Chemometric-Based Optimization of Ionic Liquid-Based Dispersive Liquid-Liquid Microextraction for Separation and Preconcentration of Erythrosine from Real Matrices

Adil Elik; Nail Altunay

doi:10.17776/csj.1007785

EN

Chemometric-Based Optimization of Ionic Liquid-Based Dispersive Liquid-Liquid Microextraction for Separation and Preconcentration of Erythrosine from Real Matrices

Abstract

In this research paper, a simple and economic ionic liquid-based liquid-liquid microextraction (IL-DLLME) procedure was developed to ensure efficient and rapid separation and preconcentration of erythrosine from cosmetic and food samples. Important parameters such as IL volume, temperature, acetone volume, ultrasonic time and pH that may affect the IL-DLLME procedure have been optimized by central composite design (CCD) based on response surface methodology (RSM). The optimum values of IL volume, temperature, acetone volume, ultrasonic time and pH were determined as 440 µL, 35 oC, 120 µL, 9 min and 4.2, respectively. Using these optimum conditions, some analytical data obtained for erythrosine were listed below. Working range, limit of detection and enrichment factor were 2-400 ng mL-1, 0.65 ng mL-1 and 79, respectively. The relative standard deviation (RSD%) was 2.4% for 50 ng mL-1 of erythrosine. The recovery obtained in the analysis of real samples was in the range of 93.2-108.5%. The analytical data obtained showed that the IL-DLLME procedure was successfully applied to the selected samples

Keywords

References

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Details

Primary Language

English

Subjects

-

Journal Section

Research Article

Authors

Adil Elik ^*
0000-0002-3942-4711
Türkiye

Nail Altunay
0000-0001-9053-7570
Türkiye

Publication Date

March 30, 2022

Submission Date

October 10, 2021

Acceptance Date

February 16, 2022

Published in Issue

Year 1970 Volume: 43 Number: 1

DOI

https://doi.org/10.17776/csj.1007785

IZ

https://izlik.org/JA25MB65CC

Cite

RIS / Bibtex

APA

Elik, A., & Altunay, N. (2022). Chemometric-Based Optimization of Ionic Liquid-Based Dispersive Liquid-Liquid Microextraction for Separation and Preconcentration of Erythrosine from Real Matrices. Cumhuriyet Science Journal, 43(1), 53-60. https://doi.org/10.17776/csj.1007785