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Alkolsüz İçecekler ve Gıda Ürünlerinde Tartrazinin Özütlenmesi için Basit ve Ucuz Ultrason Destekli Mikroekstraksiyon Prosedürü

Yıl 2019, Cilt: 40 Sayı: 2, 275 - 284, 30.06.2019

Nail Altunay

https://doi.org/10.17776/csj.499721
Cited By: 3

Öz

Bu çalışmada, basit ve
ucuz ultrason destekli iyonik sıvı bazlı yüzer organik damlacıklar
mikroekstraksiyonu (UA-IL-FODME), sentetik yiyecek boyalarının (tartrazin),
alkolsüz içeceklerde ve gıda ürünlerinde spektrofotometrik olarak belirlenmesi
için önerilmiştir.1-Oktil-3-metilimidazolyum tetrafloroborat [C8MIM] [BF4] ve
1-oktanol sırasıyla ekstraksiyon çözücü ve dağıtıcı çözücü olarak
kullanılmıştır. Yöntem, pH 5.5'te tarrazin 'in iyonik faza ultrasonik etki
yardımıyla özütlenmesine dayanır. Bazı deneysel değişkenler (pH, iyonik sıvı
miktarı, dispersiv çözücü çeşidi ve hacmi ve ultrasonik koşullar) çalışıldı ve
ayrıntılı olarak optimize edildi. Optimum koşullarda, yöntemin bazı analitik
parametreleri aşağıda özetlenmiştir. Çalışma aralığı, seçme sınırı, ön
konsantrasyon faktörü, geri kazanma yüzdesi ve %BBS değerleri sırasıyla 10-700
µg L-1, 3.2 µg L-1, 75, % 94.7-104.7 ve % 2.7 idi. Kapsamlı validasyon
çalışmalarının ardından, önerilen yöntem, alkolsüz içecekler ve gıda
maddelerinde tartrazininekstraksiyonu ve tayinine başarıyla uygulanmıştır.

Kaynakça

  • [1] Amin, K. A., Hameid, H.A. and Elsttar, A.A. Effect of food azo dyes tartrazine and carmoisine on biochemical parameters related to renal, hepatic function and oxidative stress biomarkers in young male rats. Food Chem. Toxicol., 48(10) (2010)2994-2999.
  • [2] Ghoreishi, S.M., Behpour, M. and Golestaneh M. Simultaneous determination of sunset yellow and tartrazine in soft drinks using gold nanoparticles carbon paste electrode. Food chem., 132(1) (2012) 637-641.
  • [3] Kucharska, M. and Grabka, J. A review of chromatographic methods for determination of synthetic food dyes. Talanta, 80(3) (2010) 1045-1051.
  • [4] Soponar, F., Moţ, A.C. and Sârbu, C. Quantitative determination of some food dyes using digital processing of images obtained by thin-layer chromatography. J. Chromatogr. A, 1188(2) (2008) 295-300.
  • [5] Hajimahmoodi, M., Afsharimanesh, M., Moghaddam, G., Sadeghi, N., Oveisi, M.R., Jannat, B. and Kanan, H. Determination of eight synthetic dyes in foodstuffs by green liquid chromatography. Food Additives & Contaminants: Part A, 30(5) (2013) 780-785.
  • [6] El-Sheikh, A.H. and Al-Degs, Y.S. Spectrophotometric determination of food dyes in soft drinks by second order multivariate calibration of the absorbance spectra-pH data matrices. Dyes Pigm., 97(2) (2013) 330-339.
  • [7] Alves, S.P., Brum, D.M., Andrade, E.C.B. and Netto, A.D.P. Determination of synthetic dyes in selected foodstuffs by high performance liquid chromatography with UV-DAD detection. Food Chem., 107(1) (2008) 489-496.
  • [8] Andrade, F.I., Guedes, M.I.F., Vieira, Í.G.P., Mendes, F.N.P., Rodrigues, P.A.S., Maia, C.S.C. and Matos L. Determination of synthetic food dyes in commercial soft drinks by TLC and ion-pair HPLC. Food Chem., 157 (2014)193-198.
  • [9] Li, X.Q., Zhang, Q.H., Ma, K., Li, H.M. and Guo, Z. Identification and determination of 34 water-soluble synthetic dyes in foodstuff by high performance liquid chromatography–diode array detection–ion trap time-of-flight tandem mass spectrometry. Food Chem., 182(2015) 316-326.
  • [10] Asfaram, A., Ghaedi, M. and Goudarzi, A. Optimization of ultrasound-assisted dispersive solid-phase microextraction based on nanoparticles followed by spectrophotometry for the simultaneous determination of dyes using experimental design. Ultrason. Sonochem., 32(2016) 407-417.
  • [11] Song, X., Shi, Z., Tan, X., Zhang, S., Liu, G. and Wu, K. One-step solvent exfoliation of graphite to produce a highly-sensitive electrochemical sensor for tartrazine. Sens. Actuators, B., 197(2014) 104-108.
  • [12] Ma, M., Luo, X., Chen, B., Su, S. and Yao S. Simultaneous determination of water-soluble and fat-soluble synthetic colorants in foodstuff by high-performance liquid chromatography–diode array detection–electrospray mass spectrometry. Journal of Chromatography A, 1103(1) (2006) 170-176.
  • [13] Qi, P., Zeng, T., Wen, Z., Liang, X. and Zhang, X. Interference-free simultaneous determination of Sudan dyes in chili foods using solid phase extraction coupled with HPLC–DAD. Food Chem., 125(4) (2011) 1462-1467.
  • [14] Long, C., Mai, Z., Yang, X., Zhu, B., Xu, X., Huang, X. and Zou X. A new liquid–liquid extraction method for determination of 6 azo-dyes in chilli products by high-performance liquid chromatography. Food Chem., 126(3) (2011) 1324-1329.
  • [15] Altunay, N., Elik, A., Bulutlu, C. and Gürkan, R. Application of simple, fast and eco-friendly ultrasound-assisted-cloud point extraction for pre-concentration of zinc, nickel and cobalt from foods and vegetables prior to their flame atomic absorption spectrometric determinations. International journal of environmental analytical chemistry, 98(7) (2018) 655-675.
  • [16] Yan, H., Qiao, J., Pei, Y., Long, T., Ding, W. and Xie, K. Molecularly imprinted solid-phase extraction coupled to liquid chromatography for determination of Sudan dyes in preserved beancurds. Food Chem., 132(1) (2012) 649-654.
  • [17] Chen, D., Li, X., Tao, Y., Pan, Y., Wu, Q., Liu, Z. and Yuan, Z. Development of a liquid chromatography–tandem mass spectrometry with ultrasound-assisted extraction method for the simultaneous determination of sudan dyes and their metabolites in the edible tissues and eggs of food-producing animals. Journal of Chromatography B, 939 (2013) 45-50.
  • [18] Elik, A. Ultrasonic-assisted leaching of trace metals from sediments as a function of pH. Talanta, 71(2) (2007) 790-794.
  • [19] Altunay, N., Elik, A. and Gürkan, R. Extraction and reliable determination of acrylamide from thermally processed foods using ionic liquid-based ultrasound-assisted selective microextraction combined with spectrophotometry. Food Additives & Contaminants: Part A, 35(2) (2018) 222-232.
  • [20] Elik, A., Altunay, N. and Gürkan, R. Microextraction and preconcentration of Mn and Cd from vegetables, grains and nuts prior to their determination by flame atomic absorption spectrometry using room temperature ionic liquid. J. Mol. Liq., 247 (2017) 262-268.
  • [21] Elik, A., Altunay, N. and Gürkan, R. Ultrasound-Assisted Low-Density Solvent-Based Dispersive Liquid–Liquid Microextraction Coupled to Spectrophotometry for the Determination of Low Levels of Histamine in Fish and Meat Products. Food Anal. Methods., 12(2) (2019) 489-502.
  • [22] Altunay, N., Elik, A. and Gürkan, R. Extraction and reliable determination of acrylamide from thermally processed foods using ionic liquid-based ultrasound-assisted selective microextraction combined with spectrophotometry. Food Additives & Contaminants: Part A, 35(2) (2018) 222-232.
  • [23] Wu, H., Guo, J.B., Du, L.M., Tian, H., Hao, C.X., Wang, Z.F. and Wang J.Y. A rapid shaking-based ionic liquid dispersive liquid phase microextraction for the simultaneous determination of six synthetic food colourants in soft drinks, sugar-and gelatin-based confectionery by high-performance liquid chromatography. Food Chem., 141(1) (2013)182-186.
  • [24] Gan, T., Sun, J.Y., Meng, W., Song, L. and Zhang, Y.X. Electrochemical sensor based on graphene and mesoporous TiO2 for the simultaneous determination of trace colourants in food. Food Chem., 141(2013) 3731–3737.
  • [25] El-Sheikh, A.H. and Al-Degs, Y.S. Spectrophotometric determination of food dyes in soft drinks by second order multivariate calibration of the absorbance spectra-pH data matrices. Dyes Pigm., 97 (2013) 330–339.
  • [26] Bazregar, M., Rajabi, M., Yamini, Y. and Asghari A. In-tube electro-membrane extraction with a sub-microliter organic solvent consumption as an efficient technique for synthetic food dyes determination in foodstuff samples. Journal of Chromatography A, 1410 (2015) 35-43.
  • [27] Nambiar, A.P., Sanyal, M. and Shrivastav, P.S. Performance evaluation and thermodynamic studies for the simultaneous cloud point extraction of erythrosine and tartrazine using mixed micelles in food samples. Food Anal. Methods., 10(2017) 3471-3480.

A Simple and Cheap Ultrasound-Assisted Microextraction Procedure For Extraction of Tartrazine in Soft Drinks and Foodstuff

Yıl 2019, Cilt: 40 Sayı: 2, 275 - 284, 30.06.2019

Nail Altunay

https://doi.org/10.17776/csj.499721
Cited By: 3

Öz

In this study, a simple and cheap ultrasound-assisted ionic liquid-based
floating organic droplets microextraction (UA-IL-FODME) has been proposed for
spectrophotometric determination of synthetic food dye (tartrazine) in soft
drinks and food samples. 1-Octyl-3-methylimidazolium tetrafluoroborate
[C8MIM][BF4] and 1-octanol were used as the extraction solvent and dispersant
solvent, respectively. The method is based on extracting the tarrazine to the
ionic phase with the help of ultrasonic effect at pH 5.5. Some experimental
variables (pH, ionic liquid amount, type and volume of dispersive solvent, and
ultrasonic conditions) were studied and optimized in detail. In optimum
conditions, some analytical parameters of the method were as follows. Operating
range, limit of detection, preconcentration factor, recovery % and RSD % values
were 10-700 µg L-1, 3.2 µg L-1, 75, 94.7-104.7% and 2.7%, respectively.
Following comprehensive validation studies, the recommended method was
successfully applied to the extravasation and determination of tartrazine in
soft drinks and foodstuff.

Anahtar Kelimeler

Floating organic droplets Ionic liquid Ultrasound Tartrazine Soft drinks Foodstuff

Kaynakça

  • [1] Amin, K. A., Hameid, H.A. and Elsttar, A.A. Effect of food azo dyes tartrazine and carmoisine on biochemical parameters related to renal, hepatic function and oxidative stress biomarkers in young male rats. Food Chem. Toxicol., 48(10) (2010)2994-2999.
  • [2] Ghoreishi, S.M., Behpour, M. and Golestaneh M. Simultaneous determination of sunset yellow and tartrazine in soft drinks using gold nanoparticles carbon paste electrode. Food chem., 132(1) (2012) 637-641.
  • [3] Kucharska, M. and Grabka, J. A review of chromatographic methods for determination of synthetic food dyes. Talanta, 80(3) (2010) 1045-1051.
  • [4] Soponar, F., Moţ, A.C. and Sârbu, C. Quantitative determination of some food dyes using digital processing of images obtained by thin-layer chromatography. J. Chromatogr. A, 1188(2) (2008) 295-300.
  • [5] Hajimahmoodi, M., Afsharimanesh, M., Moghaddam, G., Sadeghi, N., Oveisi, M.R., Jannat, B. and Kanan, H. Determination of eight synthetic dyes in foodstuffs by green liquid chromatography. Food Additives & Contaminants: Part A, 30(5) (2013) 780-785.
  • [6] El-Sheikh, A.H. and Al-Degs, Y.S. Spectrophotometric determination of food dyes in soft drinks by second order multivariate calibration of the absorbance spectra-pH data matrices. Dyes Pigm., 97(2) (2013) 330-339.
  • [7] Alves, S.P., Brum, D.M., Andrade, E.C.B. and Netto, A.D.P. Determination of synthetic dyes in selected foodstuffs by high performance liquid chromatography with UV-DAD detection. Food Chem., 107(1) (2008) 489-496.
  • [8] Andrade, F.I., Guedes, M.I.F., Vieira, Í.G.P., Mendes, F.N.P., Rodrigues, P.A.S., Maia, C.S.C. and Matos L. Determination of synthetic food dyes in commercial soft drinks by TLC and ion-pair HPLC. Food Chem., 157 (2014)193-198.
  • [9] Li, X.Q., Zhang, Q.H., Ma, K., Li, H.M. and Guo, Z. Identification and determination of 34 water-soluble synthetic dyes in foodstuff by high performance liquid chromatography–diode array detection–ion trap time-of-flight tandem mass spectrometry. Food Chem., 182(2015) 316-326.
  • [10] Asfaram, A., Ghaedi, M. and Goudarzi, A. Optimization of ultrasound-assisted dispersive solid-phase microextraction based on nanoparticles followed by spectrophotometry for the simultaneous determination of dyes using experimental design. Ultrason. Sonochem., 32(2016) 407-417.
  • [11] Song, X., Shi, Z., Tan, X., Zhang, S., Liu, G. and Wu, K. One-step solvent exfoliation of graphite to produce a highly-sensitive electrochemical sensor for tartrazine. Sens. Actuators, B., 197(2014) 104-108.
  • [12] Ma, M., Luo, X., Chen, B., Su, S. and Yao S. Simultaneous determination of water-soluble and fat-soluble synthetic colorants in foodstuff by high-performance liquid chromatography–diode array detection–electrospray mass spectrometry. Journal of Chromatography A, 1103(1) (2006) 170-176.
  • [13] Qi, P., Zeng, T., Wen, Z., Liang, X. and Zhang, X. Interference-free simultaneous determination of Sudan dyes in chili foods using solid phase extraction coupled with HPLC–DAD. Food Chem., 125(4) (2011) 1462-1467.
  • [14] Long, C., Mai, Z., Yang, X., Zhu, B., Xu, X., Huang, X. and Zou X. A new liquid–liquid extraction method for determination of 6 azo-dyes in chilli products by high-performance liquid chromatography. Food Chem., 126(3) (2011) 1324-1329.
  • [15] Altunay, N., Elik, A., Bulutlu, C. and Gürkan, R. Application of simple, fast and eco-friendly ultrasound-assisted-cloud point extraction for pre-concentration of zinc, nickel and cobalt from foods and vegetables prior to their flame atomic absorption spectrometric determinations. International journal of environmental analytical chemistry, 98(7) (2018) 655-675.
  • [16] Yan, H., Qiao, J., Pei, Y., Long, T., Ding, W. and Xie, K. Molecularly imprinted solid-phase extraction coupled to liquid chromatography for determination of Sudan dyes in preserved beancurds. Food Chem., 132(1) (2012) 649-654.
  • [17] Chen, D., Li, X., Tao, Y., Pan, Y., Wu, Q., Liu, Z. and Yuan, Z. Development of a liquid chromatography–tandem mass spectrometry with ultrasound-assisted extraction method for the simultaneous determination of sudan dyes and their metabolites in the edible tissues and eggs of food-producing animals. Journal of Chromatography B, 939 (2013) 45-50.
  • [18] Elik, A. Ultrasonic-assisted leaching of trace metals from sediments as a function of pH. Talanta, 71(2) (2007) 790-794.
  • [19] Altunay, N., Elik, A. and Gürkan, R. Extraction and reliable determination of acrylamide from thermally processed foods using ionic liquid-based ultrasound-assisted selective microextraction combined with spectrophotometry. Food Additives & Contaminants: Part A, 35(2) (2018) 222-232.
  • [20] Elik, A., Altunay, N. and Gürkan, R. Microextraction and preconcentration of Mn and Cd from vegetables, grains and nuts prior to their determination by flame atomic absorption spectrometry using room temperature ionic liquid. J. Mol. Liq., 247 (2017) 262-268.
  • [21] Elik, A., Altunay, N. and Gürkan, R. Ultrasound-Assisted Low-Density Solvent-Based Dispersive Liquid–Liquid Microextraction Coupled to Spectrophotometry for the Determination of Low Levels of Histamine in Fish and Meat Products. Food Anal. Methods., 12(2) (2019) 489-502.
  • [22] Altunay, N., Elik, A. and Gürkan, R. Extraction and reliable determination of acrylamide from thermally processed foods using ionic liquid-based ultrasound-assisted selective microextraction combined with spectrophotometry. Food Additives & Contaminants: Part A, 35(2) (2018) 222-232.
  • [23] Wu, H., Guo, J.B., Du, L.M., Tian, H., Hao, C.X., Wang, Z.F. and Wang J.Y. A rapid shaking-based ionic liquid dispersive liquid phase microextraction for the simultaneous determination of six synthetic food colourants in soft drinks, sugar-and gelatin-based confectionery by high-performance liquid chromatography. Food Chem., 141(1) (2013)182-186.
  • [24] Gan, T., Sun, J.Y., Meng, W., Song, L. and Zhang, Y.X. Electrochemical sensor based on graphene and mesoporous TiO2 for the simultaneous determination of trace colourants in food. Food Chem., 141(2013) 3731–3737.
  • [25] El-Sheikh, A.H. and Al-Degs, Y.S. Spectrophotometric determination of food dyes in soft drinks by second order multivariate calibration of the absorbance spectra-pH data matrices. Dyes Pigm., 97 (2013) 330–339.
  • [26] Bazregar, M., Rajabi, M., Yamini, Y. and Asghari A. In-tube electro-membrane extraction with a sub-microliter organic solvent consumption as an efficient technique for synthetic food dyes determination in foodstuff samples. Journal of Chromatography A, 1410 (2015) 35-43.
  • [27] Nambiar, A.P., Sanyal, M. and Shrivastav, P.S. Performance evaluation and thermodynamic studies for the simultaneous cloud point extraction of erythrosine and tartrazine using mixed micelles in food samples. Food Anal. Methods., 10(2017) 3471-3480.
Toplam 27 adet kaynakça vardır.

Ayrıntılar

Birincil Dil İngilizce
Bölüm Natural Sciences
Yazarlar

Nail Altunay 0000-0001-9053-7570

Yayımlanma Tarihi 30 Haziran 2019
Gönderilme Tarihi 20 Aralık 2018
Kabul Tarihi 22 Şubat 2019
Yayımlandığı Sayı Yıl 2019Cilt: 40 Sayı: 2

Kaynak Göster

APA Altunay, N. (2019). A Simple and Cheap Ultrasound-Assisted Microextraction Procedure For Extraction of Tartrazine in Soft Drinks and Foodstuff. Cumhuriyet Science Journal, 40(2), 275-284. https://doi.org/10.17776/csj.499721

Cited By

Synthetic Food Dyes – Some Aspects Of Use And Methods Of Determination
Methods and Objects of Chemical Analysis
L.O. Dubenska
https://doi.org/10.17721/moca.2020.5-20
Ultrasonic-assisted cloud point microextraction and spectrophotometric determination of Ponceau 4R in various beverage samples using Non-ionic surfactant PONPE 7.5
Food Additives & Contaminants: Part A
Serhan Meral
https://doi.org/10.1080/19440049.2021.1873427
A novel ultrasonication-assisted deep eutectic solvent microextraction procedure for tartrazine at trace levels from environmental samples
Journal of the Iranian Chemical Society
Mustafa Soylak
https://doi.org/10.1007/s13738-019-01781-5