Cumhuriyet Science Journal
Araştırma Makalesi
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Yıl 2022, Cilt 43, Sayı 1, 38 - 44, 30.03.2022

Yasemin IŞIKVER Ali IŞIKVER

https://doi.org/10.17776/csj.1000417

Öz

Kaynakça

  • [1] El-Azazy M., Dimassi S., El-Shafie A., Issa A., Bio-Waste Aloe vera Leaves as an Efficient Adsorbent for Titan Yellow from Wastewater: Structuring of a Novel Adsorbent Using Plackett-Burman Factorial Design, Appl. Sci., 9 (2019) 4856.
  • [2] Işıkver Y., Synthesis of Anionic Hydrogels for Uranyl Ion Adsorption, Cumhuriyet Sci. J., 38(4) (2017) 770–780.
  • [3] Işikver Y.,Removal of some cationic dyes from aqueous solution by acrylamide- or 2-hydroxyethyl methacrylate-based copolymeric hydrogels, Fiber. Polym.,18(11) (2017) 2070–2078.
  • [4] Cheng X., Li N., Zhu M., Zhang L., Deng Y., Deng C., Positively charged microporous ceramic membrane for the removal of Titan Yellow through electrostatic adsorption, J. Environ. Sci., 44 (2016) 204–212.
  • [5] Ghaemi M., Absalan G., Sheikhian L., Adsorption characteristics of Titan yellow and Congo red on CoFe2O4 magnetic nanoparticles, J. Iran. Chem. Soc., 11(6) (2014) 1759–1766.
  • [6] Web of Science, WOS. Available at: https://www.webofscience.com/wos/woscc/summary/36b6867e-d99d-4371-8868-4ac9292c9274-0d0c3701/relevance/1. Retrieved October 14, 2021.
  • [7] Rastgordani M., Zolgharnein J., Mahdavi V., Derivative spectrophotometry and multivariate optimization for simultaneous removal of Titan yellow and Bromophenol blue dyes using polyaniline@SiO2 nanocomposite, Microchem. J., 155 (2020) 104717.
  • [8] Sun J., Ma X., Li X., Fan J., Chen Q., Liu X., Pan J., Synthesis of a Cationic Polyacrylamide under UV Initiation and Its Flocculation in Estrone Removal, Int. J. Polym. Sci., 2018 (2018) 1–11.
  • [9] Feng L., Zheng H., Tang X., Zheng X., Liu S., Sun Q., Wang M., The investigation of the specific behavior of a cationic block structure and its excellent flocculation performance in high-turbidity water treatment, RSC Adv., 8(27) (2018) 15119–15133.
  • [10] Giles C. H., MacEwan T. H., Nakhwa S. N., Smith D., Studies in adsorption. Part XI. A system of classification of solution adsorption isotherms, and its use in diagnosis of adsorption mechanisms and in measurement of specific surface areas of solids, J. Chem. Soc., 786 (1960) 3973-3993.
  • [11] Ivanovska A., Dojčinović B., Maletic S., Pavun L., Asanović K., Kostić M., Waste Jute Fabric as a Biosorbent for Heavy Metal Ions from Aqueous Solution, Fiber. Polym., 21 (2020) 1992-2002.
  • [12] Saraydın D., Işıkver Y., Karadağ E,. A Study on the Correlation Between Adsorption and Swelling for Poly(Hydroxamic Acid) Hydrogels-Triarylmethane Dyes Systems, J. Polym. Environ., 26(9) (2018) 3924–3936.
  • [13] Yabo W., Yi X., Yongkui Z., Siyang T., Chencen G., Jiansheng W., Raymond L., Chem. Eng. Res. Des., 114 (2016) 258-267.
  • [14] Nechifor G., Pascu D. E., Pascu M., Traistaru G. A., Albu P. C., U.P.B. Sci. Bull. Series B, 77 (2015) 63-72.

Synthesis and Characterization of Cationic P(AAm-AETAC) Hydrogels, and Their Uses in Adsorption of Titan Yellow

Yıl 2022, Cilt 43, Sayı 1, 38 - 44, 30.03.2022

Yasemin IŞIKVER Ali IŞIKVER

https://doi.org/10.17776/csj.1000417

Öz

In this study, a new cationic P(AAm-AETAC) hydrogels were prepared by a radical addition reaction in aqueous solution with acrylamide and [2-(acryloyloxy)ethyl] trimethylammonium chloride) comonomers in the presence of ethylene glycolmethacrylate. Hydrogels were characterized by spectroscopic, surface, and thermal analysis. The hydrogel does not undergo any structural degradation with the effect of heat up to 250 oC.
The adsorption of titan yellow from aqueous solution to the newly prepared cationic hydrogels was evaluated by Freundlich, Langmuir, and Temkin isotherms. The dye adsorption to hydrogels prepared from adsorption isotherms was L type according to the Giles adsorption isotherms. It was determined that the adsorption of titan yellow to the hydrogels prepared from the RL values calculated for a concentration of 500 mg L-1 titan yellow was favorable. The dye removal efficiency of the hydrogel from the aqueous solution was found to be about 98%. As a result, it can be said that the cationic P(AAm-AETAC) hydrogel, which is prepared at a low cost, can provide a high amount of removal in the adsorption of anionic dyes from aqueous solutions.

Anahtar Kelimeler

[2-(acryloyloxy)ethyl] trimethylammonium chloride, Acrylamide, Hydrogel, Titan yellow, Adsorption

Kaynakça

  • [1] El-Azazy M., Dimassi S., El-Shafie A., Issa A., Bio-Waste Aloe vera Leaves as an Efficient Adsorbent for Titan Yellow from Wastewater: Structuring of a Novel Adsorbent Using Plackett-Burman Factorial Design, Appl. Sci., 9 (2019) 4856.
  • [2] Işıkver Y., Synthesis of Anionic Hydrogels for Uranyl Ion Adsorption, Cumhuriyet Sci. J., 38(4) (2017) 770–780.
  • [3] Işikver Y.,Removal of some cationic dyes from aqueous solution by acrylamide- or 2-hydroxyethyl methacrylate-based copolymeric hydrogels, Fiber. Polym.,18(11) (2017) 2070–2078.
  • [4] Cheng X., Li N., Zhu M., Zhang L., Deng Y., Deng C., Positively charged microporous ceramic membrane for the removal of Titan Yellow through electrostatic adsorption, J. Environ. Sci., 44 (2016) 204–212.
  • [5] Ghaemi M., Absalan G., Sheikhian L., Adsorption characteristics of Titan yellow and Congo red on CoFe2O4 magnetic nanoparticles, J. Iran. Chem. Soc., 11(6) (2014) 1759–1766.
  • [6] Web of Science, WOS. Available at: https://www.webofscience.com/wos/woscc/summary/36b6867e-d99d-4371-8868-4ac9292c9274-0d0c3701/relevance/1. Retrieved October 14, 2021.
  • [7] Rastgordani M., Zolgharnein J., Mahdavi V., Derivative spectrophotometry and multivariate optimization for simultaneous removal of Titan yellow and Bromophenol blue dyes using polyaniline@SiO2 nanocomposite, Microchem. J., 155 (2020) 104717.
  • [8] Sun J., Ma X., Li X., Fan J., Chen Q., Liu X., Pan J., Synthesis of a Cationic Polyacrylamide under UV Initiation and Its Flocculation in Estrone Removal, Int. J. Polym. Sci., 2018 (2018) 1–11.
  • [9] Feng L., Zheng H., Tang X., Zheng X., Liu S., Sun Q., Wang M., The investigation of the specific behavior of a cationic block structure and its excellent flocculation performance in high-turbidity water treatment, RSC Adv., 8(27) (2018) 15119–15133.
  • [10] Giles C. H., MacEwan T. H., Nakhwa S. N., Smith D., Studies in adsorption. Part XI. A system of classification of solution adsorption isotherms, and its use in diagnosis of adsorption mechanisms and in measurement of specific surface areas of solids, J. Chem. Soc., 786 (1960) 3973-3993.
  • [11] Ivanovska A., Dojčinović B., Maletic S., Pavun L., Asanović K., Kostić M., Waste Jute Fabric as a Biosorbent for Heavy Metal Ions from Aqueous Solution, Fiber. Polym., 21 (2020) 1992-2002.
  • [12] Saraydın D., Işıkver Y., Karadağ E,. A Study on the Correlation Between Adsorption and Swelling for Poly(Hydroxamic Acid) Hydrogels-Triarylmethane Dyes Systems, J. Polym. Environ., 26(9) (2018) 3924–3936.
  • [13] Yabo W., Yi X., Yongkui Z., Siyang T., Chencen G., Jiansheng W., Raymond L., Chem. Eng. Res. Des., 114 (2016) 258-267.
  • [14] Nechifor G., Pascu D. E., Pascu M., Traistaru G. A., Albu P. C., U.P.B. Sci. Bull. Series B, 77 (2015) 63-72.

Ayrıntılar

Birincil Dil İngilizce
Konular Kimya, Ortak Disiplinler
Bölüm Natural Sciences
Yazarlar

Yasemin IŞIKVER (Sorumlu Yazar)
CUMHURIYET UNIVERSITY, FACULTY OF SCIENCE
0000-0001-6481-188X
Türkiye

Ali IŞIKVER Bu kişi benim
MEB Ulaş ÇPAL, Sivas
0000-0003-3871-9435
Türkiye

Destekleyen Kurum Yok
Proje Numarası Yok
Teşekkür Yok
Yayımlanma Tarihi 30 Mart 2022
Başvuru Tarihi 24 Eylül 2021
Kabul Tarihi 27 Ocak 2022
Yayınlandığı Sayı Yıl 2022, Cilt 43, Sayı 1

Kaynak Göster

APA Işıkver, Y. & Işıkver, A. (2022). Synthesis and Characterization of Cationic P(AAm-AETAC) Hydrogels, and Their Uses in Adsorption of Titan Yellow . Cumhuriyet Science Journal , 43 (1) , 38-44 . DOI: 10.17776/csj.1000417
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