Araştırma Makalesi
Yıl 2022,
Cilt: 9 Sayı: 4, 526 - 536, 31.12.2022
Öz
Anahtar Kelimeler
N-vinylcarbazole Benzyl Methacrylate (BZMA) Zinc Oxide Composite Optical Properties Thermal Analysis
Kaynakça
- Aqel, A., ALOthman, Z. A., Yusuf, K., Badjah-Hadj-Ahmed, A. Y., & Alwarthan, A. A. (2013). Preparation and evaluation of benzyl methacrylate monoliths for capillary chromatography. Journal of Chromatographic Science, 52(3), 1–10. doi:10.1093/chromsci/bmt011
- Barim, G. (2021). Synthesis and thermal degradation kinetics of poly(benzyl methacrylate)/graphite composites. Journal of Materials and Electronic Devices, 2(1), 30-35.
- Bashir, S., Awan, M. S., Farrukh, M. A., Naidu, R., Khan, S. A., Rafique, N., Ali, S., Hayat, I., Hussain, I. & Khan, M. Z. (2022). In-vivo (Albino Mice) and in-vitro Assimilation and Toxicity of Zinc Oxide Nanoparticles in Food Materials. International Journal of Nanomedicine, 17, 4073-4085. doi:10.2147/IJN.S372343
- Demirelli, K., Abubakar, A. M., Ahmad, A. A. & Bağcı, E. (2022a). The effect of end group and graphene on dielectric properties and thermal degradation of poly(benzyl methacrylate) prepared by ATRP method. Polymer Bulletin. doi:10.1007/s00289-021-04003-2
- Demirelli, K., Barim, E., Tuncer, H., Barim, G,. & Abubakar, A. M. (2022b). Synthesis and characterization of N-(2-acetylbenzofuran-3-yl)methacryl-amide and ethyl methacrylate copolymer/graphite oxide composites and study of their kinetic and electrical properties. Polymer Bulletin, 79, 4721-4743. doi:10.1007/s00289-021-03730-w
- Flynn, J. H., & Wall, L. A. (1966). General treatment of the thermogravimetry of polymers. Journal of Research of the National Bureau of Standards – A. Physics and Chemistry, 70A(6), 487-523. doi:10.6028/jres.070a.043
- Ghosh, D., & Biswas, M. (2009). NanoZnO initiated polymerization of N-vinylcarbazole (NVC) and evaluation of a poly(N-vinylcarbazole)–ZnO nanocomposite. Journal of Polymer Research, 16, 245-254. doi:10.1007/s10965-008-9223-1
- Ghosh, D., Sardar, P. S., Biswas, M., Mondal, A., & Mukherjee, N. (2010). Dielectric characteristics of poly(N-vinylcarbazole) and its nanocomposites with ZnO and acetylene black. Materials Chemistry and Physics, 123(1), 9-12. doi:10.1016/j.matchemphys.2010.04.019
- Goumri, M., Hatel, R., Ratier, B., & Baitoul, M. (2020). Optical and electrical properties of poly (N‑vinylcarbazole)/grapheneoxide nanocomposites for organic semiconductor devices. Applied Physics A, 126, 647. doi:10.1007/s00339-020-03812-y
- Haldar, I., Kundu, A., Biswas, M., & Nayak, A. (2011). Preparation and evaluation of a poly(N-vinylcarbazole)–Fe3O4 (PNVC–Fe3O4) nanocomposite. Materials Chemistry and Physics, 128(1-2), 256-264. doi:10.1016/j.matchemphys.2011.03.008
- Isusi, M., Rodríguez, M., Garay, T., Vilas, J. L. & León, L. M. (2006). Thermal properties of copolymers of N-vinylcarbazole with acrylic and methacrylic monomers. Journal of Macromolecular Science Part B, Physics, 41(2), 241-253. doi:10.1081/MB-120003083
- Kissinger, H. E. (1957). Reaction kinetics in differential thermal analysis. Analytical Chemistry, 29(11), 1702-1706. doi:10.1021/ac60131a045
- Li, H., Liu, J., Lin, L., Mu, Q., Sun, X., & Liu, X. (2014). Preparation and characterization of UV-curable copolymers containing alkali soluble carboxyl pendant for negative photoresist. Polymer Science Series B, 56, 855-862. doi:10.1134/S1560090414770024
- Liu, X., Dai, X., Boyko, W., Fleischer, A. S., & Feng, G. (2022). Surfactant-mediated synthesis of monodisperse Poly(benzyl methacrylate)-based copolymer microspheres. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 633(Part 2), 127870. doi:10.1016/j.colsurfa.2021.127870
- Ozawa, T. (1965). A new method of analyzing thermogravimetric data. Bulletin of the Chemical Society of Japan, 38(11), 1881-1886. doi:10.1246/bcsj.38.1881
- Pearson, J. M., & Stolka, M. (1981). Poly(N-vinylcarbazole). Gordon and Breach Science Publishers.
- Reyna-Gonzalez, J. M., Roquero P., & Rivera, E. (2009). A Comparative investigation between poly(N-vinylcarbazole) and poly(3,6-N-vinylcarbazole): spectroscopy, conductivity, thermal and optical Properties. Designed Monomers and Polymers, 12(3), 233-245. doi:10.1163/156855509X436058
- Saçak, M. (2012). Polimer Kimyası. Ankara, Gazi Kitabevi.
- Ueno, K. (2018). Soft materials based on colloidal self-assembly in ionic liquids. Polymer Journal, 50, 951-958. doi:10.1038/s41428-018-0083-1
- Worzakowska, M. (2016). Starch-g-poly(benzyl methacrylate) copolymers, Characterization and thermal properties. Journal of Thermal Analysis and Calorimetry, 124, 1309-1318. doi:10.1007/s10973-016-5328-7
- Yakuphanoglu, F., Yahia, I. S., Barim, G., & Şenkal, B. F. (2010). Double-walled carbon nanotube/polymer composites: Electrical properties under dc and ac fields. Synthetic Metals, 160(15-16), 1718-1726. doi:10.1016/j.synthmet.2010.06.007
Synthesis, Characterization, Optical and Thermal Properties of P(NVC-co-BZMA) Copolymer and Its ZnO Composites
Öz
Recent studies have paid particular attention to polymer-nanoparticle composite materials considering they have a number of interesting properties, which include optical, thermal, electrical, and others (Reyna-Gonzalez et al., 2009; Yakuphanoglu et al., 2010). In this study, a free radical polymerization process was used to create a copolymer of N-vinylcarbazole (NVC) and benzyl methacrylate (BZMA) at 25–75 mol% each. The procedure was conducted at 70°C with azobisisobutyronitrile (AIBN) acting as the initiator. Nano zinc oxide powders were then added to composites at three different ratios of 5%, 10%, and 15% weight of the copolymer. In order to better understand the structures of the P(NVC-co-BZMA) and its composites, FT-IR, 1H NMR, and UV spectroscopic techniques were also implemented. The optical characteristics of both the pure copolymer and its composites were examined. In the visible region, the composite containing 15% nano ZnO had the highest optical absorbance value. Additionally, the thermal behaviours of the composites and copolymers were analysed.
Anahtar Kelimeler
N-vinylcarbazole Benzyl Methacrylate (BZMA) Zinc Oxide Composite Optical Properties Thermal Analysis
Kaynakça
- Aqel, A., ALOthman, Z. A., Yusuf, K., Badjah-Hadj-Ahmed, A. Y., & Alwarthan, A. A. (2013). Preparation and evaluation of benzyl methacrylate monoliths for capillary chromatography. Journal of Chromatographic Science, 52(3), 1–10. doi:10.1093/chromsci/bmt011
- Barim, G. (2021). Synthesis and thermal degradation kinetics of poly(benzyl methacrylate)/graphite composites. Journal of Materials and Electronic Devices, 2(1), 30-35.
- Bashir, S., Awan, M. S., Farrukh, M. A., Naidu, R., Khan, S. A., Rafique, N., Ali, S., Hayat, I., Hussain, I. & Khan, M. Z. (2022). In-vivo (Albino Mice) and in-vitro Assimilation and Toxicity of Zinc Oxide Nanoparticles in Food Materials. International Journal of Nanomedicine, 17, 4073-4085. doi:10.2147/IJN.S372343
- Demirelli, K., Abubakar, A. M., Ahmad, A. A. & Bağcı, E. (2022a). The effect of end group and graphene on dielectric properties and thermal degradation of poly(benzyl methacrylate) prepared by ATRP method. Polymer Bulletin. doi:10.1007/s00289-021-04003-2
- Demirelli, K., Barim, E., Tuncer, H., Barim, G,. & Abubakar, A. M. (2022b). Synthesis and characterization of N-(2-acetylbenzofuran-3-yl)methacryl-amide and ethyl methacrylate copolymer/graphite oxide composites and study of their kinetic and electrical properties. Polymer Bulletin, 79, 4721-4743. doi:10.1007/s00289-021-03730-w
- Flynn, J. H., & Wall, L. A. (1966). General treatment of the thermogravimetry of polymers. Journal of Research of the National Bureau of Standards – A. Physics and Chemistry, 70A(6), 487-523. doi:10.6028/jres.070a.043
- Ghosh, D., & Biswas, M. (2009). NanoZnO initiated polymerization of N-vinylcarbazole (NVC) and evaluation of a poly(N-vinylcarbazole)–ZnO nanocomposite. Journal of Polymer Research, 16, 245-254. doi:10.1007/s10965-008-9223-1
- Ghosh, D., Sardar, P. S., Biswas, M., Mondal, A., & Mukherjee, N. (2010). Dielectric characteristics of poly(N-vinylcarbazole) and its nanocomposites with ZnO and acetylene black. Materials Chemistry and Physics, 123(1), 9-12. doi:10.1016/j.matchemphys.2010.04.019
- Goumri, M., Hatel, R., Ratier, B., & Baitoul, M. (2020). Optical and electrical properties of poly (N‑vinylcarbazole)/grapheneoxide nanocomposites for organic semiconductor devices. Applied Physics A, 126, 647. doi:10.1007/s00339-020-03812-y
- Haldar, I., Kundu, A., Biswas, M., & Nayak, A. (2011). Preparation and evaluation of a poly(N-vinylcarbazole)–Fe3O4 (PNVC–Fe3O4) nanocomposite. Materials Chemistry and Physics, 128(1-2), 256-264. doi:10.1016/j.matchemphys.2011.03.008
- Isusi, M., Rodríguez, M., Garay, T., Vilas, J. L. & León, L. M. (2006). Thermal properties of copolymers of N-vinylcarbazole with acrylic and methacrylic monomers. Journal of Macromolecular Science Part B, Physics, 41(2), 241-253. doi:10.1081/MB-120003083
- Kissinger, H. E. (1957). Reaction kinetics in differential thermal analysis. Analytical Chemistry, 29(11), 1702-1706. doi:10.1021/ac60131a045
- Li, H., Liu, J., Lin, L., Mu, Q., Sun, X., & Liu, X. (2014). Preparation and characterization of UV-curable copolymers containing alkali soluble carboxyl pendant for negative photoresist. Polymer Science Series B, 56, 855-862. doi:10.1134/S1560090414770024
- Liu, X., Dai, X., Boyko, W., Fleischer, A. S., & Feng, G. (2022). Surfactant-mediated synthesis of monodisperse Poly(benzyl methacrylate)-based copolymer microspheres. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 633(Part 2), 127870. doi:10.1016/j.colsurfa.2021.127870
- Ozawa, T. (1965). A new method of analyzing thermogravimetric data. Bulletin of the Chemical Society of Japan, 38(11), 1881-1886. doi:10.1246/bcsj.38.1881
- Pearson, J. M., & Stolka, M. (1981). Poly(N-vinylcarbazole). Gordon and Breach Science Publishers.
- Reyna-Gonzalez, J. M., Roquero P., & Rivera, E. (2009). A Comparative investigation between poly(N-vinylcarbazole) and poly(3,6-N-vinylcarbazole): spectroscopy, conductivity, thermal and optical Properties. Designed Monomers and Polymers, 12(3), 233-245. doi:10.1163/156855509X436058
- Saçak, M. (2012). Polimer Kimyası. Ankara, Gazi Kitabevi.
- Ueno, K. (2018). Soft materials based on colloidal self-assembly in ionic liquids. Polymer Journal, 50, 951-958. doi:10.1038/s41428-018-0083-1
- Worzakowska, M. (2016). Starch-g-poly(benzyl methacrylate) copolymers, Characterization and thermal properties. Journal of Thermal Analysis and Calorimetry, 124, 1309-1318. doi:10.1007/s10973-016-5328-7
- Yakuphanoglu, F., Yahia, I. S., Barim, G., & Şenkal, B. F. (2010). Double-walled carbon nanotube/polymer composites: Electrical properties under dc and ac fields. Synthetic Metals, 160(15-16), 1718-1726. doi:10.1016/j.synthmet.2010.06.007
Toplam 21 adet kaynakça vardır.
Ayrıntılar
| Birincil Dil | İngilizce |
|---|---|
| Bölüm | Kimya |
| Yazarlar | |
| Yayımlanma Tarihi | 31 Aralık 2022 |
| Gönderilme Tarihi | 5 Kasım 2022 |
| Yayımlandığı Sayı | Yıl 2022 Cilt: 9 Sayı: 4 |
