Cumhuriyet Science Journal
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Blending Effect of Maleic Anhydride-Styrene-Methyl Methacrylate Terpolymer on Polyvinylchloride (Pvc)/Polystyrene (Ps) Mixtures

Yıl 2022, Cilt 43, Sayı 1, 61 - 65, 30.03.2022

Ersen YILMAZ

https://doi.org/10.17776/csj.1012540

Öz

The blending effect of poly maleic anhydride-styrene-methyl methacrylate (MA-St-MMA) terpolymer on non-miscible PVC and Polystyrene was studied depending on their thermomechanical properties. Depending on the amount of the synthesized and used compatibilizer the tensile strength, modulus, and thermomechanical properties of the blends are enhanced. The unmodified and blends with small amounts of compatibilizer exhibit two-step degradation whereas those containing 6, 8 and 10 percent compatibilizer showed a single glass transition (Tg). All the results reveal that PS/PVC mixtures modified with MA-St-MMA have superior mechanical properties and phase adhesions than mixtures without terpolymer.

Anahtar Kelimeler

Polymer blend, Compatilization, Maleic anhydride, Poly vinylchloride, Polystyrene, Terpolymer

Kaynakça

  • [1] Imren D., Boztug A., Yilmaz E., Zengin H.B., Viscometric investigation of compatibilization of the poly(vinyl chloride)/poly(ethylene-co-vinyl acetate) blends by terpolymer of maleic anhydride-styrene-vinyl acetate, Journal of Molecular Structure, 891 (2008) 329-332.
  • [2] Boztug A., Yilmaz E., Effects of reactive terpolymer containing maleic anhydride on thermomechanical properties of poly(vinyl chloride) based multicomponent blends, Materials Research Innovations, 11(3) (2007) 158-160.
  • [3] Imren D., Compatibilization of immiscible poly(vinyl chloride) (PVC)/polystyrene (PS) blends with maleic anhydride-styrene-vinyl acetate terpolymer (MAStVA), Journal of Molecular Structure , 963 (2010) 245-249.
  • [4] Bolayir G., Soygun K., Simsek S, Yilmaz E., Dogan A., Boztug A., Dogan O.M., Effects of the Different Methacrylate Monomers on Bond Strength Between Soft Liner and Acrylic Resin, Asian Journal of Chemistry, 25(14) (2013) 8079-80819
  • [5] Boztuğ A., Zengin H.B., Basan S., Thermomechanical and thermogravimetric analysis of blends of poly (vinyl chloride)(PVC) with maleic anhydride–allyl propionate copolymer, Journal of Molecular Structure, 697 (1-3) (2004) 61-64.
  • [6] Boztug A., Preparation and thermomechanical characterization of poly (vinyl chloride) blends compatible with terpolymer‐containing maleic anhydride, J. Appl. Polym. Sci., 94 (2004) 1586–1589.
  • [7] Aksit A., Menzel T., Aksit M., Altstädt V., Properties of Styrene-Maleic Anhydride Copolymer Compatibilized Polyamide 66/Poly (Phenylene Ether) Blends: Effect of Maleic Anhydride Concentration and Copolymer Content. Materials (Basel, Switzerland), 13(5) (2020) 1237.
  • [8] Dharmarajan N., Datta S., Ver Strate G., Ban L., Compatibilized polymer blends of isotactic polypropylene and styrene—maleic anhydride copolymer, Polymer, 36(20) (1995) 3849-3861.
  • [9] Boztug A., Basan S., The modification and characterization of maleic anhydride-styrene-methyl metacrylate terpolymer by poly(ethylene adipate), J. Mol. Struct., 830 (2007) 126-130.
  • [10] Pork J.W., Lm S.S., Miscibility and morp-hology blends of poly(L-Lactic acid) and poly(vinyl acetate- co-vinyl alcohol), Polymer, 44 (2003) 4341-4354.
  • [11] Merfeld G.D., Paul D.R., Polymer-polymer interactions based on mean field approximations, In: Polymer Blend Formulation, Paul DR, Bucknall CB (Eds). New York: John Wiley, Ch 3, (2000) 55-93.
  • [12] Qiu J., Xing C., Cao X., Wang H., Wang L., Zhao L., Li Y., Miscibility and Double Glass Transition Temperature Depression of Poly(l-lactic acid) (PLLA)/Poly(oxymethylene) (POM) Blends, Macromolecules, 46 (14) (2013) 5806-5814.
  • [13] Aubin M.E., Prud'homme R., Analysis of the glass transition temperature of miscible polymer blends, Macromolecules, 21(10) (1988) 2945-2949.
  • [14] Hearn E.J., Chapter 1 - Simple stress and strain, Editor(s): E.J. HEARN, Mechanics of Materials 1. 3rd. Butterworth-Heinemann, (1997) 1-26.
  • [15] Meyers R., Encyclopedia of Physical Science and Technology, 3rd ed. California, (2001) 86-92.

Yıl 2022, Cilt 43, Sayı 1, 61 - 65, 30.03.2022

Ersen YILMAZ

https://doi.org/10.17776/csj.1012540

Öz

Kaynakça

  • [1] Imren D., Boztug A., Yilmaz E., Zengin H.B., Viscometric investigation of compatibilization of the poly(vinyl chloride)/poly(ethylene-co-vinyl acetate) blends by terpolymer of maleic anhydride-styrene-vinyl acetate, Journal of Molecular Structure, 891 (2008) 329-332.
  • [2] Boztug A., Yilmaz E., Effects of reactive terpolymer containing maleic anhydride on thermomechanical properties of poly(vinyl chloride) based multicomponent blends, Materials Research Innovations, 11(3) (2007) 158-160.
  • [3] Imren D., Compatibilization of immiscible poly(vinyl chloride) (PVC)/polystyrene (PS) blends with maleic anhydride-styrene-vinyl acetate terpolymer (MAStVA), Journal of Molecular Structure , 963 (2010) 245-249.
  • [4] Bolayir G., Soygun K., Simsek S, Yilmaz E., Dogan A., Boztug A., Dogan O.M., Effects of the Different Methacrylate Monomers on Bond Strength Between Soft Liner and Acrylic Resin, Asian Journal of Chemistry, 25(14) (2013) 8079-80819
  • [5] Boztuğ A., Zengin H.B., Basan S., Thermomechanical and thermogravimetric analysis of blends of poly (vinyl chloride)(PVC) with maleic anhydride–allyl propionate copolymer, Journal of Molecular Structure, 697 (1-3) (2004) 61-64.
  • [6] Boztug A., Preparation and thermomechanical characterization of poly (vinyl chloride) blends compatible with terpolymer‐containing maleic anhydride, J. Appl. Polym. Sci., 94 (2004) 1586–1589.
  • [7] Aksit A., Menzel T., Aksit M., Altstädt V., Properties of Styrene-Maleic Anhydride Copolymer Compatibilized Polyamide 66/Poly (Phenylene Ether) Blends: Effect of Maleic Anhydride Concentration and Copolymer Content. Materials (Basel, Switzerland), 13(5) (2020) 1237.
  • [8] Dharmarajan N., Datta S., Ver Strate G., Ban L., Compatibilized polymer blends of isotactic polypropylene and styrene—maleic anhydride copolymer, Polymer, 36(20) (1995) 3849-3861.
  • [9] Boztug A., Basan S., The modification and characterization of maleic anhydride-styrene-methyl metacrylate terpolymer by poly(ethylene adipate), J. Mol. Struct., 830 (2007) 126-130.
  • [10] Pork J.W., Lm S.S., Miscibility and morp-hology blends of poly(L-Lactic acid) and poly(vinyl acetate- co-vinyl alcohol), Polymer, 44 (2003) 4341-4354.
  • [11] Merfeld G.D., Paul D.R., Polymer-polymer interactions based on mean field approximations, In: Polymer Blend Formulation, Paul DR, Bucknall CB (Eds). New York: John Wiley, Ch 3, (2000) 55-93.
  • [12] Qiu J., Xing C., Cao X., Wang H., Wang L., Zhao L., Li Y., Miscibility and Double Glass Transition Temperature Depression of Poly(l-lactic acid) (PLLA)/Poly(oxymethylene) (POM) Blends, Macromolecules, 46 (14) (2013) 5806-5814.
  • [13] Aubin M.E., Prud'homme R., Analysis of the glass transition temperature of miscible polymer blends, Macromolecules, 21(10) (1988) 2945-2949.
  • [14] Hearn E.J., Chapter 1 - Simple stress and strain, Editor(s): E.J. HEARN, Mechanics of Materials 1. 3rd. Butterworth-Heinemann, (1997) 1-26.
  • [15] Meyers R., Encyclopedia of Physical Science and Technology, 3rd ed. California, (2001) 86-92.

Ayrıntılar

Birincil Dil İngilizce
Konular Kimya, Ortak Disiplinler
Bölüm Natural Sciences
Yazarlar

Ersen YILMAZ (Sorumlu Yazar)
tunceli munzur üniversitesi
0000-0002-8567-1668
Türkiye

Destekleyen Kurum Munzur Üniversitesi MUNIBAP
Proje Numarası MFMUB017-03
Yayımlanma Tarihi 30 Mart 2022
Başvuru Tarihi 20 Ekim 2021
Kabul Tarihi 28 Şubat 2022
Yayınlandığı Sayı Yıl 2022, Cilt 43, Sayı 1

Kaynak Göster

APA Yılmaz, E. (2022). Blending Effect of Maleic Anhydride-Styrene-Methyl Methacrylate Terpolymer on Polyvinylchloride (Pvc)/Polystyrene (Ps) Mixtures . Cumhuriyet Science Journal , 43 (1) , 61-65 . DOI: 10.17776/csj.1012540
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