šimon P. Isoconversional methods. J Therm Anal Calorim [Internet]. 2004;76(1):123–32. Available from: <URL>.
  • 25. Manikandan G, Jayabharathi J, Rajarajan G, Thanikachalam V. Kinetics and vaporization of anil in nitrogen atmosphere – Non-isothermal condition. J King Saud Univ - Sci [Internet]. 2012 Jul 1;24(3):265–70. Available from: <URL>.
  • 26. Li H, Niu S, Lu C. Thermal Characteristics and Kinetic Calculation of Castor Oil Pyrolysis. Procedia Eng [Internet]. 2017 Jan 1;205:3711–6. Available from: <URL>.
  • 27. Gundogar AS, Kok M V. Thermal characterization, combustion and kinetics of different origin crude oils. Fuel [Internet]. 2014 May 1;123:59–65. Available from: <URL>.
  • 28. Lim ACR, Chin BLF, Jawad ZA, Hii KL. Kinetic Analysis of Rice Husk Pyrolysis Using Kissinger-Akahira-Sunose (KAS) Method. Procedia Eng [Internet]. 2016 Jan 1;148:1247–51. Available from: <URL>.
  • 29. Biryan F, Demirelli K. Thermal decomposition, kinetics and electrical measurements of Poly(3-Acetamidopropyl Methacrylate)/graphite composites. Ferroelectrics [Internet]. 2019 Oct 3;550(1):51–75. Available from: <URL>.
  • 30. Flynn JH, Wall LA. General treatment of the thermogravimetry of polymers. J Res Natl Bur Stand Sect A Phys Chem [Internet]. 1966 Nov;70A(6):487. Available from: <URL>.
  • 31. Ozawa TB. Chemical Society [MI. Japan. 1965;38:1881.
  • 32. Doyle CD. Estimating isothermal life from thermogravimetric data. J Appl Polym Sci [Internet]. 1962 Nov 1;6(24):639–42. Available from: <URL>.
  • 33. Foner S. Versatile and Sensitive Vibrating-Sample Magnetometer. Rev Sci Instrum [Internet]. 1959 Jul 1;30(7):548–57. Available from: <URL>.
  • 34. Long Y, Chen Z, Duvail JL, Zhang Z, Wan M. Electrical and magnetic properties of polyaniline/Fe3O4 nanostructures. Phys B Condens Matter [Internet]. 2005 Dec 15;370(1–4):121–30. Available from: <URL>.
  • 35. Hu P, Kang L, Chang T, Yang F, Wang H, Zhang Y, et al. High saturation magnetization Fe3O4 nanoparticles prepared by one-step reduction method in autoclave. J Alloys Compd [Internet]. 2017 Dec 25;728:88–92. Available from: <URL>.
  • 36. Tukur A, Pekdemir ME, Haruna H, Coşkun M. Magnetic nanoparticle bonding to PVC with the help of click reaction: characterization, thermal and electrical investigation. J Polym Res [Internet]. 2020 Jun 18;27(6):161. Available from: <URL>.

Yıl 2023, Cilt: 10 Sayı: 4, 919 - 928, 11.11.2023

Abdulrahman Tukur Mustafa Ersin Pekdemir Abdullahi Musa Abubakar

Öz

Anahtar Kelimeler

PVC Fe3O4 thermal degradation kinetics click chemistry

Kaynakça

  • 1. Charles J, Ramkumaar GR, Azhagiri S, Gunasekaran S. FTIR and Thermal Studies on Nylon-66 and 30% Glass Fibre Reinforced Nylon-66. E-Journal Chem [Internet]. 2009;6(1):23–33. Available from: <URL>.
  • 2. Stepto RFT, Work WJ. International Union of Pure and Applied Chemistry Commission on Macromolecular Nomenclature (IV. 1). Polym news. 1998;23(5).
  • 3. Ehrenstein GW, Riedel G, Trawiel P. Thermal analysis of plastics: theory and practice. Carl Hanser Verlag GmbH Co KG; 2012.
  • 4. Chrissafis K, Bikiaris D. Can nanoparticles really enhance thermal stability of polymers? Part I: An overview on thermal decomposition of addition polymers. Thermochim Acta [Internet]. 2011 Aug 20;523(1–2):1–24. Available from: <URL>.
  • 5. Hurley MJ, Gottuk D, Hall JR, Harada K, Kuligowski E, Puchovsky M, et al., editors. SFPE Handbook of Fire Protection Engineering [Internet]. New York, NY: Springer New York; 2016. Available from: <URL>.
  • 6. Król-Morkisz K, Pielichowska K. Thermal Decomposition of Polymer Nanocomposites With Functionalized Nanoparticles. In: Polymer Composites with Functionalized Nanoparticles [Internet]. Elsevier; 2019. p. 405–35. Available from: <URL>.
  • 7. Mano JF, Koniarova D, Reis RL. Thermal properties of thermoplastic starch/synthetic polymer blends with potential biomedical applicability. J Mater Sci Mater Med [Internet]. 2003 Feb 1;14(2):127–35. Available from: <URL>.
  • 8. Wang H, Tao X, Newton E. Thermal degradation kinetics and lifetime prediction of a luminescent conducting polymer. Polym Int [Internet]. 2004 Jan 1;53(1):20–6. Available from: <URL>.
  • 9. Chang TC, Yang CW, Wu KH, Wu TR, Chiu YS. Organic–inorganic hybrid materials3 Characterization and degradation of poly(imide–silica) hybrids doped with LiCF3SO3. Polym Degrad Stab [Internet]. 2000 Apr;68(1):103–9. Available from: <URL>.
  • 10. Chaudhary RG, Juneja HD, Gandhare N V. Evaluation of kinetic parameters from TG/DTG data of chelate polymer compounds of isophthaoyl bis (paramethoxyphenylcarbamide). J Chinese Adv Mater Soc [Internet]. 2013 Dec;1(4):305–16. Available from: <URL>.
  • 11. Carvalho CT, Caires FJ, Lima LS, Ionashiro M. Thermal investigation of solid 2-methoxycinnamylidenepyruvate of some bivalent transition metal ions. J Therm Anal Calorim [Internet]. 2012 Mar 3;107(3):863–8. Available from: <URL>.
  • 12. Sekerci M, Yakuphanoglu F. Thermal analysis study of some transition metal complexes by TG and DSC methods. J Therm Anal Calorim [Internet]. 2004 Nov 2;75(1):189–95. Available from: <URL>.
  • 13. Chaudhary RG, Juneja HD, Gharpure MP. Thermal degradation behaviour of some metal chelate polymer compounds with bis(bidentate) ligand by TG/DTG/DTA. J Therm Anal Calorim [Internet]. 2013 May 21;112(2):637–47. Available from: <URL>.
  • 14. Padole Gaikwad GS, Juneja HD. Synthesis, thermal degradation, and kinetic parameters studies of some coordination polymers. J Therm Anal Calorim [Internet]. 2010 May 31;100(2):645–50. Available from: <URL>.
  • 15. Xu Z, Kolapkar SS, Zinchik S, Bar-Ziv E, McDonald AG. Comprehensive kinetic study of thermal degradation of polyvinylchloride (PVC). Polym Degrad Stab. 2020 Jun;176:109148. Available from: <URL>.
  • 16. Ephraim A, Pozzobon V, Lebonnois D, Peregrina C, Sharrock P, Nzihou A, et al. Pyrolysis of wood and PVC mixtures: thermal behaviour and kinetic modelling. Biomass Convers Biorefinery [Internet]. 2023 Jul 13;13(10):8669–83. Available from: <URL>.
  • 17. Wang Z, Xie T, Ning X, Liu Y, Wang J. Thermal degradation kinetics study of polyvinyl chloride (PVC) sheath for new and aged cables. Waste Manag [Internet]. 2019 Nov 1;99:146–53. Available from: <URL>.
  • 18. Zhou R, Huang B, Ding Y, Li W, Mu J. Thermal Decomposition Mechanism and Kinetics Study of Plastic Waste Chlorinated Polyvinyl Chloride. Polymers (Basel) [Internet]. 2019 Dec 12;11(12):2080. Available from: <URL>.
  • 19. Altarawneh S, Al-Harahsheh M, Dodds C, Buttress A, Kingman S. Thermal degradation kinetics of polyvinyl chloride in presence of zinc oxide. Thermochim Acta [Internet]. 2022 Jan 1;707:179105. Available from: <URL>.
  • 20. Ghaebi Mehmandoust S, Alizadeh R, Babaluo AA. Kinetic study of the poly(vinyl chloride)/titanium dioxide nanocomposites photodegradation under accelerated ultraviolet and visible light exposure. Polym Adv Technol [Internet]. 2014 Aug 1;25(8):799–808. Available from: <URL>.
  • 21. Shi Z, Wang Y, Xiao T, Dong S, Lan T. Preparation and Thermal Decomposition Kinetics of a New Type of a Magnetic Targeting Drug Carrier. ACS Omega [Internet]. 2021 Feb 2;6(4):3427–33. Available from: <URL>.
  • 22. AlFannakh H. Nonisothermal Kinetic Analysis and AC Conductivity for Polyvinyl Chloride (PVC)/Zinc Oxide (ZnO) Nanocomposite. Adv Polym Technol [Internet]. 2020 Aug 17;2020:1233401. Available from: <URL>.
  • 23. Pekdemir ME, Tukur A, Coskun M. Thermal and dielectric investigation of magnetic nanoparticles functionalized with PVC via click chemistry. Polym Bull [Internet]. 2021 Oct 17;78(10):6047–57. Available from: <URL>.
  • 24. Šimon P. Isoconversional methods. J Therm Anal Calorim [Internet]. 2004;76(1):123–32. Available from: <URL>.
  • 25. Manikandan G, Jayabharathi J, Rajarajan G, Thanikachalam V. Kinetics and vaporization of anil in nitrogen atmosphere – Non-isothermal condition. J King Saud Univ - Sci [Internet]. 2012 Jul 1;24(3):265–70. Available from: <URL>.
  • 26. Li H, Niu S, Lu C. Thermal Characteristics and Kinetic Calculation of Castor Oil Pyrolysis. Procedia Eng [Internet]. 2017 Jan 1;205:3711–6. Available from: <URL>.
  • 27. Gundogar AS, Kok M V. Thermal characterization, combustion and kinetics of different origin crude oils. Fuel [Internet]. 2014 May 1;123:59–65. Available from: <URL>.
  • 28. Lim ACR, Chin BLF, Jawad ZA, Hii KL. Kinetic Analysis of Rice Husk Pyrolysis Using Kissinger-Akahira-Sunose (KAS) Method. Procedia Eng [Internet]. 2016 Jan 1;148:1247–51. Available from: <URL>.
  • 29. Biryan F, Demirelli K. Thermal decomposition, kinetics and electrical measurements of Poly(3-Acetamidopropyl Methacrylate)/graphite composites. Ferroelectrics [Internet]. 2019 Oct 3;550(1):51–75. Available from: <URL>.
  • 30. Flynn JH, Wall LA. General treatment of the thermogravimetry of polymers. J Res Natl Bur Stand Sect A Phys Chem [Internet]. 1966 Nov;70A(6):487. Available from: <URL>.
  • 31. Ozawa TB. Chemical Society [MI. Japan. 1965;38:1881.
  • 32. Doyle CD. Estimating isothermal life from thermogravimetric data. J Appl Polym Sci [Internet]. 1962 Nov 1;6(24):639–42. Available from: <URL>.
  • 33. Foner S. Versatile and Sensitive Vibrating-Sample Magnetometer. Rev Sci Instrum [Internet]. 1959 Jul 1;30(7):548–57. Available from: <URL>.
  • 34. Long Y, Chen Z, Duvail JL, Zhang Z, Wan M. Electrical and magnetic properties of polyaniline/Fe3O4 nanostructures. Phys B Condens Matter [Internet]. 2005 Dec 15;370(1–4):121–30. Available from: <URL>.
  • 35. Hu P, Kang L, Chang T, Yang F, Wang H, Zhang Y, et al. High saturation magnetization Fe3O4 nanoparticles prepared by one-step reduction method in autoclave. J Alloys Compd [Internet]. 2017 Dec 25;728:88–92. Available from: <URL>.
  • 36. Tukur A, Pekdemir ME, Haruna H, Coşkun M. Magnetic nanoparticle bonding to PVC with the help of click reaction: characterization, thermal and electrical investigation. J Polym Res [Internet]. 2020 Jun 18;27(6):161. Available from: <URL>.
Toplam 36 adet kaynakça vardır.

Ayrıntılar

Birincil Dil İngilizce
Konular Fiziksel Kimya
Bölüm ARAŞTIRMA MAKALELERİ
Yazarlar

Abdulrahman Tukur 0000-0002-6910-8533

Mustafa Ersin Pekdemir 0000-0002-4979-1777

Abdullahi Musa Abubakar 0000-0002-9323-1953

Yayımlanma Tarihi 11 Kasım 2023
Gönderilme Tarihi 25 Ocak 2023
Kabul Tarihi 14 Temmuz 2023
Yayımlandığı Sayı Yıl 2023 Cilt: 10 Sayı: 4

Kaynak Göster

Vancouver Tukur A, Pekdemir ME, Abubakar AM. Thermal Degradation Kinetics of Modified Fe3O4 With Poly(Vinyl Chloride) via Click Chemistry. JOTCSA. 2023;10(4):919-28.
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