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Major and trace element enrichment in Kızıldere formation (Arsuz-Hatay)

Year 2021, Volume: 42 Issue: 4, 830 - 835, 29.12.2021

Esef Kılınç , Meryem Yeşilot Kaplan

Abstract

The study area is in the Arsuz - HATAY region and the geochemical properties and deposition environment of the claystones in the Kızıldere Formation (Middle - Upper Miocene) were investigated in this study. Kızıldere Formation, which is common in Arsuz and İskenderun (Hatay) regions, has both bedrock and reservoir rock characteristics. It generally consists of a sequence of medium bedded sandstones and thin to medium bedded claystones. The average concentrations of major and trace elements in the samples taken from ten different points of the Arsuz region were determined (V-1180.65 ppm, Ni-219.83 ppm, Cr-149.26 ppm, Co-19.45 ppm, Cu-22.63 ppm, Rb-42.96 ppm, As-8.40 ppm, Zn-54.47 ppm, Sb- 0.61 ppm, Mo-1.28 ppm, Cd - (- 0.71) ppm, Pb- 5.68 ppm, U-1, It is 35 ppm, Ba-171.15 ppm, Li-24.64 ppm, Cs-3.06 ppm, S-325.48 ppm). V / Ni, Ni / Co, V (V + Ni), V / Cr, (Cu / Mo) / Zn ratios in claystones and increases in concentrations in trace elements (e.g. V, U, Ni) indicates that it precipitated in the marine-anoxic environment. In addition, in the distribution mapping drawn according to the trace elements Ni-U-Cu-Zn in the region, the paleo-environment changes with organic matter conservation were determined. 

Keywords

Depositional properties Geochemical characteristics , Kızıldere Formation Claystones Reservoir rock

Thanks

This study was prepared with thesis number 521587.

References

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  • [14] Tekin E., Varol B., Ayyıldız T., Kozlu H., İskenderun Havzası Messiniyen (Üst Miyosen) Evaporitlerinin Sedimantolojisi. Ankara: MTA 59. Türkiye Jeoloji Kurultayı, (2006) 191-192.
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  • [22] Wedepohl K.H., Environmental influences on the chemical composition of shales and clays, In: Ahrens, L.H., Press, F.,Runcorn, S.K., Urey, H.C. (Eds.), Physics and Chemistry of the Earth, 8 (1971) 307-331. Hallberg R., Халлберг Р., A Geochemical Method for Investigation of Paleoredox Conditions in Sediments, Ambio Special Report, (4) (1976) 139-147.

Year 2021, Volume: 42 Issue: 4, 830 - 835, 29.12.2021

Esef Kılınç , Meryem Yeşilot Kaplan

Abstract

References

  • [1] Schneider S., Hornung J., Hinderer M., Garzanti E., Petrography and Geochemistry of Modern River Sediments in an Equatorial Environment (Rwenzori Mountains and Albertine Rift, Uganda) Implications for Weathering and Provenance, Sedimentary Geology, 336 (2016) 106-119.
  • [2] Rollinson H. R., Using Geochemical Data: Evaluation, Presentation, Interpretation, Routledge, 2014.
  • [3] Gélinas Y., Baldock J.A., Hedges, J.I., Organic Carbon Composition of Marine Sediments: Effects of Oxygen Exposure on Oil Generation Potential, Science, 294 (2001) 145-148.
  • [4] Xie X., Borjigin T., Zhang Q., Zhang Z., Qin J., Bian L., Volkman, J. K., Intact Microbial Fossils in the Permian Lucaogou Formation Oil Shale, Junggar Basin, NW China, International Journal of Coal Geology, 146 (2015) 166-178.
  • [5] Kӓtz B.J., Controlling Factors on Source Rock Development a Review of Productivity, Preservation, and Sedimentation Rate, In: Harris, N.B. (eds), The Deposition of Organic Carbon Rich Sediments: Models, Mechanisms, and Consequences, SEPM, (2005) 282.
  • [6] Koca D., Sarı A., Koç Ş., Yavuz B., Koralay D.B., Denizel Kaynak Kayalarda Ana ve İz Element Zenginleşmelerine Türkiye’den Bir Örnek: Akkuyu Formasyonu (Orta Toroslar), Ankara, Gazi Üniv. Müh. Mim. Fak. Der., 25(2) (2010) 243-256.
  • [7] Schmidt G.C., Stratigraphic Nomenclature for the Adana Region Petroleum District VII, Ankara, Petroleum Administration Bull., 6 (1961) 47-63.
  • [8] Kozlu H., İskenderun Basen Jeolojisi ve Petrol Olanakları, TPAO Rapor no:1921, 1982.
  • [9] Kozlu H., Misis Andırın Dolaylarının Stratigrafisi ve Yapısal Evrimi. Ankara: Türkiye 7. Petrol Kongresi, (1987) 104-113.
  • [10] Yaşar E., Assessment of Petroleum geology of Iskenderun Basin, (2018) 200-206.
  • [11] Kozlu H., Doğu Akdeniz Bölgesinde Yer Alan Neojen Basenlerinin (İskenderun, Misis-Andırın) Tektono-stratigrafi Birimleri ve Bunların Tektonik Gelişimi. Adana: Yayınlanmamış Doktora Tezi, Çukurova Üniversitesi, Fen Bilimleri Enstitüsü, (1997) 189.
  • [12] Kılınç E., Yeşi̇lot Kaplan M., Source Rock Characterictic of The Kızıldere Clays (ARSUZ-HATAY), Cumhuriyet Sci. J., 39(2) (2018) 524-530.
  • [13] Kilinc E., Kaplan M.Y., Paleoenvironmental Conditions, Geochemistry and Hydrocarbon Potential of Kızıldere Formation (Hatay-Turkey), Fresenius Environmental Bulletin, 28(4A), (2019) 3516-3526.
  • [14] Tekin E., Varol B., Ayyıldız T., Kozlu H., İskenderun Havzası Messiniyen (Üst Miyosen) Evaporitlerinin Sedimantolojisi. Ankara: MTA 59. Türkiye Jeoloji Kurultayı, (2006) 191-192.
  • [15] Soua M., Productivity and bottom water redox conditions at the Cenomanian-Turonian Oceanic Anoxic Event in the southern Tethyan margin, Tunisia, Revue Mediterraneenne de l'Environement, 4 (2010) 653-664
  • [16] Pedersen T.F., Calvert S.E., Anoxia vs. productivity: what controls the formation of organic-carbon-rich sediments and sedimentary rocks, American Association of Petroleum Geologists Bulletin, 74 (1990) 454-466.
  • [17] Kılınç, E., Arsuz (Hatay) yöresi Kızıldere formasyonunun hidrokarbon potansiyelinin araştırılması, MS Thesis, İskenderun Teknik Üniversitesi, Mühendislik ve Fen Bilimleri Enstitüsü (2018) 96.
  • [18] Pattan J.N., Pearce N.J.C., Bottom water oxygenation history in southeastern Arabian Sea during the past 140 ka: Results from redox-sensitive elements, Palaeogeography, Palaeoclimatology, Palaeoecology, 280 (2009) 396-405.
  • [19] Jones B., Manning D.A.C., Comparison of geological indices used for the interpretation of palaeoredox conditions in ancient mudstones, Chemical Geology, 111 (1994) 111-129.
  • [20] Goldberg K., Humayun M., Geochemical paleoredox indicators in organic-rich shales of the Irati Formation, Permian of the Paraná Basin, southern Brazil, Brazilian Journal of Geology, 46(3) (2016) 377-393.
  • [21] Lewan M.D., Factors controlling the proportionality of vanadium and nickelin crude oils, Geochimica et Cosmochimica Acta., 48 (1984) 2231-2238.
  • [22] Wedepohl K.H., Environmental influences on the chemical composition of shales and clays, In: Ahrens, L.H., Press, F.,Runcorn, S.K., Urey, H.C. (Eds.), Physics and Chemistry of the Earth, 8 (1971) 307-331. Hallberg R., Халлберг Р., A Geochemical Method for Investigation of Paleoredox Conditions in Sediments, Ambio Special Report, (4) (1976) 139-147.
There are 22 citations in total.

Details

Primary Language English
Subjects Material Production Technologies
Journal Section Natural Sciences
Authors

Esef Kılınç 0000-0002-5510-1568

Meryem Yeşilot Kaplan 0000-0001-8900-8823

Publication Date December 29, 2021
Submission Date January 15, 2021
Acceptance Date October 23, 2021
Published in Issue Year 2021Volume: 42 Issue: 4

Cite

APA Kılınç, E., & Yeşilot Kaplan, M. (2021). Major and trace element enrichment in Kızıldere formation (Arsuz-Hatay). Cumhuriyet Science Journal, 42(4), 830-835.