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Sn Temelli Sn-Pb-Al Üçlü Alaşımında Yapısal, Elektriksel, Termal, Mekaniksel Özellikler ve Mikrosertlik

Yıl 2017, , 39 - 51, 08.12.2017

Canan Alper Billur , Mehmet Arı , Tuncay Karaaslan Buket Saatçi

https://doi.org/10.17776/csj.341093

Öz

Ötektik Sn-Pb-Al (Sn61.82Pb38.10Al0.08) üçlü alaşımı ve sabit
Al konsantrasyonunda Sn-Pb-Al  üçlü
alaşımının  (Sn-[x] wt. % Pb-10 wt. % Al) (x=40, 30, 20
and 10) beş farklı örneğinin yapısal, elektriksel, termal, mekaniksel özelliği
ve mikrosertliği araştırıldı. Örneklerin sıcaklığa bağlı olarak elektriksel
iletkenliği  dört nokta elektriksel
iletkenlik tekniği kullanılarak ölçüldü. Örneklerin sıcaklığa bağlı olarak
termal iletkenliği elektriksel ölçümlerden elde edilen datalarla birlikte  Wiedemann-Franz (W-F) yasasıyla gösterildi.
Taramalı elektron mikroskobu(SEM), X ışınları difraktometresi(XRD), EDX
ölçümleri, yüzey morfolojisini açığa çıkartmak, kristal yapı, hücre
parametreleri, tane boyutları ve kimyasal bileşimini belirlemek için
gerçekleştirildi. Çekme testleri alaşımdaki her bir bileşimin tane boyutlarına
bağlı olarak  en büyük gerilme
mukavemetini belirlemek için 
gerçekleştirildi. Alaşımın herbir bileşimi için mikrosertlik
sonuçları  Vickers test cihazı
kullanılarak bulundu.  

Anahtar Kelimeler

Elektriksel ve mekaniksel özellikler Mikrosertlik Kristal yapı

Kaynakça

  • [1]. Guang-ming X., Bao-mian L., Jian-zhong C., Effect of Heat Treatment on Microstructure and Property of Al-Sn-Pb Bearing Material, J. Iron Steel Res. Int., 2006, 13, 2, 73-76.
  • [2]. Noskova N.I., Korshunov L.G., Korznikov A.V., Microstructure and tribological properties of Al - Sn, Al - Sn - Pb, AND Sn - Sb - Cu alloys subjected to severe plastic deformation, Met. Sci. Heat Treat., 2008, 50, 11-12, 593-599.
  • [3]. Noskova N.I., Vil’danova N.F., Filippov YuI., Churbaev R.V., Pereturina I.A., Korshunov L.G., Korznikov A.V., Preparation, deformation, and failure of functional Al-Sn and Al-Sn-Pb nanocrystalline alloys, The Physics of Metals and Metallography, 2006, 102, 646-651.
  • [4]. Shim J.H., Lee H.N., Ha H.P., Cho Y.W., Yoon E.P., Liquid miscibility gap in the Al-Pb-Sn system, J. Alloys Compd., 2001, 327, 270-274.
  • [5]. Kittel C. Introduction to Solid State Physics, 8th Ed. John Wiley and Sons, New York, 2005, pp. 156.
  • [6]. Ari M., Saatçi B., Gündüz M., Meydaneri F., Bozoklu M., Microstructure and Thermo-Electrical Transport Properties Of Cd-Sn Alloys, Mater. Charact., 2008, 59, 624-630.
  • [7]. Saatçi B., Ari M., Gündüz M., Türktekin S., Meydaneri F., Durmuş S., Özdemir M., Structural and Transport Properties Of Sn-Mg Alloys, Continuum Mech. Thermodyn., 2013, 25,739-748.
  • [8]. Ocak Y., Aksöz S., Maraşlı N., Keşlioğlu K., Thermal and electrical conductivity of Sn–Ag-In alloys, J. Non-Crystalline Solids., 2010, 356, 1795-1801.
  • [9]. Aksöz S., Maraşlı N., Thermal and And Electrical Conductivities Of Silver-Indium-Tin Alloys, J. Physics Chem.Solids., 2012, 73, 902-910.
  • [10]. Ari M., Saatçi B., Gündüz M., Payveren M., S. Durmuş, Thermo-Electrical Characterization of Sn-Zn Alloys, Mater. Charact., 2008, 59, 757-763.
  • [11]. Saatci B., Ari M., Gündüz M., Meydaneri F., Bozoklu M., Durmus S., Thermal and Electrical Conductivities Of Cd-Zn Alloys, J. Phys. Condens. Matter., 2006, 18, 10643-10653.
  • [12]. Meydaneri F., Ari M., Saatçi B., Thermo-Electrical Characterization Of Lead-Cadmium (Pb-Cd) Alloys, Accepted Manuscript, Int. J. Phys. Sci., 2012, 7, 48, 6210-6221.
  • [13]. Cullity B.D.: Elements of X-Ray Diffraction, Inc, third edition, Addison-Wesley Publishing Company, United States of America, 1967. [14]. Callister W.D.: Materials Science and Engineering-An Introduction, John Wiley and Sons, New York, 1997.
  • [15]. Smits F.M., Measurement the of Sheet Resistivities Four-Point Probe, The Bell sys. Tech. J., 1958, 711-718.
  • [16]. Ziya A.B., Ohshima K., X-ray diffraction study of the structure and thermal parameters of the ternary Au–Ag–Pd alloys, J. Alloys Compd., 2006,425, 123-128.
  • [17]. Juˇsk˙enas R., Mockus Z., Kanapeckaite S., Stalnionis G., Survila A., XRD studies of the phase composition of the electrodeposited copper-rich Cu–Sn alloys, Electrochimica Acta. 2006, 52 , 928-935.
  • [18]. Ortiz A.L., Shaw L., X-ray diffraction analysis of a severely plastically deformed aluminum alloy, Acta Mater., 2004, 52, 2185-2197.
  • [19]. Shalaby R.M., Effect of silicon addition on mechanical and electrical properties of Sn–Zn based alloys rapidly quenched from melt, Materials Science and Engineering A, 2012, 550, 112-117.
  • [20]. Shalaby R.M., Effect of silver and indium addition on mechanical properties and indentation creep behavior of rapidly solidified Bi–Sn based lead-free solder alloys, Materials Science and Engineering A, 2013, 560, 86-95.
  • [21]. Billah Md.M., Shorowordi K.M., Sharif A., Effect of micron size Ni particle addition in Sn–8Zn–3Bi lead-free solder alloy on the microstructure, thermal and mechanical propertiesJ. Alloys Compd., 2014, 585, 32-39.
  • [22]. Scherrer P., Nachrichten von der Gesellschaft der Wissenschaften zu Göttingen, Mathematisch-Physikalische Klasse, Göttinger Nachrichten Gesell. (1918) 98-100.
  • [23]. Patterson A.L., The Scherrer Formula for X-Ray Particle Size Determination, Phys. Rev., 1939, 56,978-982.
  • [24]. Mishra R., Zemanova A., Kroupa A., Flandorfer H., Ipser H., Synthesis and characterization of Sn-rich Ni–Sb–Sn nanosolders, J. Alloys Compd., 2012, 513, 224-229.
  • [25]. E. Çadırlı, U. Böyük, H. Kaya, N. Maraşlı, S. Aksöz, Y. Ocak, Dependence Of Electrical Resistivity On Temperature And Sn Content In Pb-Sn Solders, J. Elect. Mater., 2011, 40, 2,195-200.
  • [26]. E. Çadırlı, H. Kaya, The effect of composition on microhardness and determination of electrical and thermal properties in the Sn-Cu alloys, J. Mater. Sci : Materıals In Electronıcs. 2011, 22, 1378-1386.
  • [27]. Çadirli E., Böyük U., Kaya H., Maraşli N., Determination Of Mechanical, Electrical And Thermal Properties Of The Sn-Bi-Zn Ternary Alloy, J. Non-Crystalline Solids, 2011, 357, 2876-2881.
  • [28]. Y. Ocak, S. Aksöz, N. Maraşli, K. Keşlioğlu, Dependency Of Thermal And Electrical Conductivity On Temperature And Composition Of Sn In Pb-Sn Alloys, Fluid Phase Equilibria, 2010, 295, 60-67.
  • [29]. Öztürk E., Aksöz S., Keşlioğlu K., Maraşli N., The Measurement Of Thermal Conductivity Variation With Temperature For Sn-20 Wt.% In Based Lead-Free Ternary Solders Thermochimica Acta, 2013, 554, 63-70.
  • [30]. Kaygisiz Y., Ocak Y., Aksöz S., Keşlioğlu K., Maraşli N., Thermal Conductivity And Interfacial Energies Of Solid Sn3sb2 In The Sn-Sb Peritectic System, Thermochimica Acta. 2011,520, 25-32.
  • [31]. Saatçi B., Çimen S., Pamuk H., Gündüz M., The interfacial free energy of solid Sn on the boundary interface with liquid Cd–Sn eutectic solution, J. Phys. Condens. Matter. 2007; 19: 326219 (11pp).
  • [32]. Aksöz S., Ocak Y., Keşlioğlu K. Maraşlı N., Determination Of Thermo-Electrical Properties In Sn Based Alloys, Met. Mater. Int. 2010, 16, 3, 507-515.
  • [33]. Saatçi B., Maraşlı N., Gündüz M., Thermal Conductivities Of Solid And Liquid Phases In Pb-Cd And Sn-Zn Binary Eutectic Alloys, Thermochimica Acta, 2007 ; 454 : 128-134.

Structural, electrical, thermal, mechanical properties and micro-hardness in Sn-based Sn-Pb-Al ternary alloys

Yıl 2017, , 39 - 51, 08.12.2017

Canan Alper Billur , Mehmet Arı , Tuncay Karaaslan Buket Saatçi

https://doi.org/10.17776/csj.341093

Öz

The structural,
electrical, thermal, mechanical properties and micro-hardness of five different
samples of Sn-Pb-Al ternary alloys (Sn-[x] wt. % Pb-10 wt. % Al) (x=40, 30, 20
and 10) with constant Al concentrations, and the eutectic Sn-Pb-Al (Sn61.82Pb38.10Al0.08)
ternary alloy were investigated. The electrical conductivity of the samples,
depending on temperature, was measured using the four-point probe technique
(4PPT). The temperature dependence of the thermal conductivities of the samples
was shown using the Wiedemann-Franz (W-F) law with the data obtained from
electrical measurements. Scanning Electron Microscope (SEM), X-ray diffraction
(XRD), and Energy Dispersive X-ray Analysis (EDX) measurements were carried out
to reveal the surface morphology, crystal structure, cell parameters, grain
sizes, and chemical compositions. Tensile tests were carried out to determine the
ultimate tensile strengths depending on the particle size of each component in
the alloys. The results of the micro-hardness tests were found using a Vickers
test machine for each component of the alloys. 

Anahtar Kelimeler

Electrical and mechanical properties Micro-hardness Crystal structure

Kaynakça

  • [1]. Guang-ming X., Bao-mian L., Jian-zhong C., Effect of Heat Treatment on Microstructure and Property of Al-Sn-Pb Bearing Material, J. Iron Steel Res. Int., 2006, 13, 2, 73-76.
  • [2]. Noskova N.I., Korshunov L.G., Korznikov A.V., Microstructure and tribological properties of Al - Sn, Al - Sn - Pb, AND Sn - Sb - Cu alloys subjected to severe plastic deformation, Met. Sci. Heat Treat., 2008, 50, 11-12, 593-599.
  • [3]. Noskova N.I., Vil’danova N.F., Filippov YuI., Churbaev R.V., Pereturina I.A., Korshunov L.G., Korznikov A.V., Preparation, deformation, and failure of functional Al-Sn and Al-Sn-Pb nanocrystalline alloys, The Physics of Metals and Metallography, 2006, 102, 646-651.
  • [4]. Shim J.H., Lee H.N., Ha H.P., Cho Y.W., Yoon E.P., Liquid miscibility gap in the Al-Pb-Sn system, J. Alloys Compd., 2001, 327, 270-274.
  • [5]. Kittel C. Introduction to Solid State Physics, 8th Ed. John Wiley and Sons, New York, 2005, pp. 156.
  • [6]. Ari M., Saatçi B., Gündüz M., Meydaneri F., Bozoklu M., Microstructure and Thermo-Electrical Transport Properties Of Cd-Sn Alloys, Mater. Charact., 2008, 59, 624-630.
  • [7]. Saatçi B., Ari M., Gündüz M., Türktekin S., Meydaneri F., Durmuş S., Özdemir M., Structural and Transport Properties Of Sn-Mg Alloys, Continuum Mech. Thermodyn., 2013, 25,739-748.
  • [8]. Ocak Y., Aksöz S., Maraşlı N., Keşlioğlu K., Thermal and electrical conductivity of Sn–Ag-In alloys, J. Non-Crystalline Solids., 2010, 356, 1795-1801.
  • [9]. Aksöz S., Maraşlı N., Thermal and And Electrical Conductivities Of Silver-Indium-Tin Alloys, J. Physics Chem.Solids., 2012, 73, 902-910.
  • [10]. Ari M., Saatçi B., Gündüz M., Payveren M., S. Durmuş, Thermo-Electrical Characterization of Sn-Zn Alloys, Mater. Charact., 2008, 59, 757-763.
  • [11]. Saatci B., Ari M., Gündüz M., Meydaneri F., Bozoklu M., Durmus S., Thermal and Electrical Conductivities Of Cd-Zn Alloys, J. Phys. Condens. Matter., 2006, 18, 10643-10653.
  • [12]. Meydaneri F., Ari M., Saatçi B., Thermo-Electrical Characterization Of Lead-Cadmium (Pb-Cd) Alloys, Accepted Manuscript, Int. J. Phys. Sci., 2012, 7, 48, 6210-6221.
  • [13]. Cullity B.D.: Elements of X-Ray Diffraction, Inc, third edition, Addison-Wesley Publishing Company, United States of America, 1967. [14]. Callister W.D.: Materials Science and Engineering-An Introduction, John Wiley and Sons, New York, 1997.
  • [15]. Smits F.M., Measurement the of Sheet Resistivities Four-Point Probe, The Bell sys. Tech. J., 1958, 711-718.
  • [16]. Ziya A.B., Ohshima K., X-ray diffraction study of the structure and thermal parameters of the ternary Au–Ag–Pd alloys, J. Alloys Compd., 2006,425, 123-128.
  • [17]. Juˇsk˙enas R., Mockus Z., Kanapeckaite S., Stalnionis G., Survila A., XRD studies of the phase composition of the electrodeposited copper-rich Cu–Sn alloys, Electrochimica Acta. 2006, 52 , 928-935.
  • [18]. Ortiz A.L., Shaw L., X-ray diffraction analysis of a severely plastically deformed aluminum alloy, Acta Mater., 2004, 52, 2185-2197.
  • [19]. Shalaby R.M., Effect of silicon addition on mechanical and electrical properties of Sn–Zn based alloys rapidly quenched from melt, Materials Science and Engineering A, 2012, 550, 112-117.
  • [20]. Shalaby R.M., Effect of silver and indium addition on mechanical properties and indentation creep behavior of rapidly solidified Bi–Sn based lead-free solder alloys, Materials Science and Engineering A, 2013, 560, 86-95.
  • [21]. Billah Md.M., Shorowordi K.M., Sharif A., Effect of micron size Ni particle addition in Sn–8Zn–3Bi lead-free solder alloy on the microstructure, thermal and mechanical propertiesJ. Alloys Compd., 2014, 585, 32-39.
  • [22]. Scherrer P., Nachrichten von der Gesellschaft der Wissenschaften zu Göttingen, Mathematisch-Physikalische Klasse, Göttinger Nachrichten Gesell. (1918) 98-100.
  • [23]. Patterson A.L., The Scherrer Formula for X-Ray Particle Size Determination, Phys. Rev., 1939, 56,978-982.
  • [24]. Mishra R., Zemanova A., Kroupa A., Flandorfer H., Ipser H., Synthesis and characterization of Sn-rich Ni–Sb–Sn nanosolders, J. Alloys Compd., 2012, 513, 224-229.
  • [25]. E. Çadırlı, U. Böyük, H. Kaya, N. Maraşlı, S. Aksöz, Y. Ocak, Dependence Of Electrical Resistivity On Temperature And Sn Content In Pb-Sn Solders, J. Elect. Mater., 2011, 40, 2,195-200.
  • [26]. E. Çadırlı, H. Kaya, The effect of composition on microhardness and determination of electrical and thermal properties in the Sn-Cu alloys, J. Mater. Sci : Materıals In Electronıcs. 2011, 22, 1378-1386.
  • [27]. Çadirli E., Böyük U., Kaya H., Maraşli N., Determination Of Mechanical, Electrical And Thermal Properties Of The Sn-Bi-Zn Ternary Alloy, J. Non-Crystalline Solids, 2011, 357, 2876-2881.
  • [28]. Y. Ocak, S. Aksöz, N. Maraşli, K. Keşlioğlu, Dependency Of Thermal And Electrical Conductivity On Temperature And Composition Of Sn In Pb-Sn Alloys, Fluid Phase Equilibria, 2010, 295, 60-67.
  • [29]. Öztürk E., Aksöz S., Keşlioğlu K., Maraşli N., The Measurement Of Thermal Conductivity Variation With Temperature For Sn-20 Wt.% In Based Lead-Free Ternary Solders Thermochimica Acta, 2013, 554, 63-70.
  • [30]. Kaygisiz Y., Ocak Y., Aksöz S., Keşlioğlu K., Maraşli N., Thermal Conductivity And Interfacial Energies Of Solid Sn3sb2 In The Sn-Sb Peritectic System, Thermochimica Acta. 2011,520, 25-32.
  • [31]. Saatçi B., Çimen S., Pamuk H., Gündüz M., The interfacial free energy of solid Sn on the boundary interface with liquid Cd–Sn eutectic solution, J. Phys. Condens. Matter. 2007; 19: 326219 (11pp).
  • [32]. Aksöz S., Ocak Y., Keşlioğlu K. Maraşlı N., Determination Of Thermo-Electrical Properties In Sn Based Alloys, Met. Mater. Int. 2010, 16, 3, 507-515.
  • [33]. Saatçi B., Maraşlı N., Gündüz M., Thermal Conductivities Of Solid And Liquid Phases In Pb-Cd And Sn-Zn Binary Eutectic Alloys, Thermochimica Acta, 2007 ; 454 : 128-134.
Toplam 32 adet kaynakça vardır.

Ayrıntılar

Birincil Dil İngilizce
Bölüm Natural Sciences
Yazarlar

Canan Alper Billur

Mehmet Arı

Tuncay Karaaslan

Buket Saatçi

Yayımlanma Tarihi 8 Aralık 2017
Gönderilme Tarihi 2 Ekim 2017
Kabul Tarihi 24 Ekim 2017
Yayımlandığı Sayı Yıl 2017

Kaynak Göster

APA Alper Billur, C., Arı, M., Karaaslan, T., Saatçi, B. (2017). Structural, electrical, thermal, mechanical properties and micro-hardness in Sn-based Sn-Pb-Al ternary alloys. Cumhuriyet Science Journal, 38(4), 39-51. https://doi.org/10.17776/csj.341093