Araştırma Makalesi
UV-VIS spectrophotometric determination of magnesium after complexing with 8-hydroxy quinoline in sodium dodecyl sulphate micellar medium
Öz
In this study, an alternatifive UV-VIS spectrophotometric method for determination of magnesium was proposed. The method is based on complexation with 8-hydoxyquinoline (oxin) in sodium dodecyl sulphate (SDS) micelle medium, the absorbance of the product was recorded at 390 nm. pH of the solution, the concentration of ligand and surfactant were critical parameters, which affect the absorbance measurements, and optimised. The molar absorptivitiy coefficient is 5×102 Lmol-1cm-1, the Sandell’s sensitivity is 0,052 µgcm-2, detection limit is 0,3 mgL-1, quantification limit is 1,1 mgL-1 and linear working range is 2-8 mgL-1 at pH 12 and 390 nm. The proposed method was applied for determination of magnesium to some drug and mineral water samples, nearly good accuracy and reproducible volues were obtained percent as recovery and relative standart deviation.
Anahtar Kelimeler
Magnesium analys UV-VIS spectrophotometric method 8-hydoxyquinoline sodyumdodecilsulphate
Destekleyen Kurum
-
Proje Numarası
-
Kaynakça
- Pramaura, E. and Pelizetti, E., Surfactants in Analytical chemistry, Chapter 4, Hardbound, 2008; pp 203-211.
- Young A., Sweet T. R. and Baker B. B. Simultaneous Spectrophotometric Determination of Calcium and Magnesium, Analytical Chemistry, 27(3) (1955) 356-359.
- Ferguson J. W., Richard J. J., O’laughlin J. W. and Banks C. V. Simultaneous Spectrophotometric Determination of Calcium and Magnesium with Chlorophosphonazo III, Analytical Chemistry, 36 (4) (1964) 796-799.
- Shibata S. Uchiumi, A., Saski S. and Goto K. Spectrophotometric determination of magnesium with chromotrope 2R: Application to zinc and aluminum alloys, Analytica Chimica Acta, 44 (2) (1969) 345–352.
- Lurie, J., Handbook of Analytical Chemistry, MIR publıshers, Moskow: (1975); pp 261 - 326,
- Khayam-Bashi H., Liu TZ. and Walter V. Measurement of Serum Magnesium with a Centrufigal Analyzer, Clin. Nephrol., 46 (1977) 326-331.
- Ceba M., R., Fernándezgutiérrez A. and Mahedero M. C. 1,8-dihydroxyanthraquinone-Mg (II) complex: II. Spectrophotometric study, Determination of Mg(II), Microchemical Journal, 27 (1982) 339-344.
- Xing Q. and Ying Z. Rapid analysis of cation-exchangeable property in acidic soil: III. Sensitive spectrophotometric determination of microgram amounts of exchangeable magnesium with xylidyl Blue I in the presence of CTAB, Microchemical Journal, (33) (3) (1986) 364-370.
- Peerzeda N. and Kozlik E., Spectrophotometric Determination of Magnesium with 2,2',6',2'' Terpyridine, Analytical Letters, (23) (6) (1990) 1087 – 1093.
- Idriss K. A., Sedaira H. and Ahmed H. M. An Insight into the Solution Equilibria of Magnesium (II) with Purpurin and Spectrophotometric Determination of Magnesium, Talanta, 54(2) (2001) 369-375.
- Tesfaldet Z. O., Staden J. F. and Stefan R. I. Spectrophotometric determination of magnesium in pharmaceutical preparations by cost-effective sequential injection Analysis, Talanta, (64) (2004) 981-988
- Fangqin C., Yaning Z., Huimin C. and Chuan D. UV spectrophotometric determination of magnesium and calcium in brine from salt lake, Inorganic Chemicals Industry,13 (2006) 11-21.
- Afkhami A., Madrakian T. and Abbasi M. T. Simultaneous determination of calcium, magnesium and zinc in different foodstuffs and pharmaceutical samples with continuous wavelet transforms, Food Chemistry, (109) (3) (2008) 660–669.
- Dallali N. and Agrawal Y. K. Solvent Extraction and Spectrophotometric Determination of Magnesium by Paratoly l-2-Thenohydroxamic Acid and Quinalizarin, Iran. J. Chem. & Chem. Eng., (23) (1) (2004) 65-71.
- Abernethy M. and Fowler R. T., Micellar Imrovement of the Calmatige Compleximetric Measurement of Magnesium in Plasma, Clin. Chem., 28 (3) (1982) 520-522
- Ratge D., Koshe K. and Wisser H. Measurement of Magnesium in Serum and Urine with a Random Access Analyzer by Use of a Modified Xylidyl blue-1 Procedure, Clin Chim Acta., 159 (1986) 197-203.
- Benamor M. ve Aguerssif N., Simultaneous determination of calcium and magnesium by derivative spectrophotometry in pharmaceutical products, Spectrochimica Acta Part A, (69) (2008) 676-681.
- Gürkan R., Ulusoy H. I. and Akçay M. Micellar-Sensitized Spectrophotometric Determination of Magnesium in Drinking Water, Eurasian J. Anal. Chem., (4) (2) (2009) 127-140.
- Bode H., On Sandell’s sensitivity, Fresenius J Anal. Chem., 339:898 (1991) 12-15.
Yıl 2020,
Cilt: 41 Sayı: 3, 671 - 679, 30.09.2020
Öz
Proje Numarası
-
Kaynakça
- Pramaura, E. and Pelizetti, E., Surfactants in Analytical chemistry, Chapter 4, Hardbound, 2008; pp 203-211.
- Young A., Sweet T. R. and Baker B. B. Simultaneous Spectrophotometric Determination of Calcium and Magnesium, Analytical Chemistry, 27(3) (1955) 356-359.
- Ferguson J. W., Richard J. J., O’laughlin J. W. and Banks C. V. Simultaneous Spectrophotometric Determination of Calcium and Magnesium with Chlorophosphonazo III, Analytical Chemistry, 36 (4) (1964) 796-799.
- Shibata S. Uchiumi, A., Saski S. and Goto K. Spectrophotometric determination of magnesium with chromotrope 2R: Application to zinc and aluminum alloys, Analytica Chimica Acta, 44 (2) (1969) 345–352.
- Lurie, J., Handbook of Analytical Chemistry, MIR publıshers, Moskow: (1975); pp 261 - 326,
- Khayam-Bashi H., Liu TZ. and Walter V. Measurement of Serum Magnesium with a Centrufigal Analyzer, Clin. Nephrol., 46 (1977) 326-331.
- Ceba M., R., Fernándezgutiérrez A. and Mahedero M. C. 1,8-dihydroxyanthraquinone-Mg (II) complex: II. Spectrophotometric study, Determination of Mg(II), Microchemical Journal, 27 (1982) 339-344.
- Xing Q. and Ying Z. Rapid analysis of cation-exchangeable property in acidic soil: III. Sensitive spectrophotometric determination of microgram amounts of exchangeable magnesium with xylidyl Blue I in the presence of CTAB, Microchemical Journal, (33) (3) (1986) 364-370.
- Peerzeda N. and Kozlik E., Spectrophotometric Determination of Magnesium with 2,2',6',2'' Terpyridine, Analytical Letters, (23) (6) (1990) 1087 – 1093.
- Idriss K. A., Sedaira H. and Ahmed H. M. An Insight into the Solution Equilibria of Magnesium (II) with Purpurin and Spectrophotometric Determination of Magnesium, Talanta, 54(2) (2001) 369-375.
- Tesfaldet Z. O., Staden J. F. and Stefan R. I. Spectrophotometric determination of magnesium in pharmaceutical preparations by cost-effective sequential injection Analysis, Talanta, (64) (2004) 981-988
- Fangqin C., Yaning Z., Huimin C. and Chuan D. UV spectrophotometric determination of magnesium and calcium in brine from salt lake, Inorganic Chemicals Industry,13 (2006) 11-21.
- Afkhami A., Madrakian T. and Abbasi M. T. Simultaneous determination of calcium, magnesium and zinc in different foodstuffs and pharmaceutical samples with continuous wavelet transforms, Food Chemistry, (109) (3) (2008) 660–669.
- Dallali N. and Agrawal Y. K. Solvent Extraction and Spectrophotometric Determination of Magnesium by Paratoly l-2-Thenohydroxamic Acid and Quinalizarin, Iran. J. Chem. & Chem. Eng., (23) (1) (2004) 65-71.
- Abernethy M. and Fowler R. T., Micellar Imrovement of the Calmatige Compleximetric Measurement of Magnesium in Plasma, Clin. Chem., 28 (3) (1982) 520-522
- Ratge D., Koshe K. and Wisser H. Measurement of Magnesium in Serum and Urine with a Random Access Analyzer by Use of a Modified Xylidyl blue-1 Procedure, Clin Chim Acta., 159 (1986) 197-203.
- Benamor M. ve Aguerssif N., Simultaneous determination of calcium and magnesium by derivative spectrophotometry in pharmaceutical products, Spectrochimica Acta Part A, (69) (2008) 676-681.
- Gürkan R., Ulusoy H. I. and Akçay M. Micellar-Sensitized Spectrophotometric Determination of Magnesium in Drinking Water, Eurasian J. Anal. Chem., (4) (2) (2009) 127-140.
- Bode H., On Sandell’s sensitivity, Fresenius J Anal. Chem., 339:898 (1991) 12-15.
Toplam 19 adet kaynakça vardır.
Ayrıntılar
| Birincil Dil | İngilizce |
|---|---|
| Bölüm | Natural Sciences |
| Yazarlar | |
| Proje Numarası | - |
| Yayımlanma Tarihi | 30 Eylül 2020 |
| Gönderilme Tarihi | 8 Ekim 2019 |
| Kabul Tarihi | 5 Haziran 2020 |
| Yayımlandığı Sayı | Yıl 2020Cilt: 41 Sayı: 3 |