Abstract
Removal
of metals and heavy metals from industrial wastewaters is a serious concern for
water systems. In this study, environmentally friendly natural polymer coated,
cost-effective, easy to operate HA/QR magnetic nanoparticles were suggested to
overcome this problem, for the first time in literature. Fe3O4
magnetic nanoparticles were synthesized with co-precipitation technique and a
core-shell structure was obtained with humic acid sodium salt (HA) solution. At
the second step of the procedure, synthesized magnetic nanoparticles were
coated with quercetin solution. Scanning electron microscopy (SEM), X-Ray diffraction
(XRD) and particle size analyses were performed to enlighten and characterize
the structure. The newly synthesized nanoparticles were used for the batch-wise
adsorption of copper and nickel metals, successfully. Maximum adsorption
capacities were calculated as 14.61 mg/g for copper and 28.30 mg/g using 0.03 g
adsorbents, at pH=7. Adsorption isotherms were evaluated and it was concluded
that adsorption equilibrium fitted to both Langmuir and Freundlich isotherm
models, better correlated with Langmuir isotherm model.
References
- Ashish B., Naeti K., Himanshu K., Copper toxicity: A comprehensive study, Res. J. Recent Sci. 2 (2013) 58-67.
- Azouaou N., Sadaoi Z., Mokaddem H., Removal of cadmium from aqueous solution by adsorption on vegetable wastes, O. J. App. 24 (2008) 4638-4643.
- Liu D., Li Z., Zhu Y., Kumar R., Recycled chitosan nanofibril as an effective Cu(II), Pb(II), and Cd(II) ionic chelating agent: adsorption and desorption performance, Carbohydr. Polym. 111 (2014) 469-476.
- Liphadzi M. S., Kirkham M. B., Preperation of magnetic carboxy methyl chitosan nanoparticles for adsorption of heavy metal ions, S. Afr. J. Bot. 72 (2006) 391-397.
- Chang Y. C., Chen D. H., Preparation and adsorption properties of monodisperse chitosan-bound Fe3O4 magnetic nanoparticles for removal of Cu(II) ions, J. Colloid Interface Sci. 283 (2005) 446- 451.
- Savage N., Diallo M. S., Nanomaterials and water purification: opportunities and challenges, J. Nanopart. Res. 7 (2005) 331-342.
- Erdem E., Karapınar N., Donat R., The removal of heavy metal cations by natural zeolites, J. Colloid Interface Sci. 284 (2004) 309-314.
- Shatialam A. M., Al-Harthy A., Al-Zawhry A., Feed water pretreatment in RO systems in middleeast desalination 150 (2002) 235-245.
- Murthy Z. V. P., Chaudhai L. B., Seperation of binary heavy metals from aqueous solutions by nanofiltration and characterization of the membrane using Spiegler-Kedem model, Chem. Eng. J. 150 (2008) 181-187.
- Fenglian F., Wang Q., Removal of heavy metal ions from wastewaters, a review, J. Environ. Manage. 92 (2011) 407-418.
- Yean S., Cong L., Yavuz J. T., Yu M., Effect of material particle size on adsorption and desorption of arsenite and arsenate, J. Mater. Res. Technol. 20 (2005) 3255-3264.
- Shen Y. F., Tang J., Me Z. N., Wang Y. D., Ren Y., Zou L., Preperation and application of Fe3O4 nanoparticles for wastewater purification, Sep. Purif. Technol. 68 (2009) 312-319.
- Ozdemir F. A., Demirata B., Apak R., Adsorptive removal of methylene blue from simulated dyeing wastewater with melamine-formaldehyde-urea resin, J. Appl. Polym. Sci. 112 (2009) 3442-3448.
- Ajenifuja E., Ajao J. A. , Ajayi E. O. B., Adsorption isotherm studies of Cu (II) and Co (II) in high concentration Aaqueous solutions on photocatalytically modified diatomaceous ceramic adsorbents, Appl. Water Sci. 7 (2017) 3793-3801.
- McKay G., Otterburn M. S., Sweenay A. G., The removal of color from effluent using various adsorbents, Water Res. 14 (1980) 15-20.
- Ozer A., Pirincci H. B., The adsorption of Cd(II) ions on sulphuric acid-treated wheat Bran, J. Hazard. Mater. 137 (2006) 849-855.
- Du S., Lou Y., Zou F., Li X., Li D., Polydopamine-coated Fe3O4 nanoparticles as synergistic redox mediators for catalytic reduction of azo dyes, NANO (2017)12-21.
- Wan Q., Huang Q., Liu M., Xu D., Huang H., Zhang Z., Wei Y., Aggregation-induced emission active luminescent polymeric nanoparticles: Non-covalent fabrication methodologies and biomedical applications 9 (2017) 145-160.
- Ghaemi N., A new approach to copper ion removal from water by polymeric nanocomposite membrane embedded with -alumina nanoparticles, Appl. Surf. Sci. 364 (2016) 221-228.
- Fouldagar M., Behestiti M., Salozyan H., Single and binary adsortpon of nickel and copper from aqueous solution by -alumina nanoparticle equilibrium and kinetic modelling, J. Mol. Liq. 211 (2015) 1060-1073.
- Thanh D. N., Novak P., Vejpravova J., Vu H. N., Lederer J., Munshi T., Removal of copper and nickel from water using nanocomposite of magnetic hydroxyapatite nanorods, J. Magn. Magn. Mater. 456 (2018) 451-460.
Hümik Asit/Kuversetin Kaplı Fe3O4 Manyetik Nanoparçacıklar ile Cu2+ ve Ni2+ Metallerinin Adsorpsiyon Yöntemiyle Giderimi
Abstract
Endüstriyel
atıksulardan metal ya da ağır metal giderilmesi su sistemleri için ciddi
sorunlar oluşturabilmektedir. Bu çalışmada, bu sorunları tamamen gidermek ya da
en aza indirmek için bir çözüm yolu önerildi. Çalışma kapsamında, literatürde
ilk kez, doğal polimer olan hümik asit sodyum tuzu ile kaplı olduğu için çevre
dostu olan, ekonomik ve manyetik özelliğinden dolayı kullanım kolaylığı
sağlayan HA/QR manyetik nanoparçacıklar sentezlendi. Sentez prosedürünün
birinci adımında birlikte çöktürme tekniğiyle Fe3O4 manyetik
nanoparçacıklar sentezlendi ve çekirdek-kabuk (core-shell) modeline uygun
olarak hümik asit çözeltisi ile muamale edilerek kaplandı. İkinci adımda ise,
sentezlenen partiküller kuersetin çözeltisi ile kaplandı. Oluşan nano yapının
aydınlatılması için SEM (Taramalı Elektron Mikroskopisi), X ışını kırınımı
(XRD) ve parçacık boyut analizi teknikleri kullanıldı. Yeni sentezlenen
parçacıklar Cu2+ ve Ni2+ metallerinin giderimi için adsorban olarak
başarıyla kullanıldı. pH=7 değerinde 0.03 g adsorban kullanılarak hesaplanan
adsorpsiyon kapasiteleri Cu2+ için 14.61 mg/g; Ni2+ için 28.30 mg/g olarak hesaplandı. Adsorpsiyon
izotermleri değerlendirildiğinde, elde edilen adsorpsiyon izoterm eğrisinin hem
Langmuir hem Freundlich modeline uyum sağladığı gözlemlendi.
References
- Ashish B., Naeti K., Himanshu K., Copper toxicity: A comprehensive study, Res. J. Recent Sci. 2 (2013) 58-67.
- Azouaou N., Sadaoi Z., Mokaddem H., Removal of cadmium from aqueous solution by adsorption on vegetable wastes, O. J. App. 24 (2008) 4638-4643.
- Liu D., Li Z., Zhu Y., Kumar R., Recycled chitosan nanofibril as an effective Cu(II), Pb(II), and Cd(II) ionic chelating agent: adsorption and desorption performance, Carbohydr. Polym. 111 (2014) 469-476.
- Liphadzi M. S., Kirkham M. B., Preperation of magnetic carboxy methyl chitosan nanoparticles for adsorption of heavy metal ions, S. Afr. J. Bot. 72 (2006) 391-397.
- Chang Y. C., Chen D. H., Preparation and adsorption properties of monodisperse chitosan-bound Fe3O4 magnetic nanoparticles for removal of Cu(II) ions, J. Colloid Interface Sci. 283 (2005) 446- 451.
- Savage N., Diallo M. S., Nanomaterials and water purification: opportunities and challenges, J. Nanopart. Res. 7 (2005) 331-342.
- Erdem E., Karapınar N., Donat R., The removal of heavy metal cations by natural zeolites, J. Colloid Interface Sci. 284 (2004) 309-314.
- Shatialam A. M., Al-Harthy A., Al-Zawhry A., Feed water pretreatment in RO systems in middleeast desalination 150 (2002) 235-245.
- Murthy Z. V. P., Chaudhai L. B., Seperation of binary heavy metals from aqueous solutions by nanofiltration and characterization of the membrane using Spiegler-Kedem model, Chem. Eng. J. 150 (2008) 181-187.
- Fenglian F., Wang Q., Removal of heavy metal ions from wastewaters, a review, J. Environ. Manage. 92 (2011) 407-418.
- Yean S., Cong L., Yavuz J. T., Yu M., Effect of material particle size on adsorption and desorption of arsenite and arsenate, J. Mater. Res. Technol. 20 (2005) 3255-3264.
- Shen Y. F., Tang J., Me Z. N., Wang Y. D., Ren Y., Zou L., Preperation and application of Fe3O4 nanoparticles for wastewater purification, Sep. Purif. Technol. 68 (2009) 312-319.
- Ozdemir F. A., Demirata B., Apak R., Adsorptive removal of methylene blue from simulated dyeing wastewater with melamine-formaldehyde-urea resin, J. Appl. Polym. Sci. 112 (2009) 3442-3448.
- Ajenifuja E., Ajao J. A. , Ajayi E. O. B., Adsorption isotherm studies of Cu (II) and Co (II) in high concentration Aaqueous solutions on photocatalytically modified diatomaceous ceramic adsorbents, Appl. Water Sci. 7 (2017) 3793-3801.
- McKay G., Otterburn M. S., Sweenay A. G., The removal of color from effluent using various adsorbents, Water Res. 14 (1980) 15-20.
- Ozer A., Pirincci H. B., The adsorption of Cd(II) ions on sulphuric acid-treated wheat Bran, J. Hazard. Mater. 137 (2006) 849-855.
- Du S., Lou Y., Zou F., Li X., Li D., Polydopamine-coated Fe3O4 nanoparticles as synergistic redox mediators for catalytic reduction of azo dyes, NANO (2017)12-21.
- Wan Q., Huang Q., Liu M., Xu D., Huang H., Zhang Z., Wei Y., Aggregation-induced emission active luminescent polymeric nanoparticles: Non-covalent fabrication methodologies and biomedical applications 9 (2017) 145-160.
- Ghaemi N., A new approach to copper ion removal from water by polymeric nanocomposite membrane embedded with -alumina nanoparticles, Appl. Surf. Sci. 364 (2016) 221-228.
- Fouldagar M., Behestiti M., Salozyan H., Single and binary adsortpon of nickel and copper from aqueous solution by -alumina nanoparticle equilibrium and kinetic modelling, J. Mol. Liq. 211 (2015) 1060-1073.
- Thanh D. N., Novak P., Vejpravova J., Vu H. N., Lederer J., Munshi T., Removal of copper and nickel from water using nanocomposite of magnetic hydroxyapatite nanorods, J. Magn. Magn. Mater. 456 (2018) 451-460.
Details
| Primary Language | English |
|---|---|
| Journal Section | Natural Sciences |
| Authors | |
| Publication Date | June 30, 2019 |
| Submission Date | January 3, 2018 |
| Acceptance Date | January 4, 2019 |
| Published in Issue | Year 2019 |