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Isıl Püskürtme Yöntemi ile Büyütülen SnO2 nin Karakteristik Özelliklerine Sb-Katkısının Etkisi

Year 2019, Volume: 40 Issue: 1, 162 - 169, 22.03.2019

Güven Turgut

https://doi.org/10.17776/csj.512892

Abstract

Bu çalışma Sb-katkısının SnO2 nin
kristal, yüzeysel, optik ve elektriksel özelliklerine etkisini sunmaktadır. Sb
katkılı numuneler ısıl püskürtme yöntemi ile cam altlıklar üzerine büyütmüştür.
Piramit ve çok yüzlü şekilli tetragonal Sb katkılı SnO2 taneleri XRD ve SEM
analizleri ile belirlenmiştir. Filmler için dejenere n-tipi iletkenlik özelliği
elektriksel ve optiksel karakterizasyonlar ile belirlenmiştir. Özdirenç ve
tabaka direnci değerleri ilk olarak ağırlıkça % 1.5 Sb içeriği ile azalmıştır
ve sonra bu değerler daha fazla Sb içeriği ile artmıştır. Fakat taşıyıcı
konsantrasyonu ağırlıkça % 2.5 Sb içeriği ile artmıştır, sonra ise % 3.5 Sb
içeriği ile azalmaya başlamıştır. Numunelerin optik bant aralığı Sb katkılama
ile azalma eğilimindedir. Bu çalışmada elde edilen sonuçlardan Sb katkılı kalay
oksit ince filmlerin optoelektronik uygulamalarda kullanılabileceği
söylenebilir.

Keywords

Isıl püskürtme SnO2 Sb-katkılama Elektriksel özellikler

References

  • [1]. Babu B., Kadam A.N., Ravikumar R.V.S.S.N., Byon C., Enhanced visible light photocatalytic activity of Cu-doped SnO2 quantum dots by solution combustion synthesis, J. Alloy. Comp. 703 (2017) 330-336.
  • [2]. Turgut G., Effect of Ta doping on the characteristic features of spray-coated SnO2, Thin Solid Films 594 (2015) 56-66.
  • [3]. Bhatnagar M., Dhall S., Kaushik V., Kaushal A., Mehta B.R., Improved selectivity of SnO2:C alloy nanoparticles towards H2 and ethanol reducing gases; role of SnO2:C electronic interaction, Sensors and Actuators B 246 (2017) 336-343.
  • [4]. Chandra S., George G., Ravichandran K., Thirumurugan K., Influence of simultaneous cationic (Mn) and anionic (F) doping on the magnetic and certain other properties of SnO2 thin films, Surfaces and Interfaces 7 (2017) 39-46.
  • [5]. Lian X., Li Y., Tong X., Zou Y., Liu X., An D., Wang Q., Synthesis of Ce-doped SnO2 nanoparticles and their acetone gas sensing properties, App. Surf. Sci. 407 (2017) 447-455.
  • [6]. Gao F., Li Y., Zhao Y., Wan W., Du G., Ren X., Zhao H., Facile synthesis of flower-like hierarchical architecture of SnO2 nanoarrays, J. Alloy. Comp. 703 (2017) 354-360.
  • [7]. Turgut G., Keskenler E.F., Aydın S., Sönmez E., Doğan S., Düzgün B., Ertuğrul M., Effect of Nb doping on structural, electrical and optical properties of spray deposited SnO2 thin films, Superlattices and Microstructures 56 (2013) 107-116.
  • [8]. Elangovan E., Ramamurthi K., A study on low cost-high conducting fluorine and antimony-doped tin oxide thin films, App. Surf. Sci. 249 (2005) 183-196. [9]. Ynineb F., Attaf N., Aida M.S., Bougdira J., Bouznit Y., Rinnert H., Morphological and optoelectrical study of ZnO:In/p-Si heterojunction prepared by ultrasonic spray pyrolysis, Thin Solid Films 628 (2017) 36-42.
  • [10]. Menaka S. M., Umadevi G., Manickam M., Effect of copper concentration on the physical properties of copper doped NiO thin films deposited by spray pyrolysis, Material Chemistry and Physics 191 (2017) 181-187.
  • [11]. Babar A.R., Shinde S.S., Moholkar A.V., Bhosale C.H., Kim J.H., Rajpure K.Y., Physical properties of sprayed antimony doped tin oxide thin films: The role of thickness, Journal of Semiconductors 32 (2011) 8p.
  • [12]. Babar A.R., Shinde S.S., Moholkar A.V., Bhosale C.H., Kim J.H., Rajpure K.Y., Sensing properties of sprayed antimony doped tin oxide thin films: Solution molarity, J. Alloy. Comp. 509 (2011) 3108-3115.
  • [13]. Babar A.R., Shinde S.S., Moholkar A.V., Bhosale C.H., Kim J.H., Rajpure K.Y., Structural and optoelectronic properties of antimony incorporated tin oxide thin films, J. Alloy. Compd. 505 (2010) 416-422.
  • [14]. Bisht H., Eun H.T., Mehrtens A., Aegerter M.A., Comparison of spray pyrolyzed FTO, ATO and ITO coatings for flat and bent glass substrates, Thin Solid Films 351 (1999) 109-114.
  • [15]. Elangovan E., Ramamurthi K., Effect of substrate temperature on electrical and optical properties of spray deposited SnO2:Sb Thin Films, J. Opt. Adv. Mater. 5 (2003) 415-420.
  • [16]. Elangovan E., Ramamurthi K., Studies on optical properties of polycrystalline SnO2:Sb thin films prepared using SnCl2 precursor, Cryst. Res. Cryst. Tech. 38 (2003) 779-784.
  • [17]. Elangovan E., Ramesh K., Ramamurthi K., Studies on the structural and electrical properties of spray deposited SnO2:Sb thin films as a function if substrate temperature, Solid State Commun. 130 (2004) 523-527.
  • [18]. Elangovan E., Shivashankar S.A., Ramamurthi K., Studies on structural on structural and electrical properties of sprayed SnO2:Sb films, J. Crys. Growth 276 (2005) 215-221.
  • [19]. Ravichandran K., Philominathan P., Fabrication of antimony doped tin oxide (ATO) films by an inexpensive, simplified spray technique using perfume atomizer, Mater. Lett. 62 (2008) 2980-298.
  • [20]. Ravichandran K., Phiominathan P., Analysis of critical doping level of sprayed antimony doped tin oxide films, J. Mater. Sci: Mater. in Elec. 22 (2011) 158-161.
  • [21]. Thangaraju B., Structural and electrical studies on highly conducting spray deposited fluorine and antimony doped SnO2 thin films from SnCl2 precursor, Thin Solid Films 402 (2002) 71-78.
  • [22]. Turgut G., Duman S., Özçelik F.S., Sonmez E., Gurbulak B., An investigation of Zn/ZnO:Al/p-Si/Al heterojunction diode by sol-gel spin coating technique, J. Sol-Gel Sci. Technol. 71 (2014) 589-596.
  • [23]. Smith A., Laurent J. M., Smith D. S., Bonnet J. P., Clemente R. R., Relation between solution chemistry and morphology of SnO2-based thin films deposited by a pyrosol process, Thin Solid Films 266 (1995) 20-30.
  • [24]. Turgut G. and Keskenler E.F., The characteristic investigation of spray coated W incorporated in oxide thin films, Moscow University Physics Bulletin 71 (2016) 105-113.
  • [25]. Kazmerski L.L., Polycrystalline and Amorphous Thin Films and Devices.New York: Academic Press, 1980.
  • [26]. Turgut G. and, Sönmez E., Synthesis and characterization of Mo doped SnO2 thin films with spray pyrolysis, Superlattices and Microstructures 69 (2014) 175-186.
  • [27]. Whitney J.E. and Davidson N., A Spectrophotometric Investigation of the Interaction between Antimony (III) and (V)1a,b,c in Hydrochloric Acid Solutions, J. American Chem. Soc. 71 (1949) 3809-3816.
  • [28]. Jung D. W. and Park D. W., Synthesis of nano-sized antimony-doped tin oxide (ATO) particles using a DC arc plasma jet, App. Surf. Sci. 255 (2009) 5409-5413.

Sb-Contribution Influence on the Characteristics of Spray-Coated SnO2

Year 2019, Volume: 40 Issue: 1, 162 - 169, 22.03.2019

Güven Turgut

https://doi.org/10.17776/csj.512892

Abstract

This work presents that the impact of Sb-additive on the crystalline,
morphological, optical, and electrical features of SnO2.
Sb-incorporated samples were fabricated on glass substrates with spray
pyrolysis. Pyramidal and polyhedron shaped tetragonal Sb-introduced SnO2
grains were identified with XRD and SEM analysis. The degenerate n-type
character for films was determined by electrical and optical characterizations.
The resistivity and sheet resistance values initially decreased with Sb-content
until 1.5 wt. %, then they increased with further Sb-level. However, carrier
concentration increased with 2.5 wt. % Sb-contribution, then it started to goes
down with 3.5 wt. %. The optical band-gap values of samples had a decreasing
tendency with Sb-doping. From the results obtained in the present study, it is
said that Sb-incorporated tin oxide films can be utilized in optoelectronic
implements.

Keywords

Sb-doping Electrical properties Spray Pyrolysis SnO2 Electrical properties

References

  • [1]. Babu B., Kadam A.N., Ravikumar R.V.S.S.N., Byon C., Enhanced visible light photocatalytic activity of Cu-doped SnO2 quantum dots by solution combustion synthesis, J. Alloy. Comp. 703 (2017) 330-336.
  • [2]. Turgut G., Effect of Ta doping on the characteristic features of spray-coated SnO2, Thin Solid Films 594 (2015) 56-66.
  • [3]. Bhatnagar M., Dhall S., Kaushik V., Kaushal A., Mehta B.R., Improved selectivity of SnO2:C alloy nanoparticles towards H2 and ethanol reducing gases; role of SnO2:C electronic interaction, Sensors and Actuators B 246 (2017) 336-343.
  • [4]. Chandra S., George G., Ravichandran K., Thirumurugan K., Influence of simultaneous cationic (Mn) and anionic (F) doping on the magnetic and certain other properties of SnO2 thin films, Surfaces and Interfaces 7 (2017) 39-46.
  • [5]. Lian X., Li Y., Tong X., Zou Y., Liu X., An D., Wang Q., Synthesis of Ce-doped SnO2 nanoparticles and their acetone gas sensing properties, App. Surf. Sci. 407 (2017) 447-455.
  • [6]. Gao F., Li Y., Zhao Y., Wan W., Du G., Ren X., Zhao H., Facile synthesis of flower-like hierarchical architecture of SnO2 nanoarrays, J. Alloy. Comp. 703 (2017) 354-360.
  • [7]. Turgut G., Keskenler E.F., Aydın S., Sönmez E., Doğan S., Düzgün B., Ertuğrul M., Effect of Nb doping on structural, electrical and optical properties of spray deposited SnO2 thin films, Superlattices and Microstructures 56 (2013) 107-116.
  • [8]. Elangovan E., Ramamurthi K., A study on low cost-high conducting fluorine and antimony-doped tin oxide thin films, App. Surf. Sci. 249 (2005) 183-196. [9]. Ynineb F., Attaf N., Aida M.S., Bougdira J., Bouznit Y., Rinnert H., Morphological and optoelectrical study of ZnO:In/p-Si heterojunction prepared by ultrasonic spray pyrolysis, Thin Solid Films 628 (2017) 36-42.
  • [10]. Menaka S. M., Umadevi G., Manickam M., Effect of copper concentration on the physical properties of copper doped NiO thin films deposited by spray pyrolysis, Material Chemistry and Physics 191 (2017) 181-187.
  • [11]. Babar A.R., Shinde S.S., Moholkar A.V., Bhosale C.H., Kim J.H., Rajpure K.Y., Physical properties of sprayed antimony doped tin oxide thin films: The role of thickness, Journal of Semiconductors 32 (2011) 8p.
  • [12]. Babar A.R., Shinde S.S., Moholkar A.V., Bhosale C.H., Kim J.H., Rajpure K.Y., Sensing properties of sprayed antimony doped tin oxide thin films: Solution molarity, J. Alloy. Comp. 509 (2011) 3108-3115.
  • [13]. Babar A.R., Shinde S.S., Moholkar A.V., Bhosale C.H., Kim J.H., Rajpure K.Y., Structural and optoelectronic properties of antimony incorporated tin oxide thin films, J. Alloy. Compd. 505 (2010) 416-422.
  • [14]. Bisht H., Eun H.T., Mehrtens A., Aegerter M.A., Comparison of spray pyrolyzed FTO, ATO and ITO coatings for flat and bent glass substrates, Thin Solid Films 351 (1999) 109-114.
  • [15]. Elangovan E., Ramamurthi K., Effect of substrate temperature on electrical and optical properties of spray deposited SnO2:Sb Thin Films, J. Opt. Adv. Mater. 5 (2003) 415-420.
  • [16]. Elangovan E., Ramamurthi K., Studies on optical properties of polycrystalline SnO2:Sb thin films prepared using SnCl2 precursor, Cryst. Res. Cryst. Tech. 38 (2003) 779-784.
  • [17]. Elangovan E., Ramesh K., Ramamurthi K., Studies on the structural and electrical properties of spray deposited SnO2:Sb thin films as a function if substrate temperature, Solid State Commun. 130 (2004) 523-527.
  • [18]. Elangovan E., Shivashankar S.A., Ramamurthi K., Studies on structural on structural and electrical properties of sprayed SnO2:Sb films, J. Crys. Growth 276 (2005) 215-221.
  • [19]. Ravichandran K., Philominathan P., Fabrication of antimony doped tin oxide (ATO) films by an inexpensive, simplified spray technique using perfume atomizer, Mater. Lett. 62 (2008) 2980-298.
  • [20]. Ravichandran K., Phiominathan P., Analysis of critical doping level of sprayed antimony doped tin oxide films, J. Mater. Sci: Mater. in Elec. 22 (2011) 158-161.
  • [21]. Thangaraju B., Structural and electrical studies on highly conducting spray deposited fluorine and antimony doped SnO2 thin films from SnCl2 precursor, Thin Solid Films 402 (2002) 71-78.
  • [22]. Turgut G., Duman S., Özçelik F.S., Sonmez E., Gurbulak B., An investigation of Zn/ZnO:Al/p-Si/Al heterojunction diode by sol-gel spin coating technique, J. Sol-Gel Sci. Technol. 71 (2014) 589-596.
  • [23]. Smith A., Laurent J. M., Smith D. S., Bonnet J. P., Clemente R. R., Relation between solution chemistry and morphology of SnO2-based thin films deposited by a pyrosol process, Thin Solid Films 266 (1995) 20-30.
  • [24]. Turgut G. and Keskenler E.F., The characteristic investigation of spray coated W incorporated in oxide thin films, Moscow University Physics Bulletin 71 (2016) 105-113.
  • [25]. Kazmerski L.L., Polycrystalline and Amorphous Thin Films and Devices.New York: Academic Press, 1980.
  • [26]. Turgut G. and, Sönmez E., Synthesis and characterization of Mo doped SnO2 thin films with spray pyrolysis, Superlattices and Microstructures 69 (2014) 175-186.
  • [27]. Whitney J.E. and Davidson N., A Spectrophotometric Investigation of the Interaction between Antimony (III) and (V)1a,b,c in Hydrochloric Acid Solutions, J. American Chem. Soc. 71 (1949) 3809-3816.
  • [28]. Jung D. W. and Park D. W., Synthesis of nano-sized antimony-doped tin oxide (ATO) particles using a DC arc plasma jet, App. Surf. Sci. 255 (2009) 5409-5413.
There are 27 citations in total.

Details

Primary Language English
Journal Section Natural Sciences
Authors

Güven Turgut 0000-0002-5724-516X

Publication Date March 22, 2019
Submission Date July 2, 2017
Acceptance Date January 14, 2019
Published in Issue Year 2019Volume: 40 Issue: 1

Cite

APA Turgut, G. (2019). Sb-Contribution Influence on the Characteristics of Spray-Coated SnO2. Cumhuriyet Science Journal, 40(1), 162-169. https://doi.org/10.17776/csj.512892