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Investigation of Structural, Optical and Photovoltaic Properties of Sb2S3 Thin Films

Yıl 2017, Cilt: 38 Sayı: 3, 588 - 593, 30.09.2017

Sabit Horoz , Hüsnü Koç Ömer Şahin

https://doi.org/10.17776/csj.340520
Cited By: 7

Öz

Sb2S3 thin films were
prepared on amorphous glass substrates by chemical bath deposition (CBD) at
room temperature.  The Sb2S3
thin films were characterized by x-ray diffraction (XRD), Raman spectroscopy,
scanning electron microscopy (SEM) and UV-Vis spectroscopy.  The XRD revealed that the as deposited Sb2S3
thin film has a different structure compared to annealed Sb2S3
thin film. As deposited Sb2S3 thin film showed amorphous
structures while the Sb2S3 thin film became
polycrystalline after annealing at 350 0C for 1h under N2.  The band gaps of the Sb2S3 thin
films were compared using UV-Vis spectroscopy. 
The spectral response of the Sb2S3 thin film
enhanced after the annealing process. The Sb2S3 thin
films were subsequently used to make semiconductor-sensitized TiO2 nanowire
(NW) solar cells.  The performances of
the solar cells, with the short circuit current density and open circuit
voltage, were investigated. Based on the optical and photovoltaic measurements,
we consider that annealed Sb2S3 thin films can be
promising materials for developing solar cell technologies. 

Anahtar Kelimeler

Sb2S3 thin films chemical bath deposition semiconductor –sensitized solar cells

Kaynakça

  • [1]. M T S Nair, J. Electrochem. Sec. 145, 2113(1998)
  • [2]. S Mahanty, J. Vac. Sci. Tech. A Vac Surf Films15, 3060 (1997)
  • [3]. M D Jeroh, Global Journal of Science Frontier Research A 12, 1 (2012)
  • [4]. I Grozdanov, Semicond. Sci. Technol. 9, 1234 (1994)
  • [5]. M. Versal, Thin Solid Films 515, 7171 (2007)
  • [6]. S V Forgue, RCA Rev.12 335 (1951)
  • [7]. C Ghash, Thin Solid Films 60, 61 (1979)
  • [8]. J Grigas, Phys. Status Solidi (a) 37 K39 (1976)
  • [9]. E Montrimas, Thin Solid Films 34, 65 (1976)
  • [10]. J George, Solid States Commun. 33, 987 (1980)
  • [11]. P Arun, J. Materials Sci.31, 6507 (1996)
  • [12]. P E Lippens, Physical Review B, 56 13054 (1997)
  • [13]. A Kyono, Phys Chem Minerals 29, 254 (2002)
  • [14]. F I Ezeme, Turk j. Phys 31, 205 (2007)
  • [15]. B Krishnan, Applied Surface Science 254, 3200 ( 2008)
  • [16]. Y Li, Nanoscale Research Letters 8, 89 (2013)
  • [17]. C G Lazos, Journal of the Electrochemical Society 155,158(2008)
  • [18]. Q Dai, Nano Letters 12, 1021 (2012)
  • [19]. J Pan, Eur. J. Inorg. Chem. 5302 (2009)
  • [20]. I Watanabe, Journal of Non-Crystalline Solids 58, 35 (1983)
  • [21]. B Minceva-Sukarova, Journal of Molecular Structure 410-411, 267 (1997)

Sb2S3 İnce Filmlerin Yapısal, Optik ve Fotovoltaik Özelliklerinin İncelenmesi

Yıl 2017, Cilt: 38 Sayı: 3, 588 - 593, 30.09.2017

Sabit Horoz , Hüsnü Koç Ömer Şahin

https://doi.org/10.17776/csj.340520
Cited By: 7

Öz

Sb2S3 ince filmleri, amorf cam yüzeylerde oda
sıcaklığında kimyasal banyo depolaması (CBD) yöntemi ile hazırlandı.  Sb2S3 ince filmleri,
x-ışını kırınımı (XRD), Raman spektroskopisi, taramalı elektron mikroskobu
(SEM) ve UV-Vis spektroskopisi ile karakterize edildi.  XRD, depolanmış Sb2S3
ince filminin, tavlanmış Sb2S3 ince film ile
karşılaştırıldığında farklı bir yapıya sahip olduğunu ortaya koymuştur. Depolanmış
Sb2S3 ince filmi amorf yapılar gösterirken, Sb2S3
ince filmi 350oC'de N2 altında 1 saat tavlama işleminden
sonra poli kristal hale geldi.  UV-Vis
spektroskopisi kullanılarak Sb2S3 ince filmlerin bant
boşlukları karşılaştırıldı.  Tavlama
işleminden sonra Sb2S3 ince filminin spektral tepkisi
arttı.  Daha sonra Sb2S3
ince filmleri yarı iletken-hassaslaştırılmış TiO2 nanotel (NW) güneş
pilleri yapmak için kullanıldı. Güneş pili hücrelerinin kısa devre akım
yoğunluğu ve açık devre voltajı ile performansları araştırılmıştır. Optik ve
fotovoltaik ölçümlere dayanarak, tavlanmış Sb2S3 ince
filmlerin güneş pilleri teknolojilerini geliştirme konusunda umut verici
malzemeler olabileceğini düşünüyoruz.

Anahtar Kelimeler

Sb2S3 ince filmler kimyasal banyo depolanması yarıiletken-tabanlı güneş pilleri

Kaynakça

  • [1]. M T S Nair, J. Electrochem. Sec. 145, 2113(1998)
  • [2]. S Mahanty, J. Vac. Sci. Tech. A Vac Surf Films15, 3060 (1997)
  • [3]. M D Jeroh, Global Journal of Science Frontier Research A 12, 1 (2012)
  • [4]. I Grozdanov, Semicond. Sci. Technol. 9, 1234 (1994)
  • [5]. M. Versal, Thin Solid Films 515, 7171 (2007)
  • [6]. S V Forgue, RCA Rev.12 335 (1951)
  • [7]. C Ghash, Thin Solid Films 60, 61 (1979)
  • [8]. J Grigas, Phys. Status Solidi (a) 37 K39 (1976)
  • [9]. E Montrimas, Thin Solid Films 34, 65 (1976)
  • [10]. J George, Solid States Commun. 33, 987 (1980)
  • [11]. P Arun, J. Materials Sci.31, 6507 (1996)
  • [12]. P E Lippens, Physical Review B, 56 13054 (1997)
  • [13]. A Kyono, Phys Chem Minerals 29, 254 (2002)
  • [14]. F I Ezeme, Turk j. Phys 31, 205 (2007)
  • [15]. B Krishnan, Applied Surface Science 254, 3200 ( 2008)
  • [16]. Y Li, Nanoscale Research Letters 8, 89 (2013)
  • [17]. C G Lazos, Journal of the Electrochemical Society 155,158(2008)
  • [18]. Q Dai, Nano Letters 12, 1021 (2012)
  • [19]. J Pan, Eur. J. Inorg. Chem. 5302 (2009)
  • [20]. I Watanabe, Journal of Non-Crystalline Solids 58, 35 (1983)
  • [21]. B Minceva-Sukarova, Journal of Molecular Structure 410-411, 267 (1997)
Toplam 21 adet kaynakça vardır.

Ayrıntılar

Bölüm Makaleler
Yazarlar

Sabit Horoz

Hüsnü Koç

Ömer Şahin

Yayımlanma Tarihi 30 Eylül 2017
Gönderilme Tarihi 6 Nisan 2017
Kabul Tarihi 9 Mayıs 2017
Yayımlandığı Sayı Yıl 2017Cilt: 38 Sayı: 3

Kaynak Göster

APA Horoz, S., Koç, H., & Şahin, Ö. (2017). Investigation of Structural, Optical and Photovoltaic Properties of Sb2S3 Thin Films. Cumhuriyet Science Journal, 38(3), 588-593. https://doi.org/10.17776/csj.340520

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